23380 Pigment Yellow 83
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1 Revised edition: Version: 3.2 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Pigment Yellow 83 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Pigment Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H319 Cat.: 2 Eye irritation, hazard category 2 Causes serious eye irritation. Classification according to Directive No. 67/548/EC or No. 1999/45/EC Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: GHS07-1 Signal word: Warning Hazard designation: H319 Causes serious eye irritation. 2
2 Safety designation: P280 P305+P351+P338 P337+P313 Page 2 Wear protective gloves/ clothing/ eye/ face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If eye irritation persists: Get medical advice/ attention Hazardous components for labelling: Other Hazards Dust can form an explosive mixture with air. Composition/Information on Ingredients Substance Mixture Chemical Characterization: C.I. Pigment Yellow 83 2,2 -[3,3 -Dichloro[1,1 -biphenyl]4,4 -diyl)bis(azo)]bis[n-(4-chloro- 2,5-di-methoxyphenyl)-3-oxobutyramide], CAS No , EINECS Information on Components / Hazardous Ingredients: N-[3-(Dimethylamino)propyl]-stearamid (H (M=1)) % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air. Consult physician if symptoms persist. Wash off with plenty of water and soap. If irritation continues consult a physician. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Do not induce vomiting. Symptoms: No further information available. Effects: Indication of any Immediate Medical Attention and special Treatment needed 3
3 Page Treatment: Treat symptomatically Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Use extinguishing media for surrounding fire. Foam, extinguishing powder, water spray jet. Carbon dioxide, water jet Special Hazards arising from the Substance or Mixture Special hazards: Formation of hazardous decomposition products at high temperatures, such as carbon oxides and fumes Advice for Firefighters Protective equipment: Further information: Wear self-contained respiratory protective device. Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Avoid formation of dust, wear protective clothing Environmental Precautions Environmental precautions: Do not discharge into drains, surface or ground water in concentrated form. Contact local authorities if product pollutes soil or vegetation Methods and Material for Containment and Cleaning Up Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Avoid dust formation. Moisten die spillage with water before mechanically removing it. Transfer to separate suitable containers for recovery or disposal. For information for safe handling see Section 7. See Section 13 for information on disposal. Instructions on safe handling: Provide adequate ventilation. The usual precautionary measures are to be adhered to when 4
4 handling chemicals. Page Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and well ventilated location. Store the product in the original container. Take measures to prevent electrostatic discharge. 11; Combustible solids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 TLV: 1.25 mg/m3 air-borne fraction (general dust limit) TLV: 10 mg/m3 inhalable fraction (general dust limit) Peak limit Category: 2 (II) Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Personal Protection General protective measures: Respiratory protection: Wash contaminated clothes before reuse. Wash hands before breaks and after work. Preventive skin protection. Wash hands and face at the end of work. Protective clothing recommended due to the coloring effects of the product. Wear protective mask, particle filter P2 or FFP2 or NIOSH N95 (for 5
5 Page 5 solid and liquid particles, EN 143, 149) if dust occurs. Hand protection: Protective glove material: Eye protection: Body protection: Chemical protective gloves (EN 374 (Europe), F739 (US)). The manufacturer s directions for use should be observed because of the great diversity of types. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Protective clothing, chemical resistant Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: powder yellow characteristic ph-value: 7-9 Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): not available Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: 1.5 g/cm3 6
6 Solubility in water: practically insoluble Page Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Dust can form explosive mixtures with air. No oxidizing properties. Stable if used according to specifications. Stable if used according to specifications. Dust can form explosive mixtures with air. Avoid formation of dust. None known. In case of fire: formation of carbon monoxide and carbon dioxide. 7
7 10.7. Further Information 11. Toxicological Information Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: No information available Causes serious eye irritation. No information available No data available. No data available. No data available. No data available. Aspiration hazard: No toxicity expected. Bacteria toxicity: 8
8 Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Page 8 The contents of the preparation do not comply with the criteria for the classification as PBT or vpvb. Water hazard class: 1, slightly hazardous Behaviour in sewage systems: Further ecological effects: Do not let product enter waterways or sewage system AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority Wastes from the manufacture, formulation, supply and use (MFSU) of coatings (paints, varnishes and vitreous enamels), sealants and printing inks. Empty contaminated packaging thoroughly. These may be recycled after appropriate cleaning Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. ADR Class: 9
9 Hazard no.: Page 9 Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Not classified as environmentally hazardous. Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation) Local regulations on chemical accidents: Employment restrictions: The employment restrictions for expectant and nursing mothers in accordance with the Maternity Protection Guideline (94/85/EEC) are to be observed. The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed. Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles, Registered no Technical instructions on air quality: Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. 10
10 Further Information Other Information Page 10 This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.
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