S-CO 2 cycle design and control strategy for the SFR application

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1 S-CO 2 cycle design and control strategy for the SFR application Yoonhan Ahn, Min Seok Kim, Jeong Ik Lee Ph.D. candidate. Dept. of Nuclear & Quantum Engineering, KAIST minskim@kaist.ac.kr

2 S-CO 2 Power Cycle Development 1 Small Modular sized SFR design Name CEFR PFBR-500 PRISM 4S ARC-100 Thermal power class Small Medium Medium Small Small Efficiency, % Core outlet temperature, o C Developer CIAE IGCAR GE-Hitachi Toshiba Advanced Reactor Concepts Country China India U.S.A Japan U.S.A Power conversion system Steam Rankine S-CO 2 Brayton

3 S-CO 2 Power Cycle Development 2 S-CO 2 cycle for the SFR application The benefits of the S-CO 2 cycle: relatively high efficiency under the mild turbine inlet temperature condition simple layout and compact size Potentially enhanced the safety of the SFR system 20MWe Recompression SCO 2 PCS Layout [P. Hejzlar et al, MIT-2007] Thermal efficiencies of power conversion systems and applications Comparison of sodium reaction with water and CO 2 in a pipe [J. Eoh (2010)]

4 S-CO 2 Power Cycle Development 3 S-CO 2 cycle design flow chart Innovative Brayton Cycle for SFR application S-CO 2 Cycle Design Developed Under development Further study Design Phase Layout selection Component design Size estimation Off-design analysis S-CO 2 System Analysis Code Development Steady-state design code TM Design ns-ds 1-D design HX Design PCHE S-CO 2 Integral Experiment Loop Design Phase Layout selection Component design CO 2 Recovery System Design Development of Critical Flow Model Calculating the Leakage Rate in Turbo-machinery Quasi-state analysis code CO2 Critical Flow Code Implementation Transient state analysis Part load analysis Loss of External load Start-up and shutdown TM off-design performance System code implementation Performance Experiment Compressor test Simple cycle test Recuperation cycle test Recompression cycle test Optimization of CO2 Recovery System

5 S-CO 2 Power Cycle Development 4 S-CO 2 cycle design The KAIST-Closed Cycle Design (KAIST_CCD) code, an in-house code developed by KAIST research team is based on the MATLAB. Enthalpy and other fluid properties information for the code calculation is provided directly by the NIST reference fluid thermodynamic and transport properties database (REFPROP). S-CO 2 cycle condition for SFR application T-s diagram and sensitivity analysis through the KAIST_CCD * TB : turbine, MC : main compressor, RC : recompression compressor, IHX : intermediate heat exchanger, HTR : high temperature recuperator, LTR : low temperature recuperator

6 S-CO 2 Component Design 5 S-CO 2 cycle turbomachinery design Generally, in a large scale system, axial type turbomachineries are favored over other types. However, in the S-CO 2 cycle, radial type turbomachineries can be more appropriate even for the relatively large scale MW output system due to the high density and low pressure ratio cycle characteristics. -Operating characteristics between axial and radial turbomachinery (Gong et al., 2006) Radial Relatively constant flow, variable head Best suited for lower flow rate Higher pressure ratio applications Fewer or single stage Shorter axial length due to fewer stages Relatively wider operating range Lower efficiency by up to 4% in general compared to the axial machine - Turbomachinery Technology options for S-CO 2 cycle [Sienicki, J., 2011] Axial Relatively constant head, variable flow behavior Best suited for higher flow rate Moderate pressure ratio applications Commonly used with multi stage configurations Longer axial length due to multi stages Limited operating range Higher efficiency, especially if shrouded

