Page 1 of 7. MSDS for # GRAPHPEPS FINELINERS

Transcription

1 Page n / 07 Page 1 of 7 SECTION Physical Regulatory Other Ecological information. and information. chemical... properties. / >>...// >>... / >> Odour Substances 10. Toxicity. Niosh subject - Registry to the Rotterdam of Toxic Convention: Effects of Chemical imperceptible Substances Odour threshold. SECTION 3. Composition/information on ingredients. ph. Information 11. INRS 6. - Fiche not Accidental available. Toxicologique release (toxicological measures. sheet) 3.1. SECTION Melting 12. Patty or freezing - point. Substances. > 100 C. Initial Substances boiling subject 1. Industrial Identification Hygiene point. to the Stockholm Convention: of and the Toxicology substance/mixture and of the company/undertaking -4 C Persistence N.I. Sax - Dangerous and degradability. properties of < Industrial Materials-7, 1989 Edition Boiling range Flash Information Product Personal ECHA point. website identifier not precautions, relevant. available. protective > equipment 100 C. and emergency procedures. Evaporation Use breathing Rate equipment if fumes or Not powders available Healthcare Mixtures. controls. are released into the air. These indications apply for both Flammability of solids and gases Lower Code: processing Bioaccumulative staff and those potential. Information inflammability not limit. available. involved in emergency Not FPIavailable. procedures. Upper Information Product Note inflammability The product name users: not limit. does available. Not not contain substances FINELINER available. classified as being hazardous to human health or the environment Lower 6.2. The explosive pursuant Environmental information limit. to the provisions contained precautions. set in forth the in present Directives sheet 67/548/EEC are based and/or on our EC Regulation own knowledge 1272/2008 on the (CLP) date (and of the last Upper Chemical explosive limit. safety assessment Vapour version. subsequent The Relevant Mobility product pressure. Users identified amendments in must soil. must not penetrate verify uses and of the supplements). the into suitability substance the sewer and system or thoroughness mixture come and uses into of provided contact advised with information against surface according water ground to each water. specific Vapour Information use of density the product. not available. Specific No chemical gravity. safety assessment has been Not processed available. for the mixture and the substances it contains SECTION This Methods 4. and First material aid measures. for containment and cleaning up. Solubility Intended document use must not be regarded as a soluble INKS guarantee in FOR waterfineliner on any specific PS. product property Partition The Confine Results use coefficient: using of of this n-octanol/water PBT earth product and or vpvb inert is not assessment. material. subject to Not Collect our available. direct as much control; material therefore, as possible users must, and under eliminate their the own rest responsibility, using jets of SECTION Ignition 4.1. water. temperature. 16. Other information. Description Contaminated of first material aid measures. should be disposed 1.3. comply Details with of the supplier current of health the safety and safety data sheet laws of and in compliance regulations. with The the producer provisions is set relieved forth in from point any 13. liability Decomposition temperature. Viscosity On No arising the episodes from basis improper of of available harm uses. to data, the the staff product authorised 3-5 does cps not to use contain the any product PBT or have vpvb been in percentage reported. The greater following than 0,1%. general 6.4. Explosive measures Provide Reference properties should to other be adopted sections. as necessary: Oxidising LEGD: Name appointed staff with adequate training REINOL on how s.p.a. to use chemical products. properties INHALATION: Any Other information adverse Remove on effects. personal to open protection air. and If the disposal subject is stops given breathing, sections administer 8 and Full ADR: address European Agreement concerning the S.da carriage del Francese of Dangerous 21 goods by Road artificial respiration. Get medical 9.2. advice/attention. Other information. VOC - District CAS (Directive NUMBER: and 1999/13/EC) Country Chemical : Abstract Service 10, Number % Borgaro T.se (TO) SECTION VOC Information INGESTION: (volatile 7. carbon) not Handling Get available. : medical and advice/attention. storage. 4,73 % - CE50: Effective concentration (required to induce Induce Italia a 50% vomiting effect) only if indicated by the doctor. Do not give anything by - CE mouth NUMBER: to an unconscious Identifier in ESIS person. (European Tel. archive +39 of 011 existing substances) SECTION EYES - CLP: and EC Regulation SKIN: Stability Disposal Wash 1272/2008 and with considerations. plenty reactivity. of water. Fax In the +39 event of persistent irritation, get medical advice/attention DNEL: Precautions address Derived of for No the safe Effect competent handling. Level 4.2. Before - person EmS: Most Emergency handling important the symptoms Schedule product, and consult effects, all the both other acute sections and delayed. of this material safety data sheet. Avoid leakage of No the Reactivity. Waste episodes product treatment into of damage environment. methods. - responsible GHS: Globally for the Harmonized Safety to Data health System Sheet Do ascribable not of classification eat, massi@reinol.it to drink the or product and smoke labeling have during been of use. chemicals reported. There Reuse, are when no particular possible. Neat risks of product reaction residues with other should substances be considered in normal special conditions