Revision Number: Issue date: 05/27/ PRODUCT AND COMPANY IDENTIFICATION. IDH number HAZARDS IDENTIFICATION 1

Transcription

1 Material Safety Data Sheet Henkel Revision Number: Issue date: 05/27/2009 Product name: Product type: Company address: Henkel Corporation Stephenson Highway Madison Heights, Ml Physical state Color: Odor: 1. PRODUCT AND COMPANY IDENTIFICATION ALODINE 22 TONER Coating Liquid Colorless Mild DANGER -- CORROSIVE!: CAUSES EYE United States Region: Contact fnfonnation: Telephone: For Chemical Emergency: Call CHEMTREC at Internet: 2. HAZARDS IDENTIFICATION 1 EMERGENCY OVERVIEW HMIS: HEALTH: FLAMMABILITY: PHYSICAL HAZARD: Personal Protection: *3 0 1 See MSDS Section 8 1 SKIN AND RESPIRATORY TRACT BURNS. 1 Relevant routes of exposure: Skin, Inhalation, Eyeb Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Mists, vapors or liquid may cause severe irhtation or burns. Corrosive to the skin. Contact with the skin or mucous membranes may cause severe irritation and burns. This product is severely irritating to the eyes and may cause irreversible damage including bums and blindness. This product may produce (X)rrosive damage to the gastrointestinal tract if it is swallowed. Eye, skin and respiratory disorders. Preexisting cardiovascular or bone marraw diseases. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicologicai Information. 3. COMPOSITION / INFORMATION ON INGREDIEMJi&afe.. Hazartlous components CAS NUMBER FIRST AID MEASURES % Inhalation: Skin contact: Eye contact: If Inhaled, Immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Remove contaminated clothing and foot^)^«ar. For skin contact, flush with large amounts of water. Seek immediate medical attention. In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. IDH number Page 1 of 5

2 ingestion: tes to physician: Get immediate medical attention. Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. If cyanosis is severe, intravenous injection of methylene blue, 1 mg^g body weight, may be of value. SrrFlRHGHTING MEASURES Flash point: Autoignition temperature: Flamnnable/Explosive limits - lower: Flammable/Explosive limits - upper Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: t applicable Use media appropriate for sun'ounding material. Vt/earfull protective clothing. Wear self-contained breathing apparatus. This pndduct is an aqueous mixture which will not burn. This product contains a component vrtiich is an oxidizing agent. Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocartions. Upon combustion, this product may release oxygen, which may increase the fire hazard. e: LEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spiliage If safe to do so. Wear suitable protective clothing, gloves and eye/face protection. Absorb spill with inert materia!. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE ^ "jiiitjiitf-'-if; r Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not take internally. Provide adequate ventilation. For industrial use only. NEVER ADD WATER TO PRODUCT. For dilutions, add product slowly to water while stirring. Use caution; heat may be generated. Do not mix this product vinth material which contain AMINES. NITROSAMINE may be formed. Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Thaw and mix thoroughly if frozen. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROT^SJEtON : Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. ACGIH TLV OSHA PEL AIHA WEEL OTHER 2 mg/m3 Ceiling 2 mg/m3 TWA IDH number Page 2 of 5

3 Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, apprcipriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density; Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Colorless Mild t available >12.5 > 100 C(>212 F) at 15.6 "C (60,08 "F) t applicable Complete t detennined t applicable,;^tability AND REACTIVITY stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: stable at normal conditions. Will not occur. Decomposes with heat to produce oxides of nitrogen. Adding water to this product may cause localized overheating and splattering. May react virith organic amines to form carcinogenic nitrosamines. Keep separate from acids, ammonia saits, amines, redudng agents,butadiene, phthalic acid, and anhydride, sodium amides, sodiumdisuifite, sodium thiocyanates, and combustible materials, store away from incompatible materials. (ICOCOGICAL INFORMATION NTP Carcinogen larc Carcinogen OSHA Carcinogen (Specifically Regulated) Health Effects/Target Organs Blood, Central nervous system. Corrosive, Gastrointestinal, Irritant Irritant, Com^sive, Eyes 12. ECOLOGICAL INFORMATION Ecological information: t available Page 3 of 5

4 13. PISPOSALCONSIDEBATIONS information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and pnnvincial regulations for disposal. This product, if discarded directly, would be a characteristic RCRA corrosive waste (0002). 14. TRANSPORT INF0RMAT^N:^i^:j^iJtfig^g^^ ^-TSf U.S. Department of Transportation Ground (49 CFRl solution Hazard class or division: 8 Identification number: UN 1824 Packing group: II DOT Reportable quantity: International Air Transportation {ICA0/IATA1 solution Hazard class or division: 8 Identification number: UN 1824 Packing graup: II Water Transportation (IMO/IMDGl Hazard class or division: Identification number: Packing group: SODIUM HYDROXIDE SOLUTION 8 UN EEGULATQRYJNEORMATION United States Reouiatorv Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export tincation: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory, above reporting de minimus above reporting de minimus Immediate Health, Reactive This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372), (CAS# ). (CAS# ) 1,000 lbs, (454 kg) California Proposition 65 listed chemicals are known to be present. Canada Reauiatorv Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List, IB: OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format, Prepared by: John DiCertx), Regulatory Affairs Specialist Page 4 of 5 Prc-duct name: ALODINE 22 TONER

5 DISCLAIMER: The data contained herein are furnished for Information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsit}lllty to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be Involved In the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or Implied, Including warranties of merchantability and Htness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. IDHnumber: Page 5 of 5