7 S-CO 2 Component Design 6 Turbomachinery design code [ KAIST_TMD ] Total to Total Efficiency (%) Mass Flow Rate (kg/s) KAIST_TMD Turbomachinery Efficiency-Mdot Map On-design point rpm=3600 rpm=4500 rpm=5400 rpm=6300 rpm=7200 Ideal gas based correlations cannot be used for S-CO 2 Stagnation enthalpy 2 V h0 = hs + 2 Ratio of Specific Heats Ratio of Specific Heats 30 P=6 MPa P=8 MPa 25 P=10 MPa P=12 MPa P=14 MPa 20 P=16 MPa P=18 MPa P=20 MPa Temperature(K) 30 T=285.15K T=295.15K 25 T=305.15K T=315.15K T=325.15K Ideal gas correlations 2 V TC 0 P = TC s P To V γ 1 = 1+ = 1+ M T 2C T 2 s P o To = Ps Ts p γ γ 1 s γ 1 = 1+ M 2 2 γ 1 2 γ 0.03 Diffuser 5 (m) Shroud Pressure (MPa) Governing Equation ( Continuity equation + Euler equation ) m = ρ( h s,p s )AV h 02 h 01 = UU 2 WW www UU 1 WW ww1 Vane Shaft (m) x 10-3 Call from NIST property database Predicted off-design performance map (Sandia National Lab.)

8 S-CO 2 Component Design 7 Turbomachinery design code [ KAIST_TMD ] Code validation and verification (V&V) The Sandia National Laboratory (SNL) data are the only available compressor performance data on the S-CO 2 cycle research field so far. To validate KAIST_TMD, the compressor off design map from it compared with experimental data from SNL. KAIST_TMD has similar tendency in pressure ratio, whereas the efficiencies were predicted with some errors. It suggests that internal loss models based on air yield reasonable results with S-CO 2. Three external impeller loss models are considered such as recirculation, disk friction, and leakage. External losses are added only to the impeller exit stagnation enthalpy without any pressure change. It means external losses only affect efficiencies. Pressure Ratio SNL 45krpm SNL 50krpm SNL 55 krpm SNL 64 krpm TMD 45krpm TMD 50krpm TMD 55krpm TMD 64krpm Total to static effciency [%] SNL 45krpm SNL 50krpm SNL 55krpm SNL 64krpm TMD 45krpm TMD 50krpm TMD 55krpm TMD 64krpm SolidWorks schematic of the delivered split-flow recompression loop Corrected Massflow rate [kg/s] Corrected Massflow rate [kg/s] KAIST_TMD code validation with SNL data *Source: S.A. Wright. et al., Operation and Analysis of a S-CO 2 Brayton cycle, 2010

9 S-CO 2 Component Design 8 S-CO 2 cycle turbomachinery design Turbine Performance Impeller diameter: 0.95m Rotating speed: 7200rpm->3600rpm Main Compressor Performance Impeller diameter: 0.55m Rotating speed: 7200rpm->3600rpm Recompression compressor Performance Impeller diameter: 0.74m Rotating speed: 7200rpm->3600rpm

10 S-CO 2 Component Design 9 S-CO 2 cycle heat exchanger design Operating condition High pressure ( P min > 7.4 MPa) High temperature Temperature and pressure ranges [Tutorial : Heat exchangers for Supercritical CO 2 Power Cycle Applications, Turbo Expo 2014] Printed Circuit Heat Exchanger Highly compact & effective Excellent choice for gas heat exchanger Parallel core stacking - Enables to use on large systems [Heatric] [Heatric] Chemical etching Diffusion bonding Core stacking [Heatric]