non-hazardous of use. waste. - IATA DGR: International Air Transport Association Dangerous Goods Regulation Disposal Conditions Indication must of for be any safe performed immediate storage, through medical including an attention any authorised incompatibilities. and waste special management treatment needed. firm, in compliance with national and - IC50: Emergency Immobilization telephone Concentration number 50% Information Keep local Chemical regulations. - IMDG: the International product not stability. available. in Maritime clearly labelled Code for containers. dangerous goods Keep containers away from any incompatible materials, see CONTAMINATED The section product 10 for is details. stable PACKAGING - For IMO: urgent International inquiries Maritime refer in normal to Organization conditions +39 of use 011 and storage. SECTION Contaminated 5. Firefighting packaging measures. must be recovered or disposed of in compliance with national waste management - INDEX NUMBER: Identifier in Annex VI of CLP SECTION regulations. - LC50: Specific Possibility Lethal 2. end Hazards Concentration of use(s). hazardous identification. 50% reactions. No Information - LD50: hazardous Lethal not reactions dose available. 50% are foreseeable in normal conditions of use and storage SECTION - OEL: Extinguishing Classification Occupational 14. Transport of media. the Exposure substance information. Level mixture SECTION SUITABLE - PBT: Conditions Persistent 8. EXTINGUISHING Exposure to bioaccumulative avoid. controls/personal EQUIPMT and toxic as protection. Reach Regulation None - The PEC: product extinguishing Predicted particular. is is not not environmental classified However equipment dangerous the as should hazardous Concentration usual under precautions be current pursuant of the provisions used conventional to the for provisions chemical of the kind: Code products set carbon forth of International should in dioxide, Directives be foam, respected. 67/548/EEC Carriage powder of Dangerous and water spray. Goods /45/EC PEL: Predicted by Road and/or exposure (ADR) EC Regulation and level by Rail 1272/2008 (RID), of (CLP) the International (and subsequent Maritime amendments Dangerous and Goods supplements). Code (IMDG), and of UNSUITABLE the - PNEC: Control Incompatible International Predicted parameters. EXTINGUISHING Air materials. no Transport effect concentration Association EQUIPMT (IATA) regulations Information None - REACH: Label in particular. elements. EC not Regulation available. 1907/2006 SECTION - RID: Regulation 15. Regulatory concerning information. the international transport of dangerous goods by train This - TLV: Special Exposure Hazardous Threshold product hazards controls. decomposition is Limit arising not Value subject from products. the to hazard substance labeling or mixture. pursuant to Directives 67/548/EEC and 1999/45/EC and Information subsequent - HAZARDS TWA STEL: CAUSED not amendments Short-term available. BY EXPOSURE exposure and supplements. limit IN THE EVT OF FIRE Observance - Do TWA: Safety, not breathe Time-weighted health of safety combustion and measures average environmental products. exposure used in regulations/legislation handling limit chemical substances. specific for the substance or mixture. SECTION RESPIRATORY 11. Toxicological PROTECTION Seveso - VOC: category. Volatile organic Compounds information Warning None - vpvb: Advice required. Very symbols: for Persistent firefighters. and very Bioaccumulative as for REACH Regulation. Restrictions EYE According GERAL PROTECTION relating to INFORMATION currently to the product available or contained data, substances this pursuant product to Annex has XVII not to EC yet Regulation produced 1907/2006. health damages. Anyway, it must be Hazard None handled Use jets required. GERAL sentences according of BIBLIOGRAPHY water (R): to to good cool industrial the containers practices. to prevent product decomposition and the development of substances HAND 1. potentially Directive PROTECTION hazardous 1999/45/EC for and health. following Always amendments wear full fire prevention gear. Collect extinguishing water to prevent it Substances Caution None from Information draining required. Candidate into List on toxicological the (Art. sewer 59 REACH). 2. Directive recommendations 67/548/EEC and (S): following system. effects. amendments Dispose of and contaminated adjustments water used for extinction and the remains of the SKIN Information 3. fire Regulation according PROTECTION not (EC) to available. applicable 1907/2006 regulations. (REACH) of the European Parliament 2.3. None 4. SPECIAL Other Regulation required. hazards. PROTECTIVE (EC) 1272/2008 EQUIPMT (CLP) of FOR the European FIRE-FIGHTERS Parliament Substances subject to authorisarion (Annex XIV REACH). SECTION 5. Normal Regulation fire 12. fighting Ecological (EC) 790/2009 clothing information. (I i.e. Atp. fire CLP) kit of (BS the European 469), gloves Parliament (BS 659) and boots (HO specification A29 and SECTION Information 6. A30) Regulation in combination 9. not Physical (EC) available. 453/2010 with and chemical self-contained of the European properties. open Parliament circuit positive pressure compressed air breathing apparatus (BS Use 137). Substances 7. Regulation this subject product (EC) to exportation according 286/2011 reporting (II to Atp. pursuant good CLP) to working (EC) of the Reg. European practices. 689/2008: Parliament Avoid littering. Inform the competent authorities, should 9.1. Information on basic physical and chemical properties. Appearance the 8. The product Merck reach Index. waterways - 10th Edition or sewers or liquid contaminate soil or vegetation. Colour 9. Handling Chemical Safety Item Numbers: , EPY Page - SDS of 7

