MONITORING AND RESEARCH DEPARTMENT

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1 MONITORING AND RESEARCH DEPARTMENT REPORT NO HARLEM AVENUE SOLIDS MANAGEMENT AREA MONITORING REPORT FOR FOURTH QUARTER 2011 FEBRUARY 2012

2 Thomas C. Granato, Ph.D. Director of Monitoring and Research Department February 22, 2012 Mr. S. Alan Keller, P.E. Manager, Permit Section Illinois Environmental Protection Agency 1021 North Grand Avenue East P.O. Box Springfield, IL Dear Mr. Keller: Subject: Harlem Avenue Solids Management Area Stickney Water Reclamation Plant, Illinois Environmental Protection Agency Permit No AO , Monitoring Report for October, November, and December 2011 The attached five tables contain the monitoring data for the Harlem Avenue Solids Management Area for October, November, and December 2011 as required by Illinois Environmental Protection Agency (IEPA) Operating Permit No AO The data reported are as follows: Table 1, Analysis of Water from Lysimeters L-1N1 Through L-3N at the Harlem Avenue Solids Management Area Sampled on October 19, 2011 Table 2, Analysis of Monthly Composited Biosolids Placed in the Harlem Avenue Solids Management Drying Area During December 2011 Table 3, Analysis of Monthly Composited Processed Digested Biosolids Removed from the Harlem Avenue Solids Management Drying Area During October 2011 Table 4, Analysis of Monthly Composited Processed Digested Biosolids Removed from the Harlem Avenue Solids Management Drying Area During November 2011

3 Mr. S. Alan Keller 2 February 22, 2012 Subject: Harlem Avenue Solids Management Area Stickney Water Reclamation Plant, Illinois Environmental Protection Agency Permit No AO , Monitoring Report for October, November, and December 2011 Table 5, Analysis of Monthly Composited Processed Digested Biosolids Removed from the Harlem Avenue Solids Management Drying Area During December 2011 Biosolids were placed in the solids drying area during December and removed from the site during October, November, and December Very truly yours TCG:PL:cm Attachments cc w/att: R. Sulski, IEPA Records Unit, IEPA Thomas C. Granato, Ph.D. Director Monitoring and Research

4 TABLE 1: ANALYSIS OF WATER FROM LYSIMETERS L-1N1 THROUGH L-3N AT THE HARLEM AVENUE SOLIDS MANAGEMENT AREA SAMPLED ON OCTOBER 19, 2011 Lysimeter No. Parameter Unit L-1N1 L-2N L-3N ph 1 xxx,8.000 xxx,7.900 xxx,8.100 EC ms/m x, x, x, Total Dissolved Solids mg/l 1, , , Total Dissolved Organic Carbon xx, xxx,6.000 xx, Cl x, xx, x, SO 4 = xx, , x, TKN xxx,7.000 xxx,1.000 xxx,1.000 NH 3 -N xxx,6.000 x,< xxx,0.800 NO 2 + NO 3 -N xxx,0.120 xx, xxx,2.600 Total P x,< x,< xxx,0.660 Alkalinity as CaCO 3 x, x, , Al x,< x,< x,< Ca x, x, x, Cd x,< x,< x,< Cr x,< x,< x,< Cu x,< x,< x,< Fe xxx,0.500 x,< xx, Hg µg/l x,< x,< x,< K mg/l xxx,4.000 x,< x,< Mg x, x, x, Mn xxx,0.347 xxx,2.290 xxx,0.844 Na xx, xx, xx, Ni x,< xxx,0.011 x,< Pb x,< x,< x,< Zn x,< xxx,0.040 x,< phanalyzedbeyondrecommendedholdingtimeof15minutes.

5 TABLE 2: ANALYSIS OF MONTHLY COMPOSITED BIOSOLIDS PLACED IN THE HARLEM AVENUE SOLIDS MANAGEMENT DRYING AREA DURING DECEMBER 2011 Parameter Unit Concentration 1 ph xxxxx,8.100 Total Solids x % xxxx, Total Volatile Solids 2 xxxx, Valuesarethemeansofsixsamples. 2 Totalvolatilesolidsasapercentageoftotalsolids.

6 TABLE 3: ANALYSIS OF MONTHLY COMPOSITED PROCESSED DIGESTED BIOSOLIDS REMOVED FROM THE HARLEM AVENUE SOLIDS MANAGEMENT DRYING AREA DURING OCTOBER 2011 Parameter Unit Concentration 1 ph xxxxx,6.400 Total Solids x % xxxx, Total Volatile Solids 2 xxxx, TKN mg/kg x23, NH 3 -N xx2, Total P x25, Al x19, As xx,< Ca x41, Cd xxxxx,4.000 Cr xxx, Cu xxx, Fe x17, Hg xxxxx,1.100 K xx2, Mg x20, Mn xxx, Mo xxxxx,9.000 Na xx1, Ni xxxx, Pb xxx, Se xxx,< Zn xxx, Valuesarethemeansofthreesamples. 2 Totalvolatilesolidsasapercentageoftotalsolids.

7 TABLE 4: ANALYSIS OF MONTHLY COMPOSITED PROCESSED DIGESTED BIOSOLIDS REMOVED FROM THE HARLEM AVENUE SOLIDS MANAGEMENT DRYING AREA DURING NOVEMBER 2011 Parameter Unit Concentration 1 ph xxxxx,6.500 Total Solids x % xxxx, Total Volatile Solids 2 xxxx, TKN mg/kg x25, NH 3 -N xx2, Total P x26, Al x21, As xx,< Ca x42, Cd xxxxx,4.000 Cr xxx, Cu xxx, Fe x18, Hg xxxxx,0.900 K xx3, Mg x19, Mn xxx, Mo xxxx, Na xx1, Ni xxxx, Pb xxx, Se xxx,< Zn xxx, Valuesarethemeansoffoursamples. 2 Totalvolatilesolidsasapercentageoftotalsolids.

8 TABLE 5: ANALYSIS OF MONTHLY COMPOSITED PROCESSED DIGESTED BIOSOLIDS REMOVED FROM THE HARLEM AVENUE SOLIDS MANAGEMENT DRYING AREA DURING DECEMBER 2011 Parameter Unit Concentration 1 ph xxxxx,7.200 Total Solids x % xxxx, Total Volatile Solids 2 xxxx, TKN mg/kg x32, NH 3 -N xx4, Total P x28, Al x20, As xx,< Ca x39, Cd xxxxx,3.000 Cr xxx, Cu xxx, Fe x17, Hg xxxxx,0.860 K xx3, Mg x19, Mn xxx, Mo xxxxx,9.000 Na xxx, Ni xxxx, Pb xxx, Se xxx,< Zn xxx, Valuesareforonesample. 2 Totalvolatilesolidsasapercentageoftotalsolids.

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