Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (United States, Canada). Material Safety Data Sheet 1. Product and company identification Product name Material uses Supplier/Manufacturer Validation date Responsible name In case of emergency 2. RR Rust Remover for Pavers and Slabs Hazards identification Rust Remover for pavers and slabs Use to takes out rust from pavers and slabs made of concrete. Techniseal 300, avenue Liberté Candiac, QC, Canada, J5R 6X1 Tel (514) Toll free Fax (450) /30/200 Atrion Regulatory Services, Inc. CANUTEC (613) Physical state Liquid. Odor Wintermint. OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Emergency overview DANGER! CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Do not breathe vapor or mist. Do not ingest. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. Potential acute health effects Inhalation Corrosive to the respiratory system. Ingestion May cause burns to mouth, throat and stomach. May be harmful if swallowed. Skin Corrosive to the skin. Causes burns. Eyes Corrosive to eyes. Causes burns. Potential chronic health effects Chronic effects Contains material that may cause target organ damage, based on animal data. Carcinogenicity No known significant effects or critical hazards. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Target organs Contains material which may cause damage to the following organs upper respiratory tract, skin, eye, lens or cornea. Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following respiratory tract irritation coughing Ingestion Adverse symptoms may include the following stomach pains Date of issue 09/30/200 Page 1/

2 2. Skin Eyes Hazards identification Medical conditions aggravated by overexposure See toxicological information (section 11) 3. Adverse symptoms may include the following pain or irritation redness blistering may occur Adverse symptoms may include the following pain watering redness Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Composition/information on ingredients Name United States CAS number % Phosphoric acid Canada Name CAS number % Phosphoric acid There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First aid measures Eye contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 20 minutes. Get medical attention immediately. Skin contact In case of contact, immediately flush skin with plenty of water for at least 20 minutes. Get medical attention immediately. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5. Fire-fighting measures Flammability of the product Not flammable. Extinguishing media Suitable Use water spray, dry chemical powder or carbon dioxide for extinction. Not suitable None known. Hazardous thermal Decomposition products may include the following materials decomposition products phosphorus oxides Date of issue 09/30/200 Page 2/

3 5. Fire-fighting measures Special protective equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section ). Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning up Small spill Large spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). The spilled material may be neutralized with sodium carbonate, sodium bicarbonate or sodium hydroxide. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note see section 1 for emergency contact information and section 13 for waste disposal. 7. Handling and storage Handling Storage Put on appropriate personal protective equipment (see section ). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from alkalis. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Separate from alkalis. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.. Exposure controls/personal protection Product name United States Exposure limits Phosphoric acid NIOSH REL (United States, 12/2001). STEL 3 mg/m³ 15 minute(s). TWA 1 mg/m³ 10 hour(s). OSHA PEL (United States, 11/2006). TWA 1 mg/m³ hour(s). ACGIH TLV (United States, 1/200). STEL 3 mg/m³ 15 minute(s). TWA 1 mg/m³ hour(s). Date of issue 09/30/200 Page 3/

4 . Exposure controls/personal protection Canada Product name Exposure limits Phosphoric acid CA Alberta Provincial (Canada, 10/2006). 15 min OEL 3 mg/m³ 15 minute(s). hrs OEL 1 mg/m³ hour(s). CA British Columbia Provincial (Canada, 7/2007). TWA 1 mg/m³ hour(s). STEL 3 mg/m³ 15 minute(s). CA Ontario Provincial (Canada, 3/2007). TWAEV 1 mg/m³ hour(s). STEV 3 mg/m³ 15 minute(s). CA Quebec Provincial (Canada, 12/2006). TWAEV 1 mg/m³ hour(s). STEV 3 mg/m³ 15 minute(s). Consult local authorities for acceptable exposure limits. Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures Hygiene measures Personal protection Eyes Skin Respiratory Hands Personal protective equipment (Pictograms) Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Face shield. Synthetic apron. Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Nitrile gloves. HMIS Code/Personal protective equipment Environmental exposure controls D Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Date of issue 09/30/200 Page 4/

