: Mold Spray 80 Winter

Transcription

1 Date of issue: 05/01/2015 Supersedes: 11/05/2013 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Mold Spray 80 Winter CAS No : Mixture Product code : 3674 Other means of identification : Alumina-Silicate Wet Air Set Mortar-Slurry 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Refractory 1.3. Details of the supplier of the safety data sheet Resco Products, Inc. One Robinson Plaza, Suite Steubenville Pike Pittsburgh, PA United States Emergency telephone number Emergency number : EMERGENCY ONLY (CHEMTREC) USA & Canada Outside USA & Canada SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 Eye Irrit. 2B H320 Carc. 1A H350 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 04/10/2015 EN (English) Page 1 GHS Other hazards Other hazards not contributing to the : Ethylene glycol is toxic to humans. classification 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture : Danger : H315 - Causes skin irritation H319 - Causes serious eye irritation H350 - May cause cancer (After drying or heating, Inhalation) : P202 - Do not handle until all safety precautions have been read and understood P280 - Wear eye protection, protective gloves, protective clothing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention Name Product identifier % GHS-US classification aluminium oxide, non-fibrous (CAS No) Not classified sodium silicate, alkaline 1.6/2.6, 35%<=conc<=55%, aqueous solutions (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 ethylene glycol (CAS No) Not classified quartz (CAS No) Carc. 1A, H350 cristobalite (CAS No) Carc. 1A, H350 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

2 First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Allow victim to breathe fresh air. Allow the victim to rest. : Gently wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : After drying or heating. May cause cancer by inhalation. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media : No unsuitable extinguishing media known Special hazards arising from the substance or mixture Fire hazard : Not flammable. Reactivity : Air Setting Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : If spilled, may cause the floor to be slippery For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop release Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment : Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with eyes. Avoid contact with skin. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH ACGIH TWA (mg/m³) mg/m³ PEL (TWA) (mg/m³) 0.1 mg/m³ ACGIH ACGIH ACGIH Ceiling (mg/m³) 100 mg/m³ ACGIH ACGIH TWA (mg/m³) 1 mg/m³ 04/10/2015 EN (English) 2/7

3 ACGIH ACGIH TWA (mg/m³) mg/m³ respirable dust PEL (TWA) (mg/m³) 0.05 mg/m³ respirable dust 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : After air drying or heating. Dust when sawing or tear out. Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) : Slurry. : Grey : Earthy Odor : : Relative evaporation rate (ether=1) : Melting point : > 2000 F Freezing point : 20 F Boiling point Flash point Critical temperature Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Vapour pressure at 50 C Critical pressure Relative vapour density at 20 C : : : : : None Relative density : 2.2 Solubility Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : : Water: Moderate : 9.2. SECTION 10: Stability and reactivity Reactivity Air Setting Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong acids. Strong bases Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 04/10/2015 EN (English) 3/7

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 oral rat LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC group IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information Toxicity > 2000 mg/kg (Rat) > 5000 mg/kg (Rat; Literature study) > mg/kg (Rat; Experimental value) : Causes skin irritation. : Causes eye irritation. : May cause cancer (After drying or heating, Inhalation). 1 - Carcinogenic to humans 1 - Carcinogenic to humans : Based on available data, the classification criteria are not met. LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 LC50 fishes 1 EC50 Daphnia 1 LC50 fish 2 Threshold limit algae 1 Threshold limit algae 2 Threshold limit algae BOD (% of ) : After drying or heating. May cause cancer by inhalation. Danger of serious damage to health by prolonged exposure through inhalation. : Causes skin irritation. : Causes serious eye irritation mg/l (96 h; Gambusia affinis; Pure substance) 216 mg/l (96 h; Daphnia magna; Pure substance) 210 mg/l (96 h; Brachydanio rerio; Pure substance) 632 mg/l (96 h; Lymnaea sp.; Pure substance) mg/l (96 h; Pimephales promelas; Static system) > mg/l (24 h; Daphnia magna) mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Static system) > mg/l (168 h; Scenedesmus quadricauda) 2000 mg/l (192 h; Microcystis aeruginosa) > 100 mg/l (72 h; Selenastrum capricornutum; GLP) Biodegradability: not applicable. Biodegradability: not applicable. No (test) data on mobility of the components available. 04/10/2015 EN (English) 4/7

5 BOD (% of ) BOD (% of ) BOD (% of ) BOD (% of ) Readily biodegradable in water. Biodegradable in the soil g O₂/g substance 1.24 g O₂/g substance 1.29 g O₂/g substance 0.36 % Biodegradability: not applicable. Biodegradability: not applicable. BCF fish 1 BCF other aquatic organisms 1 BCF other aquatic organisms 2 10 (72 h; Leuciscus idus) (Procambarus sp.; Chronic) 190 (24 h; Algae) (Experimental value) Low potential for bioaccumulation (BCF < 500) Mobility in soil Surface tension N/m (20 C) Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Effect on the global warming : None known : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. 04/10/2015 EN (English) 5/7

6 ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations EPA TSCA Regulatory Flag Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA WHMIS Classification D2A EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations Listed on IARC (International Agency for Research on Cancer) \ US State regulations Mold Spray Winter(Mixture) CERCLA RQ for pure ethylene glycol is 5,000 lbs. for this product this would equal 185,000 lbs. This product contains crystalline silica, a chemical known to the state of California to cause cancer. This product contains ethylene glycol a chemical known to the State of California to cause birth defects or other reproductive harm. Carcinogens List Developmental Toxicity Female Yes No No No Carcinogens List Developmental Toxicity Female Yes No No No Ethylene Glycol ( ) Carcinogens List Developmental Toxicity Female No Yes No No Male Male Male No significance risk level (NSRL) No significance risk level (NSRL) Non-significant risk level (NSRL) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: : None. Full text of H-phrases: Carc. 1A Carcinogenicity, Category 1A Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Skin Irrit. 2 Skin corrosion/irritation, Category H315 Causes skin irritation 04/10/2015 EN (English) 6/7

7 H320 Causes eye irritation H350 May cause cancer SDS US (GHS HazCom 2012) This information and recommendations set forth herein are taken from sources believed to be accurate as of the date herein, however, Resco Products, Inc. makes no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assumes no liability to any user thereof. 04/10/2015 EN (English) 7/7