Version: 5.1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 5.1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Primal WS 24 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: General varnishing Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: Safety designation: EUH208 May produce an allergic reaction. Hazardous components for labelling: Other Hazards 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Contains 1,2-Benzisothiazol-3(2H)-one: can cause allergic reactions. Chemical Characterization: Acrylic colloidal dispersion in water with small particle size. Mixture Acrylic latex Information on Components / Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air. Wash off with plenty of water and soap. Consult a physician if irritation persists. Rinse open eyes with plenty of water. In case of discomfort seek medical help After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Use extinguishing media for surrounding fire. Unsuitable extinguishing media: None known. 3

3 5. 2. Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Material can splatter above 100 C/212 F. Dried prod uct can burn. Wear self-contained respiratory protective device and protective clothing Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear protective clothing. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Caution: Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent, inert material (sand, earth) and dispose accordingly. Protective clothing, see Section 8. See Section 13 for information on disposal. Avoid contact with eyes, skin and clothing Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not inhale gas/fumes/vapours/aerosols. Wash thoroughly after handling. Storage conditions: Requirements for storage areas and containers: Protect from frost. Stir well before use. Keep from freezing; material may coagulate. Store between 1-49 C ( F). No special measures necessary. Information on fire and explosion protection: Monomer vapors may be evolved when material is heated during 4

4 processing operations. Page Storage class (VCI): Further Information: Specific End Use(s) Avoid acid conditions: formaldehyde is released. Provide adequate ventilation Further information: Exposure Controls/Personal Protection Parameters to be Controlled Further information for this product can be found in the technical data sheet. Parameters to be controlled (DE): Does not contain any components with workplace limit values. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Use local exhaust ventilation in case of dust and/or fume formation. Facilities storing or utilizing this material should be equipped with an eyewash facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: The usual precautionary measures are to be adhered to when handling chemicals. A respiratory protection program meeting OSHA and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator s use. Protective gloves Neoprene Safety glasses with protective shields (EN 166). Body protection: Environmental precautions: 9. Physical and Chemical Properties 5

5 9. 1. Information on Basic Physical and Chemical Properties Page 5 Form: Color: Odor: Odor threshold: liquid milky white ammoniacal ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information not available 100 C (H2O) not available < 1.00 H2O not available no information available no information available 2.266,4808 Pa (20 C H2O) < 1,0000 H2O (air=1) g/cm3 dilutable no information available Product is not auto-ignitable. No data available. 600,000 mpa.s max not available Solubility in solvents: 6

6 Viscosity, kinematic Page Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Percent volatility: % The product is chemically stable. No data available. There are no known products which are incompatible with this product. Thermal decomposition may yield acrylic monomers. > 5000 mg/kg (rat) > 5000 mg/kg (rabbit) Slight irritant effect possible. Non-irritating to eyes Ingestion: 7

7 No information available Page Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: By analogy with a product of similar composition. LC50: > 100 mg/l (96h, Oncorhynchus mykiss; OECD 203) EC50: > 100 ppm (48h, Daphnia magna; OECD 202) not determined EC50: 777 mg/l (72h, Selenastrum capricornutum; OECD 201) Not inherently biodegradable and not readily eliminable. Inhibition of respiration of the activated sludge: > 100 mg/l (no inhibitory effect; OECD 209) This substance is not classified as PBT (persistent, bioaccumulative, toxic), nor as vpvb (very persistent, very bioaccumulative). 1, slightly hazardous Further ecological effects: 8

8 AOX Value: 13. Disposal Considerations Waste Treatment Methods Page 8 Product: European Waste Code (EWC): Uncleaned packaging: Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer. Incinerate liquid and contaminated solids in accordance with local, state and federal regulations. Waste codes should be assigned by the user based on the application for which the product was used. Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: 9

9 Page Environmental Hazards Special Precautions for User Not classified as environmentally hazardous. Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water (German Regulation) Seveso II: does not apply Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. REACH: This mixture contains exclusively components which have been either pre-registered, are exempted from registration or must not be registered according to EC Regulation 1907/2006 (REACH). This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.