Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E

Transcription

1 Technical Information January 2016 Supersedes issue dated October 2015 WF-No _050411e-06/Page 1 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Acrylic terpolymer products for hair-setting preparations with a strong, long-lasting effect. = Registered trademark of BASF in many countries. = Trademark of BASF

2 04_050411e-06 January 2016 Page 2 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Chemical nature Terpolymer of tert-butyl acrylate, ethyl acrylate and methacrylic acid Formula INCI-name Acrylates Copolymer PRD-No. Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Appearance Luvimer 100 P: white powder. Luvimer 36 D Polymer: approx. 36% dispersion in water Luvimer 30 E: approx. 30% solution in ethanol. Storage Shelf life Specifications Luvimer 100 P can be stored for three years and Luvimer 30 E can be stored for two years at 25 C in the unopened original containers. Luvimer 36 D Polymer can be stored for six months in the unopened original containers. It should be kept at temperatures over 0 C. See separate document: "Standard Specification (not for regulatory purposes) available via BASF s WorldAccount: (registered access). Technical properties In neutralized form, Luvimer is an anionic film-forming agent for hair setting products. It is available in the form of a powder, an aqueous dispersion and an ethanolic solution, allowing the formulator to select the most suitable form for his product. Setting effect Even in small quantities, Luvimer provides an excellent setting effect. As can be seen from the curl retention curve, Luvimer provides a prolonged setting effect even under extreme conditions. Curl retention at 25 C effect of humidity

3 04_050411e-06 January 2016 Page 3 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Hydrocarbon tolerance Ethanolic solutions of Luvimer (100 P, 30 E) are tolerant to propane/butane or dimethyl ether (DME) or mixtures of these propellants over a wide range of concentrations. Ethanolic solutions containing 3% (solids) of Luvimer completely neutralized with 2 aminomethylpropanol (AMP) tolerate a maximum of 50% propane/butane or a maximum of 70% DME, depending on the particular formulation. The following graphs show the tolerance of Luvimer to propane/butane at different concentrations in - ethanol absolute and - 96% ethanol. Propane/butane (25 : 75) tolerance in 96% ethanol at -20 C Luvimer 100 P (Batch No ) Propane/butane (25 : 75) tolerance in ethanol absolute at room temperature and at -20 C Luvimer 100 P (Batch No ) We recommend that DME be used with Luvimer 36 D Polymer. Solubility Luvimer 100 P is soluble in ethanol. When it has been completely neutralized, it is also soluble in water. Ethanolic solutions of Luvimer 100 P of higher concentration can become slightly turbid. However, this is merely an opalescence effect that, in our experience, does not lead to any precipitation of the polymer.

4 04_050411e-06 January 2016 Page 4 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Processing Neutralization For best results, Luvimer should be completely neutralized, preferably with AMP. If the neutralizing agent is added directly to Luvimer 36 D Polymer or Luvimer 30 E, a highly viscous solution that is difficult to handle is obtained. It is therefore recommended to mix the necessary quantity of neutralizing agent with the solvent, before slowly adding Luvimer 36 D Polymer or Luvimer 30 E. The usual amino alcohols, e.g. AMP (2 amino 2 methylpropan-1-ol), DEPA (diethylaminopropylamine) or TIPA (triisopropanolamine) can be used as neutralizing agents. The quantity required is calculated as follows: N = x.y.z.a/100 where N = Quantity of neutralizing agent, g x = Weight of Luvimer 100 P, kg y = Acid value z = Degree of neutralization, % A = Factor for AMP = 1.59 DEPA = 2.32 TIPA = 3.41 Example: For 1 kg of Luvimer 100 P with an acid value of 148, the following quantity of AMP is required for 100% neutralization: N = /100=235.4 g APM Compatibility Luvimer is compatible with anionic hair setting polymers, e.g. Luviset CA 66, Luviset CAN, Ultrahold 8 and Ultrahold Strong. PVP and copolymers or terpoly mers with vinylpyrrolidone or the Luviskol K grades, the Luviskol VA grades or Luviskol Plus can be added to Luvimer 100 P. Luvimer is also compatible with many other commercially available hair-setting polymers. Equivalent suggested formulations for our three grades of Luvimer can be found under the following formulation numbers. Luvimer 100 P 30 E 36 D Polymer Formulation No. 01/ / / / / / / / / / / / /00718

