152 Kennedy Road South Brampton, Ontario Canada L6W 3G4. General Inquiry Number: (905) Material Safety Data Sheet Attached
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1 152 Kennedy Road South Brampton, Ontario Canada L6W 3G4 General Inquiry Number: (905) Material Safety Data Sheet Attached
2 Page: 1/7 Material Safety Data Sheet MSDS# can Section 1. Product and Company Identification Product name WITCONATE 708 Material Uses Supplier/ Manufacturer : Surfactant. AKZO NOBEL SURFACE CHEMISTRY LLC 525 West Van Buren Chicago, IL AKZO NOBEL CHEMICALS LTD. 1 City Centre Drive, Suite 318 Mississauga, Ontario L5B 1M2 Canada In Case of Emergency CHEMTREC: CANUTEC: Medical/Handling: Product/Technical: This product is distributed by Canada Colors and Chemicals Limited General Inquiry Phone Number: (905) Hour Emergency Phone Number (416) WITCONATE 708 CCC Product Code: CCC Product Name: Section 2. Hazards Identification Physical State Color Odor Emergency Overview Liquid. Brown. Aromatic. WARNING! CAUSES EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: BLOOD, KIDNEYS, LIVER, RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM, EYE, LENS OR CORNEA. CONTAINS NAPHTHALENEA MATERIAL WHICH MAY CAUSE CANCER. FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. MAY BE HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE RESPIRATORY TRACT IRRITATION. HARMFUL TO AQUATIC ORGANISMS. MAY BE HARMFUL TO ENVIRONMENT IF RELEASED IN LARGE AMOUNTS. Keep away from heat, sparks and flame. Avoid contact with eyes, skin and clothing. Do not ingest. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact of spilled material and runoff with soil and surface waterways. Routes of Entry Absorbed through skin. Dermal contact. Eye contact. See Toxicological Information (section 11) Section 3. Composition/ Information on Ingredients Name CAS # % by Weight naphthalenesulfonic acid, bis(1methylethyl), compd. with cyclohexanamine (1:1) diisopropylnaphthalene water propylene glycol solvent naphtha (petroleum), heavy arom ,2,4trimethylbenzene <1.5 Naphthalene <1.5
3 WITCONATE 708 Page: 2/7 Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Medical Conditions Aggravated by Overexposure Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Cold water may be used. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminated clothing and shoes. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section 5. Fire Fighting Measures Flammability of the Product Autoignition Temperature Flash Points Flammable Limits Products of Combustion Fire Fighting Media and Instructions Protective Clothing (Fire) Flammable. The lowest known value is C (700 F) (propylene glycol). Closed cup: 60 C (140 F). (PenskyMartens.) The greatest known range is LOWER: 2.6% UPPER: 12.5% (propylene glycol) These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...). SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure buildup, autoignition or explosion. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other noncombustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Section 7. Handling and Storage Handling Storage Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Use explosionproof electrical (ventilating, lighting and material handling) equipment. Store in a segregated and approved area. Keep container in a cool, wellventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
4 WITCONATE 708 Page: 3/7 Section 8. Exposure Controls/ Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are proximal to the workstation location. Personal Protection Eyes Body Respiratory Hands Feet Protective Clothing (Pictograms) Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. respirator when ventilation is inadequate. Gloves. Suitable protective footwear. Wear appropriate Personal Protection in Case of a Large Spill Splash goggles. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Boots. Gloves. A selfcontained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Ingredient Name Exposure Limits United States Exposure Limits Canada naphthalenesulfonic acid, Not available. Not available. bis(1methylethyl), compd. with cyclohexanamine (1:1) diisopropylnaphthalene Not available. Not available. water Not available. Not available. propylene glycol AIHA WEEL (United States, 2005). Notes: Not available Revised Document TWA: 10 mg/m 3 8 Form: All forms solvent naphtha (petroleum), heavy arom. Not available. Not available. 1,2,4trimethylbenzene ACGIH TLV (United States, 2006). Not available. TWA: 123 mg/m times per shift, 8 TWA: 25 ppm times per shift, 8 NIOSH REL (United States, 2001). TWA: 125 mg/m times per shift, 10 TWA: 25 ppm times per shift, 10 OSHA PEL 1989 (United States, 1989). TWA: 125 mg/m times per shift, 8 TWA: 25 ppm times per shift, 8 Naphthalene ACGIH TLV (United States, 2006). Notes: Not available Adoption Refers to Appendix A Carcinogens. STEL: 79 mg/m 3 15 minute(s). STEL: 15 ppm 15 minute(s). TWA: 52 mg/m 3 8 TWA: 10 ppm 8 NIOSH REL (United States, 2001). STEL: 75 mg/m 3 15 minute(s). STEL: 15 ppm 15 minute(s). TWA: 50 mg/m 3 10 TWA: 10 ppm 10 OSHA PEL (United States, 1997).