2 Page n. 2 / 7 Page 2 of 7 SECTION 3. Composition/information on ingredients Substances. Information not relevant Mixtures. The product does not contain substances classified as being hazardous to human health or the environment pursuant to the provisions set forth in Directives 67/548/EEC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). SECTION 4. First aid measures Description of first aid measures. No episodes of harm to the staff authorised to use the product have been reported. The following general measures should be adopted as necessary: INHALATION: Remove to open air. If the subject stops breathing, administer artificial respiration. Get medical advice/attention. INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Do not give anything by mouth to an unconscious person. EYES and SKIN: Wash with plenty of water. In the event of persistent irritation, get medical advice/attention Most important symptoms and effects, both acute and delayed. No episodes of damage to health ascribable to the product have been reported Indication of any immediate medical attention and special treatment needed. SECTION 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING EQUIPMT The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. UNSUITABLE EXTINGUISHING EQUIPMT None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do not breathe combustion products Advice for firefighters. GERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137). Item Numbers: , EPY Page - SDS of 7

3 Page n. 3 / 7 Page 3 of 7 SECTION 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in emergency procedures Environmental precautions. The product must not penetrate into the sewer system or come into contact with surface water or ground water Methods and material for containment and cleaning up. Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13. SECTION 7. Handling and storage Precautions for safe handling. Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use Conditions for safe storage, including any incompatibilities. Keep the product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details Specific end use(s). SECTION 8. Exposure controls/personal protection Control parameters Exposure controls. Observance of safety measures used in handling chemical substances. RESPIRATORY PROTECTION EYE PROTECTION HAND PROTECTION SKIN PROTECTION SECTION 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance Colour liquid Item Numbers: , EPY Page - SDS of 7

4 SECTION 9. Physical and chemical properties.... / >> Odour imperceptible Odour threshold. ph. Melting or freezing point. > 100 C. Initial boiling point. < -4 C. Boiling range. Flash point. > 100 C. Evaporation Rate Flammability of solids and gases Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Specific gravity. Solubility soluble in water Partition coefficient: n-octanol/water Ignition temperature. Decomposition temperature. Viscosity 3-5 cps Explosive properties Oxidising properties 9.2. Other information. VOC (Directive 1999/13/EC) : 10,00 % VOC (volatile carbon) : 4,73 % Page n. 4 / 7 Page 4 of 7 SECTION 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use Chemical stability. The product is stable in normal conditions of use and storage Possibility of hazardous reactions. No hazardous reactions are foreseeable in normal conditions of use and storage Conditions to avoid. None in particular. However the usual precautions used for chemical products should be respected Incompatible materials Hazardous decomposition products. SECTION 11. Toxicological information. According to currently available data, this product has not yet produced health damages. Anyway, it must be handled according to good industrial practices Information on toxicological effects. SECTION 12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation. Item Numbers: , EPY Page - SDS of 7

5 SECTION 12. Ecological information.... / >> Toxicity Persistence and degradability. Page n. 5 / 7 Page 5 of Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment. On the basis of available data, the product does not contain any PBT or vpvb in percentage greater than 0,1% Other adverse effects. SECTION 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. SECTION 14. Transport information. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. SECTION 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Substances in Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Substances subject to exportation reporting pursuant to (EC) Reg. 689/2008: Item Numbers: , EPY Page - SDS of 7

6 SECTION 15. Regulatory information.... / >> Substances subject to the Rotterdam Convention: Substances subject to the Stockholm Convention: Healthcare controls. Page n. 6 / 7 Page 6 of Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contains. SECTION 16. Other information. LEGD: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification and labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative and toxic as Reach Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent and very Bioaccumulative as for REACH Regulation. GERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and following amendments 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. Regulation (EC) 286/2011 (II Atp. CLP) of the European Parliament 8. The Merck Index. - 10th Edition 9. Handling Chemical Safety Item Numbers: , EPY Page - SDS of 7

7 SECTION 16. Other information.... / >> 10. Niosh - Registry of Toxic Effects of Chemical Substances 11. INRS - Fiche Toxicologique (toxicological sheet) 12. Patty - Industrial Hygiene and Toxicology 13. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 14. ECHA website Page n. 7 / 7 Page 7 of 7 Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. Item Numbers: , EPY Page - SDS of 7