5 04_050411e-06 January 2016 Page 5 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Suggested formulations for Luvimer 100 P: Hair sprays (without water) Hairspray with Luvimer 100 P; excellent hold, pleasant feel No. 01/01131 A 0.95 AMP (56) Aminomethyl Propanol 0.10 Dow Corning 190 (16) PEG/PPG-18/18 Dimethicone Surfactant 0.03 Dowanol TPM (16) PPG-3 Methylether 0.10 D-Panthenol USP (1) Panthenol Ethanol Alcohol B 4.00 Luvimer 100 P (1) Acrylates Copolymer C Propane/Butane Propane/Butane Weigh out the components of phase A and stir until a homogeneous solution is obtained. Add phase B and stir until a homogeneous solution is obtained. Fill into appropriate containers and charge with phase C. Properties: Pressure: 3.7 bar (20 C) Density: g/ml Cloud point: -30 C clear Hairspray with Luvimer 100 P, strong hold No. 01/01130 A 0.95 AMP (56) Aminomethyl Propanol 0.10 Dow Corning 190 (16) PEG/PPG-18/18 Dimethicone Surfactant 0.10 Luvitol EHO (1) Cetearyl Ethylhexonate 0.10 D-Panthenol USP (1) Panthenol Ethanol Alcohol B 4.00 Luvimer 100 P (1) Acrylates Copolymer C Propane/Butane Propane/Butane Weigh out the components of phase A and stir until a homogeneous solution is obtained. Add phase B and stir until a homogeneous solution is obtained. Fill into appropriate containers and charge with phase C. Properties: Pressure: 3.6 bar (20 C) Density: g/ml Cloud point: -30 C clear

6 04_050411e-06 January 2016 Page 6 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Hairspray with Luvimer 100 P, D-Panthenol USP, UV-Filter; normal hold A 0.47 AMP (56) Aminomethyl Propanol 0.10 D-Panthenol USP (1) Panthenol 0.10 Uvinul MS 40 (1) Benzophenone Abil B 8843 (44) PEG-14 Dimethicone Ethanol Alcohol B 2.00 Luvimer 100 P (1) Acrylates Copolymer C Propane/Butane 3,5 bar (20 C) Propane/Butane No. 01/00979 Add phase B to phase A and stir until a clearly solution is obtained. Fill into appropriate containers and charge with phase C. Hairspray with Luvimer 100 P No. 01/00826 A 0.93 AMP (56) Aminomethyl Propanol Ethanol Alcohol B 4.00 Luvimer 100 P (1) Acrylates Copolymer C Propane/Butane Propane/Butane Add phase B and stir until a homogeneous solution is obtained. Fill into appropriate containers and charge with phase C. Properties: Pressure: 3.6 bar (20 C) Density: g/ml Cloud point: -35 C clear Hair sprays (80 % VOC) Hairspray VOC 80 with Luvimer 100 P, normal hold No. 01/00830 A 0.46 AMP (56) Aminomethyl Propanol Water dem. Aqua Ethanol Alcohol B 2.00 Luvimer 100 P (1) Acrylates Copolymer C Dimethyl Ether Dimethyl Ether Add phase B and stir until a homogeneous solution is obtained. Fill into appropriate containers and charge with phase C. Properties: Pressure: 3.2 bar (20 C) Density: g/ml Cloud point: -35 C clear

7 04_050411e-06 January 2016 Page 7 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Polymer combinations Hair spray with Luvimer 100 P and Luviskol VA 37 E No. 01/00695 A 1.20 Luviskol VA 37 E (1) VP/VA Copolymer Ethanol Alcohol B 2.40 Luvimer 100 P (1) Acrylates Copolymer 0.56 AMP (56) Aminomethyl Propanol C Dimethyl Ether Dimethyl Ether Weigh out the components of phase A and stir until a homogeneous solution is obtained. Add phase B into phase and stir until a homogeneous solution is obtained. Fill into apporiate containers and charge with phase C. Properties: Cloud point: still clear at -35 C Pressure: 3.2 bar Density: g/ml Setting formulations for pump sprays Pump Setting Spray with Luvimer 100 P No. 01/00717 A 1.39 AMP (56) Aminomethyl Propanol Ethanol 96% Alcohol B 6.00 Luvimer 100 P (1) Acrylates Copolymer Add phase B and stir until a homogeneous solution is obtained. Pump setting spray VOC 80 with Luvimer 100 P, strong hold A 1.39 AMP (56) Aminomethyl Propanol Water dem. Aqua Ethanol Alcohol B 6.00 Luvimer 100 P (1) Acrylates Copolymer No. 01/00718 Add phase B and stir until a homogeneous solution is obtained.