5 WITCONATE 708 Page: 4/7 TWA: 50 mg/m 3 8 TWA: 10 ppm 8 OSHA PEL 1989 (United States, 1989). STEL: 75 mg/m 3 15 minute(s). STEL: 15 ppm 15 minute(s). TWA: 50 mg/m 3 8 TWA: 10 ppm 8 Section 9. Physical and Chemical Properties Physical State Color Odor ph Boiling/Condensation Point Melting/Freezing Point Density Vapor Pressure Vapor Density Solubility Dispersion Properties Liquid. Brown. Aromatic. 5 to 7 [Acidic.] Not determined. Not determined g/cm 3 (25 C / 77 F) Not determined. Not determined. Soluble in cold water. See solubility in water. Section 10. Stability and Reactivity Stability and Reactivity Incompatibility with Various Substances Hazardous Polymerization The product is stable. Slightly reactive to reactive with OXIDIZING AGENTS, REDUCING AGENTS, acids. Will not occur. Section 11. Toxicological Information Toxicity to Animals Ingredient Name or Product name diisopropylnaphthalene propylene glycol solvent naphtha (petroleum), heavy arom. 1,2,4trimethylbenzene Naphthalene Test Result Route Species LDLo LC50 LC50 LDLo LDLo 3400 mg/kg >4500 mg/kg mg/kg >2080 mg/kg mg/kg mg/kg mg/kg >2000 mg/kg >2000 mg/kg >580 ppm (4 hour(s)) 6900 mg/kg mg/m 3 (4 hour(s)) 490 mg/kg 533 mg/kg 1200 mg/kg >2500 mg/kg 100 mg/kg 400 mg/kg Dermal Dermal Dermal Inhalation Inhalation Dermal Mouse quail Guinea pig Mouse Mouse Guinea pig child Dog Special Remarks on Toxicity to Animals Harmful effects are not expected from short periods of contact.
6 WITCONATE 708 Page: 5/7 Chronic Effects on Humans Acute Effects Skin Acute Effects Eyes CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH [propylene glycol]. Classified None. by NIOSH [1,2,4trimethylbenzene]. Classified 2B (Possible for human.) by IARC [Naphthalene]. Classified 2 (Reasonably Anticipated To Be Human Carcinogens.) by NTP [Naphthalene]. Classified None. by NIOSH [Naphthalene]. Classified A4 (Not classifiable for human or animal.) by ACGIH [Naphthalene]. MUTAGENIC EFFECTS: Nonmutagenic for bacteria and/or yeast. [propylene glycol]. Nonmutagenic for bacteria and/or yeast. [solvent naphtha (petroleum), heavy arom.]. Contains material which causes damage to the following organs: blood, kidneys, liver, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Severely irritating to the skin. Practically nontoxic in contact with skin. Severely irritating to the eyes. Special Remarks on Other Toxic Effects on Humans Section 12. Ecological Information : Ecotoxicity Ingredient Name or Product name Species Period Result diisopropylnaphthalene Fish (LC50) 96 hour(s) 0.5 mg/l Daphnia (EC50) 48 hour(s) 0.16 mg/l propylene glycol Daphnia magna (EC50) 48 hour(s) >10000 mg/l Pimephales promelas (LC50) 96 hour(s) 710 mg/l Pimephales promelas (LC50) 96 hour(s) mg/l Pimephales promelas (LC50) 96 hour(s) >62000 mg/l 1,2,4trimethylbenzene Pimephales promelas (LC50) 96 hour(s) 7.72 mg/l Naphthalene Daphnia magna (EC50) 48 hour(s) 1.6 mg/l Daphnia magna (EC50) 48 hour(s) mg/l Daphnia magna (EC50) 48 hour(s) 2.55 mg/l Daphnia pulex (LC50) 96 hour(s) 1 mg/l Oncorhynchus mykiss (LC50) 96 hour(s) 1.6 mg/l Oncorhynchus mykiss (LC50) 96 hour(s) 1.8 mg/l Biodegradability and Ecotoxicity Remarks This product is expected to be moderately toxic to aquatic organisms. Products of Degradation These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...). Section 13. Disposal Considerations Waste Information Section 14. Transport Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. Regulatory Information UN number Proper shipping name Class Packing Group Label Additional information DOT Classification NA 1993 Combustible liquid, n.o.s. (Petroleum solvent). Marine pollutant (diisopropylnaphthalene) Combustible liquid. III Marine pollutant Marine pollutant (P) Remarks Not regulated by ground or rail if shipped or transported in containers less than 450 liters.
