SYSTERM SAFETY DATA SHEET

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1 SAFETY DATA SHEET 1. Identification of the substance/preparation and of the company/undertaking Product name: Name and address of Supplier: Silver nitrate Classic Chemicals Sdn Bhd 19, Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam, Selangor Emergency telephone no.: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard classes and hazard categories Oxidising solid, category 2 Skin corrosion, category 1B Hazardous to the aquatic environment, chronic, category 1 Hazard statements Signal word Danger Hazard Statements May intensify fire; oxidiser. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects. Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P309+P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. Labelling according to EC Directives: Hazard symbols: O, C, N

2 SAFETY DATA SHEET Product name: Silver nitrate R-phrases R8 Contact with combustible material may cause fire. R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrases S26 S36/37/39 S45 S60 S61 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. 3. Composition/information on ingredients Product name: Silver nitrate CAS-No.: Molar mass: Molecular formula: AgNO 3 EC No.: Index No.: Other means of identification: 4. First aid measures After inhalation: Remove from exposure, rest and keep warm. In severe cases, or if exposure has been great, obtain medical attention. After skin contact: Drench the skin thoroughly with water. Remove contaminated clothing and wash before re-use. Unless contact has been slight, obtain medical attention. After eye contact: Irrigate thoroughly with water for at least 10 minutes. Obtain medical attention. After ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. 5. Fire-fighting measures Suitable extinguishing media: Water spray Special risks: May ignite combustible material. May evolve toxic fumes in fire.

3 SAFETY DATA SHEET Product name: Silver nitrate 6. Accidental release measures Wear appropriate protective clothing. If local regulations permit, transfer spillage into containers of water, stir to dissolve or suspend and run to waste, diluting greatly with running water. Otherwise mix with wet sand, transfer to container and arrange removal by disposal company. As contact with any oxidant can render organic matter (paper, wood, textiles) dangerously combustible, wash area of spillage and contaminated clothing thoroughly with water. For large spillages liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillages. 7. Handling and storage Handling: Avoid generation of dusts. Change contaminated clothing. Application of skin-protective barrier cream recommended. Wash hands after working with substances. Do not empty into drains. Storage: Store at room temperature (+15 o C to +25 o C recommended). Keep well closed and protected from direct sunlight and moisture. Store away from combustible materials. 8. Exposure controls/personal protection As appropriate to the situation and the quantity handled. Engineering methods to control or prevent exposure are preferred. Methods could include process enclosure or mechanical ventilation. Respiratory protection: Dusts respirator required when dust generated. Ventilation: Eye protection: Glove protection: Other precautions: Extraction hood Goggles or face-shield Rubber or plastic Plastic apron, sleeves, boots if handling large quantities 9. Physical and chemical properties Form: solid Colour: colourless to white Odour: odourless ph value at 100 g/l H 2 O Melting temperature 212 o C Boiling temperature 444 o C Flash point not applicable Density (20 o C) 4.33 g/ml Solubility in water (20 o C) 2150 g/l

4 SAFETY DATA SHEET Product name: Silver nitrate 10. Stability and reactivity light-sensitive. Substances to be avoided nonmetals, organic substances, alkali hydroxides, acetylidene, acetylene, aidehydes, nitriles, ammonia/ alcohols, ammonium compounds, combustible substances, hydrazine and derivatives, carbides, organic nitro compounds, heat( decomposition), magnesium in powder form( with water), alcohols. Hazardous decomposition products nitrous gases. 11. Toxicological information The following applies to soluble silver compounds: only slightly absorbed via the gastrointestinal tract. Strong irritations after contact with eyes and skin. The following applies to practically insoluble silver compounds: long-term inhalation or ingestion can result in a persistent discoloration (grey to blue) of the skin and mucous membranes (argyria). Further data LD 50 : 50 mg/kg oral, mouse. No evidence of carcinogenic properties: Evidence of reproductive effects. 12. Ecological information] The following applies to silver compounds in general: biological effects: silver ions toxic for aquatic organisms; bacteria: Ps. putida toxic as from mg/l up; protozoa: U.parduczi toxic as from 0.1 mg/l up; arthropods: D. daphnia EC 50 : mg/l up; algae: M. aeruginosa toxic as from mg/l up; Sc. quadricauda toxic as from mg/l up. The following applies to nitrates in general: may contribute to the eutrophication of water supplies. Hazard for drinking water. Fish: LC 50 > 500 mg/l. 13. Disposal considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling.