8 04_050411e-06 January 2016 Page 8 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Suggested formulations for Luvimer 30 E: Hairspray with Luvimer 30 E No. 01/00829 A 6.70 Luvimer 30 E (1) Acrylates Copolymer 0.46 AMP (56) Aminomethyl Propanol Ethanol Alcohol B Propane/Butane Propane/Butane Weigh out the components of phase A and stir until a homogeneous solution is obtained. Fill into apporiate containers and charge with phase B. Properties: Cloud point: still clear at -35 C Pressure: 4.0 bar Density: g/ml Hairspray with Luvimer 30 E in 80 VOC No. 01/00831 A 0.46 AMP (56) Aminomethyl Propanol Water, dem. Aqua Ethanol Alcohol B 6.70 Luvimer 30 E (1) Acrylates Copolymer C Dimethyl Ether Dimethyl Ether Add phase B and stir until a clear solution is obtained. Fill into apporiate containers and charge with phase C. Properties: Cloud point: still clear at -35 C Pressure: 3.2 bar Density: g/ml Hairspray with Luvimer 30 E and Luviskol VA 37 E No. 01/00835 A 8.00 Luvimer 30 E (1) Acrylates Copolymer 0.56 AMP (56) Aminomethyl Propanol 1.20 Luviskol VA 37 E (1) VP/VA Copolymer Ethanol Alcohol B Dimethyl Ether Dimethyl Ether Weigh out the components of phase A and stir until a homogeneous solution is obtained. Fill into apporiate containers and charge with phase B. Properties: Cloud point: still clear at -35 C Pressure: 3.2 bar Density: g/ml

9 04_050411e-06 January 2016 Page 9 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Pumpspray with Luvimer 30 E No. 01/ Luvimer 30 E (1) Acrylates Copolymer 1.39 AMP (56) Aminomethyl Propanol Water, dem. Aqua Ethanol Alcohol Mix together ethanol, AMP, water and Perfume, add Luvimer 30 E, stir until dissolved. Suppliers 1. BASF SE Ludwigshafen, Germany Tel.: +49(621) 60-0 Fax: +49(621) Dow Corning Corporation 2200 West Salzburg Road, MI Midland, USA Tel.: +1(517) (800) Fax: +1(517) Evonik Goldschmidt GmbH Goldschmidtstraße 100, Essen, Germany Tel.: +49(201) Fax: +49(201) ANGUS Chemical Company 1500 Lake Cook Road, IL Buffalo Grove, USA Tel.: +1(800) Fax: +1(989)

10 04_050411e-06 January 2016 Page 10 of 10 Luvimer 100 P Luvimer 36 D Polymer Luvimer 30 E Toxicology Safety An examination of the raw material did not indicate any health risks for the concentrations used and the areas of application given. However, due to the large numer of possible applications, also in combination with other pro ducts, the user has to carry out his own safety assessment of his products. We are not aware of any ill effect that can result from using Luvimer for the purpose for which they are intended and from processing them in accordance with current practices. According to the experience that we have gained over many years and other information at our disposal, Luvimer do not exert harmful effects on health, provided they are used properly, due attention is given to the precautions necessary for handling chemicals, and the information and advice given in our Safety Data Sheets are observed. Labelling Please consult the current Safety Data Sheets for information on the classification and labelling of our products and other information relevant to safety. Disclaimer This document, or any answers or information provided herein by BASF, does not constitute a legally binding obligation of BASF. While the descriptions, designs, data and information contained herein are presented in good faith and believed to be accurate, it is provided for your guidance only. Because many factors may affect processing or application/use, we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use. It does not relieve our customers from the obligation to perform a full inspection of the products upon delivery or any other obligation. NO WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. January 2016 BASF Care Chemicals Division