Plasticizers for today and for the future PVC Formulation 2014, Dusselsdorf
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1 Plasticizers for today and for the future PVC Formulation 2014, Dusselsdorf Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions
2 Table of Contents Introduction of the company Perstorp in PVC industry Plasticizers Investment Emoltene 100 (DPHP, C10) Pevalen (Polyolester plasticizer) Summary
3 Perstorp in brief World leader in several sectors of the specialty chemicals market Pioneer in formalin chemistry, plastics and surface materials Perstorp was formed in 1881, over 130 years of winning formulas Since December 2005 controlled by PAI partners, a leading European private equity company Annual turnover of more than 10 billion SEK in 2012 About 1,500 employees in 22 countries Production plants in Europe, Asia and North America Sales offices in all major markets
4 Perstorp in the PVC industry Fully integrated plasticizer producer based on the west coast of Sweden since 1980 s Perstorp exited the DOP business in 2012 Storage facilities in UK, Belgium, Germany and Portugal to serve entire Europe Focus on European market and sustainable growth Member of ECPI, VinylPlus and founding member of PlasticiserPlus
5 Perstorp believes in plasticizers Perstorp is making its largest investment in history Based on our own technology and backwardly integrated in raw materials It will be on stream in Q Two plasticizers in the product tree, Emoltene TM 100 and Pevalen TM This investment will increase the production by MT
6 Emoltene TM 100 Investment for a more sustainable future Pevalen TM Versatile general PVC plasticizer Established C10 (DPHP) GP plasticizer Excellent versatility and flexibility Expands lifespan of end products High technical performance, with good outdoor properties New capacity for Valeraldehyde and its derivatives Strengthen our production platform Fully integrated and secure supply chain Ability to offer competitive and safe products Innovative plasticizer for sensitive applications Flexible, versatile & safe High performance polyol ester plasticizer Highly efficient in providing softness Easy to process and use Low volatility ensuring no VOC and consistent properties
7 Emoltene 100 and Pevalen focus on different markets Emoltene Durable applications Pevalen - Sensitive applications Wire and cables Films & sheets e.g. roofing membranes, swimming pool liners, automotive foils Coated fabrics; e.g. tarpaulins Automotive interiors Coated fabrics; e.g. table cloths, protective clothing Films & sheets; e.g. office materials, furniture foils Flooring Plastisols; e.g. wallpaper, toys Moulded parts; e.g. grips
8 Key segments where Emoltene 100 is preferable CABLES & WIRES AUTOMOTIVE INTERIOR FILM AND SHEETS Low volatility and high UV resistance with C10 plasticizer Low volatility/migration of C10 plasticizers secures long life span required Low volatility of C10 plasticizers secures long life span required Well accepted for PVC cables at all major users Plasticized PVC not easy substituted for this industry due to the advantage PVC has vs. other polymers Plasticized PVC good UV stability and outdoor resistance
9 Volatility 0 DPHP DINP DOP -5 Weight Change, % Emoltene 100 (DPHP) has low volatility Emoltene 100 (DPHP) makes the product durable
10 Fogging Emoltene 100 (DPHP) has lower fogging Emoltene 100 (DPHP) is suitable for car interiors
11 Migration to plastics ABS PC PS Acrylic TOTM Polymeric Polymeric Polymeric DPHP TOTM TOTM TOTM DOTP DPHP DOTP DPHP DEHP DINP DINP DINCH DINCH DINCH DPHP DINP DINP DOTP DEHP DOTP Polymeric DEHP DINCH DEHP DOA ATBC DOA DOA ATBC DOA ATBC ATBC Benzoate Benzoate Benzoate Benzoate Emoltene 100 (DPHP) has low migration Emoltene 100 (DPHP) contributes with high permanency Source: www2.teknorapex.com/pvc-plasticizer-migration
12 Water absorption 0,36 0,35 Weight Change, % 0,34 0,33 0,32 0,31 0,3 0,29 DPHP DINP DOP Emoltene 100 (DPHP) has low water absorption Emoltene 100 (DPHP) suitable for outdoor applications
13 Pevalen A versatile general purpose plasticizer that is equal to or in some cases better than standard phthalate plasticizers Perstorp is increasing capacity and will meet customer demand. Perstorp will by 2015 be fully integrated in raw materials. At this time, Pevalen will be commercially competitive to other high volume plasticizers The chemistry is well established and proven Process for food contact approval underway
14 Easy storage 2,5 Viscosity 2 Emoltene 100 Viscosity Pas 1,5 1 0, Temperature C DOTP DOP DINP Dinch DINCH Pevalen Pevalen has low viscosity even at temperatures below 0 C Pevalen does not need to be heated during storage
15 Processing top of the class 15:00 Dry blend time 12:00 Time (mm/ss) 09:00 06:00 03:00 00:00 DINCH DINP DOP DOTP Pevalen Pevalen has short dry blend time Pevalen gives fast processing
16 Unique product performance Effciency Hardness (Shore A) DINCH DINP DOP DOTP Pevalen Volatility (% lost) Pevalen has a unique combination of low volatility and high plasticizing efficiency
17 Migration to rubber Pevalen has lower or equal migration to rubber
18 Migration to plastics Pevalen has comparable migration to plastics Pevalen high compatibility to PVC is also shown here it has a tendency to migrate more to non-plasticized PVC
19 Durability Extraction chemicals and oil 30,0 25,0 Weight loss % 20,0 15,0 10,0 5,0 DINCH DINP DOP Pevalen DOTP 0,0 Heptane Hexane Olive Oil -5,0 Pevalen has very good resistance to chemicals Pevalen has same performance as other plasticizers on oil
20 Durability 0,0 Extraction water solutions 1 %Soap 1% NaOH Weight loss % -0,1-0,2-0,3-0,4 DINCH DINP DOP Pevalen DOTP -0,5-0,6 Pevalen has same or better resistance to water solution as other plasticizers
21 Summary Plasticizers Emoltene 100 well-established HMW phthalate plasticizer Available in high volumes Highly competitive production platform Valued for low water absorption, low volatility and migration Reflected in improved durability, good outdoor resistance and long life span Pevalen an innovative polyol ester plasticizer High performance polyol ester plasticizer Highly efficient in providing softness Easy to process and use Low volatility and migration ensuring no VOC and consistent properties
22 Thank You for your attention! Anders Magnusson Application Specialist Perstorp Group
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