11 S-CO 2 Component Design 10 Heat exchanger design code [ KAIST_HXD ] Heat exchanger design All heat exchanger is assumed to be the Printed Circuit Heat Exchanger (PCHE) type. KAIST-HXD(Heat Exchanger Design) in-house code is used. d c t t f P c Material : SUS 316 Material density = 8000 kg/m3 Material melting point = 1375~1400 C Channel diameter, dc = 1.8~2.2mm t(plate thickness) = 0.5 mm Pc(Channel pitch) = 2.2~2.6 mm, P c = d c +t f => t f = 0.4 mm Recuperator Effectiveness(%) : 95 Fig. PCHE configuration LL Fluid sodium helium CO 2 N 2 water Counter current flow type PCHE PCHE type heat exchanger scheme drawing Nu Correlation F correlation Applicable range, [N Re ] Nu 0.8 = Pe Nu = Re f = ( Re ) f = f Re Nu = Re Pr = Re Not limited ,500-33, reference Hejzlar et al., 2007 Kim, 2009 Ngo et al., 2007 Table. Heat exchanger design parameters of 75MWe S-CO 2 cycle Heat exchanger HTR LTR PC IHX Heat, MW Effectiveness, % Volume, m Geometry, m (L x W x H) 1.1 x 2.5 x x 2.5 x x 1.75 x x 2.1 x

12 S-CO 2 Component Design 11 Heat exchanger design code [ KAIST_HXD ] Code validation and verification (V&V) Developed KAIST_HXD can be used for : 1. Design optimization 2. Steady state performance analysis Lab-scale PCHE was designed with the design code and manufactured by a Korean manufacturer. Manufactured PCHE was installed to a KAIST S-CO 2 cycle experimental facility (S-CO 2 PE) and the performance test was conducted. Experimental data was accumulated for reliable design code validation View of the S-CO 2 PE facility & designed PCHE Designed Printed Experimental Circuit Heat data of Exchanger CO 2 side (PCHE)

13 S-CO 2 Pipe Design 12 Corrosion Vibration Determination of Pipe Diameter and Thickness for S-CO 2 Cycle Energy cost Pipe diameter Pressure loss Noise Total volume: 9.7m * 7.6m * 2.9m [75MWe] - T Flow Velocity VV = ff pppp /ρρ 0.3 by Ronald W. Capps(Chem. Eng ) VV : optimal flow velocity [mm/ss] ff pppp : pipe velocity factor [mm( kkkk mm 3)0.3 /ss] ρρ : density of flow [ kkkk mm 3] PIPE VELOCITY FACTORS Motive Energy Source m (kg/m 3 ) 0.3 /s Centrifugal Pump, Blower 14 Compressor Pipe dia<6in. Pipe dia>6in. Steam Boiler Conceptual design of S-CO 2 Recompression Cycle 3D Schematic S.C ~68 Minimum thickness tt mm = PPDD 0 2(SSSS+PPPP) + AA tt mm : minimum required wall thickness [m] P: internal design pressure [Pa] Do: outside diameter of pipe [m] S: maximum allowable stress [Pa] E: weld joint efficiency Y: coefficient A: additional thickness [m] Piping was selected in accordance with the ASME standard Nominal Pipe Size External Diameter (m) Velocity (m/s) Thickness(m) Material type Pressure drop (kpa) Nickel and High Nickel Alloys, N06600, B Low and Intermediate Alloy Steel, P91 A Nickel and High Nickel Alloys, N06600, B Low and Intermediate Alloy Steel, P91 A Nickel and High Nickel Alloys, N06600, B Total pressure drop uncluding minor loss (kpa)

14 CO 2 Recovery System Design 13 CO 2 Recovery System Design The suggested concept Conventional leak rate is assumed, which the conventional leak rate is less than 1kg/s per seal. To reduce the thermal efficiency loss with CO 2 recovery It is not only simple and intuitive but also has relatively very low additional WW cccccccc. It does not need additional compressor. Calculate the WW nnnnnn,llllllll MMMM ee Thermal efficiency loss caused by CO 2 inventory recovery system is 0.17 %. One loss was considered WW nnnnnn,llllllll Inventory total mass = CO 2 in Pipe + CO 2 in HX = ( ) kg = kg (It considers the HXs and Pipes) Loss due to the mm change of turbines and compressors WW nnnnnn,llllllll = WW nnnnnn,dddddddddddd WW nnnnnn,nnnnnn = WW nnnnnn,dddddddddddd (WW tttttttt,nnnnnn WW cccccccc,nnnnnn ) Preliminary design on CO 2 inventory recovery system of S-CO 2 power cycle for 75MWe SFR application Loss thermal efficiency (%) leak rate percent (%) Storage tank (Low-pressure tank) 66.2 ºC 7.6 MPa Leakage position (High-pressure tank) T (ºC) P (MPa) 1. TB inlet MC outlet RC outlet mm (kg/s) 1.0 Total mass flow rate 3.0

