: Potassium Iodate-Iodide, 0.1N (0.0167M)

Transcription

1 Date of issue: 09/24/2013 Revision date: 02/13/2018 Supersedes: 10/06/2015 Version: 1.2 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Potassium Iodate-Iodide, 0.1N (0.0167M) : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Hazardous to the aquatic environment - Acute Hazard Category 3 H402 Full text of H statements : see section 16 Harmful to aquatic life 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) : H402 - Harmful to aquatic life : P273 - Avoid release to the environment. P501 - Dispose of contents/container to comply with local, state and federal regulations : None. SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) Not classified Potassium Iodide (CAS-No.) Aquatic Acute 2, H401 Potassium Iodate (CAS-No.) Ox. Sol. 3, H272 Sodium Hydroxide (CAS-No.) Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 3, H402 02/13/2018 EN (English US) Page 1

2 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects (acute and delayed) Symptoms/effects 4.3. Immediate medical attention and special treatment, if necessary SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical : Not expected to present a significant hazard under anticipated conditions of normal use. : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Safety glasses. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products : Keep only in the original container in a cool, well ventilated place away from : incompatible materials, Heat sources, Direct sunlight. Keep container closed when not in use. : Strong acids. Strong reducing agents. 02/13/2018 EN (English US) 2/7

3 Incompatible materials : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (ppm) 0.01 ppm Inhalable fraction ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ (Sodium hydroxide; USA; Momentary value; TLV - Adopted Value) OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ IDLH US IDLH (mg/m³) 10 mg/m³ NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³ 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation Individual protection measures/personal protective equipment Personal protective equipment: Gloves. Safety glasses. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid. Color : Colorless Odor : None. Odor threshold ph Melting point Freezing point 02/13/2018 EN (English US) 3/7

4 Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density : 1 Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong reducing agents Hazardous decomposition products Iodine vapor. Carbon dioxide. Carbon monoxide. SECTION 11: Toxicological information Information on toxicological effects : Non flammable. : Soluble in water. :. Likely routes of exposure Acute toxicity : Skin and eye contact LD50 oral rat ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity mg/kg mg/kg body weight 1350 mg/kg body weight Reproductive toxicity Specific target organ toxicity single exposure 02/13/2018 EN (English US) 4/7

5 Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish mg/l 120 h 2.7 mg/l 24 h 45.4 mg/l (LC50; Other; 96 h; Salmo gairdneri; Static system; Fresh water; Experimental value) Potassium Iodate-Iodide, 0.1N (0.0167M) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biodegradability: not applicable. Biodegradability in soil: not applicable. Biodegradability: not applicable. No test data on mobility of the substance available Potassium Iodate-Iodide, 0.1N (0.0167M) Log Pow (Estimated value) Bioaccumulation: not applicable. No bioaccumulation data available Mobility in soil 02/13/2018 EN (English US) 5/7

6 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory SARA Section 311/312 Hazard Classes SARA Section 311/312 Hazard Classes RQ (Reportable quantity, section 304 of EPA's List of Lists) SARA Section 311/312 Hazard Classes Reactive hazard Immediate (acute) health hazard Delayed (chronic) health hazard 1000 lb Immediate (acute) health hazard International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations Not listed on the Canadian IDL (Ingredient Disclosure List) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm 02/13/2018 EN (English US) 6/7

7 SECTION 16: Other information Revision date : 02/13/2018 Other information Full text of H-phrases: see section 16: H272 H312 H314 H318 H401 H402 NFPA health hazard NFPA fire hazard NFPA reactivity : None. May intensify fire; oxidizer Harmful in contact with skin Causes severe skin burns and eye damage Causes serious eye damage Toxic to aquatic life Harmful to aquatic life : 1 - Materials that, under emergency conditions, can cause significant irritation. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 02/13/2018 EN (English US) 7/7