5 SAFETY DATA SHEET Product name: Silver nitrate 14. Transport information Transport over land ADR/RID ADR/RID class: 5.1 Name of material: SILVER NITRATE Sea transport IMDG IMDG class: 5.1 UN-No.: 1493 Packaging group: II Correct technical name: SILVER NITRATE Air transport ICAO-TI and IATA-DGR ICAO/IATA class: 5.1 UN/ID-No.: 1493 Packaging group: II Correct technical name: SILVER NITRATE 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) 3 Chemical Safety Assessment No data available 16. Other information Relevant R-, H- and EUH-phrases (Number and full text) R8 Contact with combustible material may cause fire. R34 Causes burns. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May intensify fire; oxidiser. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects. Revision Date: 01 Jan 2016 The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product.

6 LEMBARAN DATA KESELAMATAN 1. Pengenalpastian bahan / sediaan dan syarikat / aku jangi Nama produk: Nama dan alamat pembekal: Argentum nitrat Classic Chemicals Sdn Bhd 19, Jalan Penerbit U1/43, Temasya Industrial Park, Shah Alam, Selangor telefon kecemasan no.: Pengenalan Bahaya Pengelasan bahan atau campuran Pengelasan menurut Peraturan (EC) No 1272/2008 [CLP] kelas bahaya dan kategori bahaya Pengoksidaan pepejal, kategori 2 Kakisan, kategori 1B Berbahaya kepada persekitaran akuatik, kronik, kategori 1 Penyataan bahaya Perkataan isyarat Penyata bahaya pernyataan langkah P210 P280 P273 P301 + P330 + P331 P304 + P340 P309 + P310 Bahaya Boleh memarakkan kebakaran; pengoksida. Boleh menyebabkan lecuran kulit dan kerosakan mata. Sangat toksik kepada hidupan akuatik dengan kesan berpanjangan. Jauhkan daripada haba / percikan api / nyalaan terbuka / permukaan panas. Dilarang merokok. Pakai sarung tangan pelindung / pakaian pelindung / perlindungan mata / muka. Elakkan daripada melepaskan ke persekitaran. JIKA TERTELAN: basuh mulut. Jangan paksa muntah. JIKA TERSEDUT: Pindahkan mangsa ke tempat udara segar dan biarkan berehat dalam kedudukan yang bernafas dengan selesa. JIKA terdedah atau jika anda merasa kurang sihat: Hubungi PUSAT RACUN atau doktor / pakar perubatan. Pelabelan menurut Arahan EC: Simbol Bahaya: O, C, N

