3.1. Substance Not applicable Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification

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1 Date of issue: 10/14/2013 Revision date: 02/19/2014 Supersedes: 10/14/2013 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Buffer Solution ph 3.00 Product code : LC Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS-US) No data available : None. SECTION 3: Composition/information on ingredients 3.1. Substance Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification Water (CAS No) Not classified Potassium Hydrogen Phthalate (CAS No) Eye Irrit. 2B, H320 Hydrochloric Acid, 37% w/w (CAS No) Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 3, H402 Formaldehyde, 37% w/w (CAS No) Flam. Liq. 3, H226 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Inhalation), H331 Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1A, H317 Carc. 1B, H350 Aquatic Acute 2, H401 02/19/2014 EN (English) Page 1

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : None Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Safety glasses. Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment Emergency procedures : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Incompatible products : Strong oxidizers. Incompatible materials : None known. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Do not eat, drink or smoke when using this product. 02/19/2014 EN (English) 2/8

3 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH Ceiling (mg/m³) 0.37 mg/m³ USA ACGIH ACGIH Ceiling (ppm) 0.3 ppm USA OSHA OSHA PEL (TWA) (ppm) 0.75 ppm USA OSHA OSHA PEL (STEL) (ppm) 2 ppm 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Respiratory protection Other information : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : Odourless. Odour threshold ph : 3 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 1 Solubility : Soluble in water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties :. Oxidising properties : None. Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity None. 02/19/2014 EN (English) 3/8

4 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions None Conditions to avoid Extremely high or low temperatures Incompatible materials Strong oxidizers Hazardous decomposition products Formaldehyde. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit LD50 oral rat LD50 oral rat LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity IARC group IARC group Reproductive toxicity Specific target organ toxicity (single exposure) 700 mg/kg 5010 mg/kg 3200 mg/kg 500 mg/kg mg/kg ph: 3 ph: Not classifiable 1 - Carcinogenic to humans Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fishes 1 EC50 Daphnia 1 LC50 fish mg/l (96 h; Gambusia affinis; Pure substance) < 56 mg/l (72 h; Daphnia magna; Pure substance) 862 mg/l (Leuciscus idus; Pure substance) 02/19/2014 EN (English) 4/8

5 TLM fish ppm (96 h; Gambusia affinis; Pure substance) LC50 fishes 1 41 mg/l (96 h; Brachydanio rerio; Pure substance) EC50 Daphnia mg/l (24 h; Daphnia magna; Pure substance) LC50 fish mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Pure substance) EC50 Daphnia 2 2 mg/l TLM fish ,96 h; Poecilia reticulata; Pure substance TLM fish ,Pisces; Pure substance TLM other aquatic organisms ,96 h Threshold limit algae mg/l (192 h; Scenedesmus quadricauda; Pure substance) Threshold limit algae mg/l (192 h; Microcystis aeruginosa; Solution <50%) Buffer Solution ph 3.00 Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. No (test)data on mobility of the components of the mixture available. Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) (5 day(s)) 0.60 Readily biodegradable in water. Biodegradability in soil: no data available. No (test)data on mobility of the components of the mixture available. Photodegradation in the air g O²/g substance 1.06 g O²/g substance g O²/g substance Bioaccumulative potential Buffer Solution ph 3.00 Bioaccumulative potential Log Pow 0.25 (QSAR) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Bioaccumulative potential Log Pow Bioaccumulative potential Bioaccumulation: not applicable. Bioaccumulative potential Mobility in soil Ecology - soil May be harmful to plant growth, blooming and fruit formation. 02/19/2014 EN (English) 5/8

6 Ecology - soil Other adverse effects Other information Toxic to flora. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information Other information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 5000 lb List of Lists) : SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 100 lb List of Lists) : SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard SARA Section Emission Reporting 0.1 % Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Buffer Solution ph 3.00 Uncontrolled product according to WHMIS classification criteria Listed on the Canadian DSL (Domestic Sustances List) inventory. Class E - Corrosive Material Listed on the Canadian DSL (Domestic Sustances List) inventory. Class D Division 2 Subdivision B - Toxic material causing other toxic effects 02/19/2014 EN (English) 6/8

7 Listed on the Canadian DSL (Domestic Sustances List) inventory. Class B Division 3 - Combustible Liquid Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects Class E - Corrosive Material Listed on the Canadian DSL (Domestic Sustances List) inventory. Uncontrolled product according to WHMIS classification criteria EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations Listed on the Canadian Ingredient Disclosure List Not listed on the Canadian Ingredient Disclosure List Listed on the Canadian Ingredient Disclosure List Not listed on the Canadian Ingredient Disclosure List US State regulations U.S. - California - U.S. - California - Proposition 65 - Proposition 65 - Carcinogens List Developmental Toxicity Yes Yes U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category Acute Tox. 4 (Oral) Acute toxicity (oral), Category Aquatic Acute 2 Hazardous to the aquatic environment AcuteHazard, Category Aquatic Acute 3 Hazardous to the aquatic environment AcuteHazard, Category Carc. 1B Carcinogenicity, Category 1B Eye Dam. 1 Serious eye damage/eye irritation, Category Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Flam. Liq. 3 Flammable liquids, Category Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1A Sensitisation Skin, category 1A 02/19/2014 EN (English) 7/8

8 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H320 Causes eye irritation H331 Toxic if inhaled H335 May cause respiratory irritation H350 May cause cancer H401 Toxic to aquatic life H402 Harmful to aquatic life NFPA health hazard NFPA fire hazard NFPA reactivity : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 0 Minimal Hazard - No significant risk to health : 0 Minimal Hazard : 0 Minimal Hazard : A SDS US (GHS HazCom 2012) Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 02/19/2014 EN (English) 8/8