5 9. Physical state Color Odor ph Physical and chemical properties Melting/freezing point Specific gravity Viscosity Solubility 10. Stability Liquid. Blue. Wintermint. Stability and reactivity Hazardous polymerization Conditions to avoid Materials to avoid Hazardous decomposition products C (12.2 F) 1.16 g/ml Dynamic 15.5 mpa s (15.5 cp) Miscible in water. Toxicological information The product is stable. Under normal conditions of storage and use, hazardous polymerization will not occur. Can react with certain metals, such as aluminum, to produce flammable hydrogen gas. Reactive or incompatible with the following materials oxidizing materialsstrong caustics, metals, cyanides, sulphides and sulphites. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Acute toxicity Product/ingredient name Species Dose Result Exposure Phosphoric acid Rabbit 2740 mg/kg LD50 Dermal - Rat 1.25 g/kg LD50 Oral - Rat 1530 mg/kg LD50 Oral - Inhalation Corrosive to the respiratory system. Ingestion May cause burns to mouth, throat and stomach. May be harmful if swallowed. Skin Corrosive to the skin. Causes burns. Eyes Corrosive to eyes. Causes burns. 12. Ecological information Environmental effects 13. Disposal considerations No known significant effects or critical hazards. Waste disposal The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7 HANDLING AND STORAGE and Section EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Date of issue 09/30/200 Page 5/

6 14. Transport information AERG 154 Regulatory information DOT Classification UN number UN105 Proper shipping name PHOSPHORIC ACID IN SOLUTION Classes PG* Label Additional information III - CORROSIVE TDG Classification UN105 PHOSPHORIC ACID IN SOLUTION III - IMDG Class UN105 PHOSPHORIC ACID III - IN SOLUTION IATA-DGR Class UN105 PHOSPHORIC ACID IN SOLUTION III - PG* Packing group 15. Regulatory information United States HCS Classification U.S. Federal regulations State regulations Corrosive material Target organ effects United States inventory (TSCA b) All components are listed or exempted. SARA 302/304/311/312 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/311/312 hazardous chemicals Phosphoric acid SARA 311/312 MSDS distribution - chemical inventory - hazard identification Phosphoric acid Immediate (acute) health hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 311 Phosphoric acid Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Connecticut Carcinogen Reporting None of the components are listed. Connecticut Hazardous Material Survey None of the components are listed. Florida substances None of the components are listed. Illinois Chemical Safety Act None of the components are listed. Illinois Toxic Substances Disclosure to Employee Act None of the components are listed. Louisiana Reporting None of the components are listed. Louisiana Spill None of the components are listed. Massachusetts Spill None of the components are listed. Massachusetts Substances The following components are listed Phosphoric acid Michigan Critical Material None of the components are listed. Minnesota Hazardous Substances None of the components are listed. New Jersey Hazardous Substances The following components are listed Phosphoric acid New Jersey Spill None of the components are listed. New Jersey Toxic Catastrophe Prevention Act None of the components are listed. New York Acutely Hazardous Substances The following components are listed Date of issue 09/30/200 Page 6/

7 15. Regulatory information Phosphoric acid New York Toxic Chemical Release Reporting None of the components are listed. Pennsylvania RTK Hazardous Substances The following components are listed Phosphoric acid Rhode Island Hazardous Substances None of the components are listed. California Prop. 65 Canada WHMIS (Canada) No products were found. Class E Corrosive material Canadian lists Canada inventory CEPA Toxic substances None of the components are listed. Canadian ARET None of the components are listed. Canadian NPRI None of the components are listed. Alberta Designated Substances None of the components are listed. Ontario Designated Substances None of the components are listed. Quebec Designated Substances None of the components are listed. All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. International regulations International lists This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). 16. Other information Label requirements CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. Hazardous Material Information System (U.S.A.) HAZARD RATINGS Health Fire hazard Physical Hazard Personal protection * D 4- Extreme 3- Serious 2- Moderate 1- Slight 0- Minimal See section for more detailed information on personal protection. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) Health Flammability Instability Special References ANSI Z400.1, MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/-64, 31 December 197. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Date of issue 09/30/200 Page 7/

8 16. Other information Date of issue 09/30/200 Version 1 Rust Remover for pavers and slabs Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 09/30/200 Page /