7 LEMBARAN DATA KESELAMATAN Nama produk: Argentum nitrat Frasa-R R8 R34 R50 / 53 S Frasa S26 S36 / 37/39 S45 S60 S61 terkena bahan mudah terbakar boleh menyebabkan kebakaran. Menyebabkan luka terbakar. Sangat toksik kepada organisma akuatik, boleh menyebabkan kesan buruk jangka panjang Dalam persekitaran akuatik. Jika bersentuhan dengan mata, basuh segera dengan menggunakan air yang banyak dan Dapatkan nasihat perubatan. Pakailah pakaian perlindungan, sarung tangan dan perlindungan mata / muka. Dalam hal kemalangan atau jika anda merasa kurang sihat, dapatkan nasihat perubatan dengan segera (tunjukkan label jika perlu). Bahan ini dan bekasnya hendaklah dilupuskan sebagai bahan buangan berbahaya. Elakkan daripada melepaskan ke persekitaran. Rujuk arahan khas / lembaran data keselamatan. 3. Komposisi / maklumat bahan produk: Argentum nitrat CAS-No.: Molar: Formula molekul: AgNO 3 EC No.: Indeks No.: cara pengenalan lain: 4. Langkah-langkah pertolongan cemas Jika tersedut: jauhi dari pendedahan, rehat dan menyimpan panas. Dalam kes-kes yang teruk, atau jika pendedahan telah besar, dapatkan rawatan perubatan. Jika terkena kulit: membasahi kulit sehingga bersih dengan air. Tanggalkan pakaian yang tercemar dan basuh sebelum digunakan semula. Melainkan hubungan telah sedikit, dapatkan rawatan perubatan. Jika terkena mata: Mengairi sehingga bersih dengan air sekurang-kurangnya 10 minit. Dapatkan rawatan perubatan. Selepas pengambilan: Basuh mulut sehingga bersih dengan air dan beri banyak air untuk minum. Dapatkan rawatan perubatan. media pemadam 5. Langkah memadam kebakaran Media pemadam yang sesuai: Semburan air risiko Khas: Boleh menyalakan bahan mudah terbakar. Boleh berkembang wasap toksik dalam api.

8 LEMBARAN DATA KESELAMATAN Nama produk: Argentum nitrat 6. Langkah-langkah pengawalan pelepasan tidak sengaja Pakai pakaian perlindungan yang sesuai. Jika peraturan tempatan permit, memindahkan tumpahan ke dalam bekas air, kacau untuk membubarkan atau menggantung dan berjalan membuang, mencairkan sangat dengan air yang mengalir. Jika tidak bercampur dengan pasir basah, memindahkan ke dalam bekas dan mengatur penyingkiran oleh syarikat pelupusan. Seperti terkena sebarang oksida boleh menyebabkan bahan organik (kertas, kayu, tekstil) berbahaya yang mudah terbakar, basuh kawasan tumpahan dan pakaian yang tercemar dengan teliti menggunakan air. Untuk tumpahan besar cecair harus lengkap dengan pasir atau tanah dan kedua-dua cecair dan pepejal dipindahkan untuk menyelamatkan bekas. Apa-apa sisa harus dianggap sebagai untuk tumpahan kecil. 7. Pengendalian dan penyimpanan pengendalian: Elakkan penjanaan habuk. Menukar pakaian yang tercemar. Pemakaian krim halangan kulit pelindung disyorkan. Basuh tangan selepas bekerja dengan bahan. Jangan buang ke dalam longkang. Penyimpanan: Simpan pada suhu bilik (+ 15 o C ke + 25 o C disyorkan). Pastikan juga ditutup dan dilindungi daripada cahaya matahari langsung dan kelembapan. Simpan jauh dari bahan yang mudah terbakar. 8. Kawalan pendedahan / perlindungan diri Sebagaimana yang sesuai dengan keadaan dan kuantiti yang dikendalikan. Kejuruteraan kaedah untuk mengawal atau mengelakkan pendedahan diutamakan. Kaedah boleh termasuk proses tertutup atau pengudaraan mekanikal. Perlindungan Pernafasan: Ventilation: Perlindungan mata: Sarung tangan perlindungan: langkah berjaga-jaga lain: Habuk pernafasan diperlukan apabila habuk. hood Pengekstrakan Goggles atau perisai muka Getah atau plastik apron plastik, lengan, but - jika pengendalian kuantiti yang besar 9. Sifat-sifat fizikal dan kimia Bentuk: pepejal Warna: berwarna kepada putih Bau: tidak berbau Nilai ph pada 100 g / l H2O Suhu lebur 212 o C Suhu didih 444 oc Takat kilat tidak berkenana Ketumptana (20 o C) 4.33 g / ml Keterlarutan dalam air (20 o C) 2150 g / l