15 CO 2 Recovery System Design 14 CO 2 critical flow model Description of CO 2 critical flow model Initial P o, T o of CO 2 High Pressure CO 2 tank Low Pressure CO 2 tank Critical pressure ratio check Isentropic Critical Flow Model Mass/Energy balance m CO2 Mass balance Mach number check (choked or not) Mass flux calculation Design specifications for experimental system Changed P o, T o of CO Update 2 in each time step Governing equations GG = ρρvv eeeeeeeeeeeeee = cccccccccccccccc PP 0 = 1 + γγ 1 PP cccccccccccccccc 2 ( γ 1) / γ 2 P M = o 1 γ 1 P Po γ 1 G = γ M 1+ M RT 2 o γγ (γγ 1) γ + 1 2( γ 1) 2 Experimental Facility for CO 2 leak simulation High/Lowpressure tank Pipe connecting two tanks Heater (Jacket-type) Valve type Design Parameters Pressure (MPa) Temperature ( ) Volume (L) I.D.: 200mm H: 1,500mm I.D. (mm) 57 Length (mm) 1090 Electric capacity (kw) Ball valve 5

16 CO 2 Recovery System Design 15 CO 2 critical flow model Code validation and verification (V&V) KAIST research team conducted experiments with CO 2 critical flow simulation facility in turbine inlet and compressor outlet conditions. The mass flux calculated by using the measured values has similar trend with the result of CO 2 critical flow model in all cases. Mass flux (kg/m 2 -sec) [From high pressure tank] Exp_1 Exp_2 Exp_3 [From low pressure tank] Exp_1 Exp_2 Exp_3 Pressure (MPa) 12 High-pressure Tank (Legend 1 & 2) Low-presure Tank (Legend 1 & 2) High-pressure Tank (Legend 3) 10 Low-presure Tank (Legend 3) Mass flux (kg/m 2 -sec) Time (sec) Legend 1 (with uncertainty) Legend 2 Legend 3 Temperature ( C) Time (sec) High-pressure Tank (Legend 1 & 2) Low-presure Tank (Legend 1 & 2) High-pressure Tank (Legend 3) Low-presure Tank (Legend 3) Time (sec) Time (sec) CO 2 critical flow model validation with experimental data

17 S-CO 2 Cycle Control Strategy 16 Part load operation control strategy of S-CO 2 cycle Comparison of S-CO 2 cycle performance in part load conditions S-CO 2 cycle quasi-static analysis code algorithm Comparison of compressor surge margin in part load conditions

18 Conclusions and Future Work 17 Conclusions and Future Work Conclusions The S-CO 2 power conversion system is suitable for the small modular SFR application due to the safety, high efficiency, and small footprint. The S-CO 2 cycle design can be potentially applied with existing lab-scale experimental data. KAIST research team has accumulated many reliable data of main component s software and hardware for the S-CO 2 cycle design, but further code V&V should be performed for the complete power system design with control strategy. Future work Code V&V for turbomachinery and heat exchanger design codes will be further performed. The leakage flow and physical phenomena in the turbomachinery seal sections will be further studied in the future. To establish the most efficient strategy for the part load conditions, the potential of the valve and inventory controls will be further investigated. Real time simulation in various operation conditions will be conducted through the transient analysis code. For the safety analysis of Sodium leak scenario, study of Na-CO 2 reaction in heat exchanger will be performed.

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