7 WITCONATE 708 Page: 6/7 TDG Classification UN 1268 PETROLEUM DISTILLATES, N.O.S. 3 III 3 IMDG Class 1268 PETROLEUM 3 III Marine pollutant DISTILLATES, Marine pollutant (P) N.O.S.Marine pollutant 3 (diisopropylnaphthalene) IATADGR Class 1268 PETROLEUM DISTILLATES, N.O.S. 3 III 3 Section 15. Regulatory Information U.S. Federal Regulations WHMIS (Canada) European Union Other International Lists TSCA: All intentionally present components are listed on the TSCA inventory. DSL: All intentionally present components are listed on the DSL. Class B3: Combustible liquid with a flash point between 37.8 C (100 F) and 93.3 C (200 F). Class D1B: Material causing immediate and serious toxic effects (TOXIC). Class D2A: Material causing other toxic effects (VERY TOXIC). Class D2B: Material causing other toxic effects (TOXIC). CEPA DSL: naphthalenesulfonic acid, bis(1methylethyl), compd. with cyclohexanamine (1:1); diisopropylnaphthalene; water; propylene glycol; solvent naphtha (petroleum), heavy arom.; 1,2,4trimethylbenzene; Naphthalene Component EC Number EC Status EC Annex naphthalenesulfonic acid, Not available. Not available. bis(1methylethyl), compd. with cyclohexanamine (1:1) diisopropylnaphthalene Not available. Not available. water Not available. Not available. propylene glycol Not available. Not available. solvent naphtha (petroleum), heavy Not available arom. 1,2,4trimethylbenzene Not available Naphthalene Not available. Not available. Australia (NICNAS): naphthalenesulfonic acid, bis(1methylethyl), compd. with cyclohexanamine (1:1); diisopropylnaphthalene; water; propylene glycol; solvent naphtha (petroleum), heavy arom.; 1,2,4trimethylbenzene; Naphthalene China: naphthalenesulfonic acid, bis(1methylethyl), compd. with cyclohexanamine (1:1); diisopropylnaphthalene; water; propylene glycol; solvent naphtha (petroleum), heavy arom.; 1,2,4trimethylbenzene; Naphthalene Germany water class: diisopropylnaphthalene; propylene glycol; solvent naphtha (petroleum), heavy arom. Japan (MITI): diisopropylnaphthalene; water; propylene glycol; 1,2,4trimethylbenzene; Naphthalene Japan (MOL): propylene glycol Korea (TCCL): diisopropylnaphthalene; water; propylene glycol; solvent naphtha (petroleum), heavy arom.; 1,2,4trimethylbenzene; Naphthalene
8 WITCONATE 708 Page: 7/7 Section 16. Other Information Philippines (RA6969): diisopropylnaphthalene; water; propylene glycol; solvent naphtha (petroleum), heavy arom.; 1,2,4trimethylbenzene; Naphthalene Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection 2 National Fire 2 Protection 2 0 Association Health 2 0 (U.S.A.) Fire Hazard Reactivity Specific Hazard Other Information Witconate is a trademark of Akzo Nobel or affiliated companies. Validation Date 11/16/2009. Previous Validation Date No Previous Validation. Validated by Product Safety Specialist Print Date 11/18/2009. Phone Number Notice to Reader The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency of such information and/or suggestions or as to the product s merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the date on this document is more than three years old, call to make certain that this sheet is current.
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