SAFETY DATA SHEET. Klercide 70/30 IPA

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Surface Disinfectant Restrictions on use : Reserved for industrial and professional use. Product dilution information : No dilution information provided. Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park, NSW Australia Emergency telephone number : , Issuing date : Section: 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 2 Serious eye damage/eye : Category 2A irritation Specific target organ toxicity - : Category 3 (Central Nervous System) single exposure GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Danger : Highly flammable liquid and vapour. Causes serious eye irritation. May cause drowsiness or dizziness. : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ eye protection/ face protection. Response: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in / 8

2 a well-ventilated place. Keep cool. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) propan-2-ol Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. Contact the Poison's Information Centre (eg Australia ; New Zealand ). If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. : Decomposition products may include the following materials: Carbon oxides : Use personal protective equipment. : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in / 8

3 Section: 6. ACCIDENTAL RELEASE MEASURES accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Wash hands thoroughly after handling. Open drum carefully as content may be under pressure. : Keep away from heat and sources of ignition. Keep in a cool, wellventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 0 C to 25 C Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Permissible concentration propan-2-ol TWA 400 ppm 983 mg/m3 VLE 500 ppm 1,230 mg/m3 Basis AU OEL AU OEL Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection : Safety goggles Face-shield : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of / 8

4 degradation or chemical breakthrough. Skin protection Respiratory protection Hygiene measures : No special protective equipment required. : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour : liquid : clear, colourless : alcohol-like ph : , 100 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 21 C closed cup : > 35 C Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble : The substance or mixture is not classified as oxidizing. Section: 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions : Stable under normal conditions. : No dangerous reaction known under conditions of normal use / 8

5 Conditions to avoid Incompatible materials Hazardous decomposition products : Heat, flames and sparks. : None known. : Decomposition products may include the following materials: Carbon oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes serious eye irritation. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. : Inhalation may cause central nervous system effects. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : No symptoms known or expected. : No symptoms known or expected. : Dizziness, Drowsiness Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure / 8

6 Aspiration toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity LD50 rat: 5,840 mg/kg 4 h LC50 rat: > 30 mg/l LD50 rabbit: 12,870 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : This product has no known ecotoxicological effects. 96 h LC50 Pimephales promelas (fathead minnow): 9,640 mg/l LC50 Daphnia magna (Water flea): > 10,000 mg/l Persistence and degradability Readily biodegradable. Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to / 8

7 Section: 14. TRANSPORT INFORMATION an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADG) UN number : 1219 Description of the goods : ISOPROPANOL Class : 3 Packing group : II Environmentally hazardous : No Air transport (IATA) UN number : 1219 Description of the goods : Isopropanol Class : 3 Packing group : II Environmentally hazardous : No Sea transport (IMDG/IMO) UN number : 1219 Description of the goods : ISOPROPANOL Class : 3 Packing group : II Marine pollutant : No Section: 15. REGULATORY INFORMATION National regulatory information Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Korea. Korean Existing Chemicals Inventory (KECI) : / 8

8 Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Taiwan Chemical Substance Inventory : Section: 16. OTHER INFORMATION Sources of key data used to compile the Safety Data Sheet Globally Harmonized System of Classification and Labelling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 8