9 LEMBARAN DATA KESELAMATAN Nama produk: Argentum nitrat 10. Kestabilan dan kereaktifan cahaya sensitif. Bahan yang perlu dielakkan bukan logam, bahan-bahan organik, hidroksida alkali, acetylidene, asetilena, aidehydes, nitril, ammonia / alkohol, sebatian ammonium, bahan-bahan mudah terbakar, hidrazin dan derivatif, karbida, sebatian nitro organik, haba (penguraian), magnesium dalam bentuk serbuk (dengan air), alkohol. Produk penguraian yang berbahaya gas nitrus. 11. Maklumat toksikologi Berikut terpakai kepada sebatian perak larut: hanya sedikit diserap melalui saluran gastrousus. kegatalan kuat selepas terkena mata dan kulit. Berikut terpakai kepada sebatian perak dikatakan tidak larut: penyedutan jangka panjang atau pengambilan boleh menyebabkan perubahan warna yang berterusan (kelabu kepada biru) pada kulit dan membran mukus (argyria). Maklumat lanjut LD 50 data: 50 mg / kg lisan, tetikus. Tiada bukti sifat karsinogen: Bukti kesan pembiakan. 12. Maklumat ekologi Berikut terpakai kepada sebatian perak secara umum: Kesan biologi: ion perak toksik kepada organisma akuatik; bakteria: Mzm. putida toksik dari mg / l sehingga; protozoa: U.parduczi toksik daripada 0.1 mg / l sehingga; artropod: D. daphnia EC 50 : mg / l sehingga; alga: M. aeruginosa toksik dari mg / l sehingga; Sc. quadricauda toksik dari mg / l sehingga. Berikut terpakai kepada nitrat secara umum: boleh menyumbang kepada eutrofikasi bekalan air. Bahaya untuk air minuman. Ikan: LC50> 500 mg / l. 13. Maklumat pelupusan sisa kimia biasanya diklasifikasikan sebagai sisa khas, dan oleh itu adalah dilindungi oleh peraturanperaturan yang berbeza mengikut lokasi. Hubungi pihak berkuasa pelupusan sisa tempatan anda untuk mendapatkan nasihat, atau berpindah kepada syarikat pelupusan kimia. Berkumur bekas kosong teliti sebelum kembali untuk dikitar semula.

10 LEMBARAN DATA KESELAMATAN Nama produk: Argentum nitrat 14. Maklumat pengangkutan Pengangkutan ke atas jalan ADR / RID ADR / RID: 5.1 Nama bahan: Argentum nitrat Pengangkutan laut kelas IMDG IMDG: 5.1 UN.: 1493 Kumpulan pembungkusan: II Nama betul nama teknikal: Argentum nitrat Pengangkutan udara ICAO-TI dan IATA-DGR kelas ICAO / IATA: 5.1 UN / ID-No.: 1493 Kumpulan pembungkusan: II nama teknikal Betul: Argentum nitrat 15. Maklumat pengawalan Keselamatan, kesihatan dan peraturan alam sekitar / undang-undang khusus untuk bahan atau campuran Bahaya air kelas (WGK) 3 Data Keselamatan Kimia Penilaian Data tidak tersedia 16. Maklumat lain R- berkaitan, H- dan EUH-frasa (Bilangan dan teks penuh) R8 R34 R50 / 53 terkena bahan mudah terbakar boleh menyebabkan kebakaran. Menyebabkan luka terbakar. Sangat toksik kepada organisma akuatik, boleh menyebabkan kesan buruk jangka panjang Dalam persekitaran akuatik. Boleh memarakkan kebakaran; pengoksida. Boleh menyebabkan lecuran kulit dan kerosakan mata. Sangat toksik kepada hidupan akuatik dengan kesan berpanjangan. Tarikh Semakan: 1 Januari 2016 Maklumat yang terkandung dalam dokumen ini adalah berdasarkan pada keadaan pengetahuan semasa kami. Ia menyifatkan produk dengan mengambil kira langkah-langkah keselamatan yang sesuai. Ia tidak mewakili jaminan sifat-sifat produk.

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