SAFETY DATA SHEET. Restrictions on use : Reserved for industrial and professional use. : Not flammable or combustible.
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1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Bleach Restrictions on use : Reserved for industrial and professional use. Product dilution information :. % -.14 % Company : Ecolab Co. 515 Tomken Road Mississauga, Ontario Canada L4W 2X Emergency telephone number : (US/Canada), (outside US) Issuing date : 3/17/214 Section: 2. HAZARDS IDENTIFICATION Physical and chemical hazards : Not flammable or combustible. Potential Health Effects Eyes Skin Chronic Exposure Physical and chemical hazards : Causes serious eye damage. : Causes severe skin burns. : Causes digestive tract burns. : May cause nose, throat, and lung irritation. : Not flammable or combustible. Potential Health Effects Eyes Skin Chronic Exposure Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS / 1
2 Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) sodium hypochlorite No hazardous ingredients Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. See toxicological information (Section 11) Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting. Hazardous combustion products : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Carbon oxides / 1
3 Special protective equipment for firefighters Specific extinguishing methods Risk of explosion. : Use personal protective equipment : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. Mixing this product with acid or ammonia releases chlorine gas. : Keep in a cool, well-ventilated place. Do not store near acids. Keep away from reducing agents. Keep away from combustible material. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : -15 C to 4 C / 1
4 Advice on safe handling Conditions for safe storage : Wash hands thoroughly after handling. Use only with adequate ventilation. : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Permissible concentration Basis chlorine TWA.5 ppm CAD AB OEL 1.5 mg/m3 STEL 1 ppm CAD AB OEL 2.9 mg/m3 TWA.5 ppm CAD BC OEL STEL 1 ppm CAD BC OEL STEV 1 ppm OEL (QUE) 2.9 mg/m3 VME.5 ppm OEL (QUE) 1.5 mg/m3 chlorine TWA.5 ppm ACGIH STEL 1 ppm ACGIH Ceiling.5 ppm NIOSH REL 1.45 mg/m3 C 1 ppm 3 mg/m3 OSHA Z1 Contains no substances with occupational exposure limit values. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : Safety goggles Face-shield : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard / 1
5 Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : light yellow Colourless Odour : Chlorine Chlorine ph : 12.5, 1 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : Not applicable. Section: 1. STABILITY AND REACTIVITY / 1
6 Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : Mixing this product with acid or ammonia releases chlorine gas. : None known. : Acids Metals : Carbon oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure :, Eye contact, Skin contact Potential Health Effects Eyes Skin Chronic Exposure Eyes Skin Chronic Exposure : Causes serious eye damage. : Causes severe skin burns. : Causes digestive tract burns. : May cause nose, throat, and lung irritation. Experience with human exposure Eye contact Skin contact Eye contact Skin contact : Redness, Pain, Corrosion : Redness, Pain, Corrosion : Corrosion, Abdominal pain : Respiratory irritation, Cough : No symptoms known or expected : No symptoms known or expected / 1
7 : No symptoms known or expected : No symptoms known or expected Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute oral toxicity Components Acute inhalation toxicity Components Acute dermal toxicity : sodium hypochlorite LD5 rat: 5,23 mg/kg : sodium hypochlorite 1 h LC5 rat: > 1,5 mg/l : sodium hypochlorite LD5 rabbit: > 1, mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae : Toxic to aquatic life. : 96 h LC5 Oncorhynchus mykiss (rainbow trout) : 2.1 mg/l 96 h LC5 Inland Silverside : 7.6 mg/l : 48 h LC5 Americamysis bahia : 18.1 mg/l 48 h LC5 Daphnia dubia :.57 mg/l / 1
8 Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) UN number : 1791 Description of the goods : HYPOCHLORITE SOLUTION Class : 8 Packing group : III Environmentally hazardous : No Sea Transport (IMDG/IMO) UN number : 1791 Description of the goods : HYPOCHLORITE SOLUTION Class : 8 Packing group : III Marine pollutant : Yes / 1
9 Not intended for transport. Section: 15. REGULATORY INFORMATION WHMIS Classification : E Corrosive Material WHMIS Classification : Not regulated under WHMIS. This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. The components of this product are reported in the following inventories: 197/26 (EU) : not determined Switzerland. New notified substances and declared preparations : Switzerland. Federal Health Agency, Giftliste 1 (Stoffe) On the inventory, or in compliance with the inventory United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Section: 16. OTHER INFORMATION / 1
10 Health Health Instability Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: HEALTH 3 3 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 3/17/214 Version : 1. Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 1
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