Sodium Azide 1. - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/ /UNDERTAKING
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1 MATERIAL SAFETY DATA SHEET FOR Material Safety Data Sheet for Reagents containing Sodium Azide 1. - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/ /UNDERTAKING Product identifier Trade name Single-Color antibodies against Human Antigens Double-Color Combinations Triple-Color Combinations Other Combinations Isotype Controls Lymphogram Lymphoclonal Dendritic Cells Exclusion Kit Screening Kit for Paroxysmal Nocturnal Haemoglobinuria (PNH) Perfect-Count Microspheres Euroflow Reagents: LST, ALOT, PCST y SST Clonalpath and Clonalpath -Plus MM MRD BCP-ALL-MRD Act-4 Cell kit PID Ig Subclassing (1 tube) Ig Subclassing (2 tubes) Reference CYT- antibody fluorochrome version CYT- antibody fluorochrome version x2 CYT- antibody fluorochrome version x3 CYT- antibody fluorochrome version CYT- antibody fluorochrome version CYT-C001 CYT-LC CYT-DENDF CYT-HPN-1 CYT-PCM-50, CYT-PCM-100 CYT-LST, CYT-ALOT, CYT-PCST, CYT-SST, CYT-SLPC-25, CYT-SLPC4-25, CYT-SLPC- 50, CYT-SLPC4-50 CYT-CP-100, CYT-CP45 CYT-MM-MRD. CYT-MM-MRD-CE-IVD, CYT-MM-MRD-T1 CYT-BCP-ALL-MRD CYT-AT4C CYT-PIDOT CYT-IGS-1 CYT-IGS Relevant identified uses of the substance or mixture and uses advised against Relevant uses: Antibodies for identification of cell subpopulations Details of the supplier of the safety data sheet Page 1 de 8
2 Manufacturer/Supplier: CYTOGNOS, S.L. Polígono La Serna, Km. 0, Nave Santa Marta de Tormes Salamanca-España Tel.: / Fax: Emergency telephone number Instituto Nacional de Toxicología (MADRID) / HAZARDS IDENTIFICATION 2.1.-Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (EU-GHS/CLP) Acute Toxicity category 4. H302 Harmful if swallowed Label elements Signal Word(s): Attention Indication(s) of danger: H302 Harmful if swallowed Safety advice: P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P301+P312 If swallowed, call a POISON CENTER or doctor/physician if you feel unwell. P301+P330 If swallowed, rinse mouth. P501 Dispose of contents/container in accordance with local/regional/national/international regulation Other hazards There are not more associated hazards. 3.- COMPOSITION/INFORMATION ON INGREDIENTS 3.1.-Substances 3.2.-Mixtures Page 2 de 8
3 Component(s) CAS No. EC No. Composition Sodium azide % Classification (EC) No 1272/2008 (EU-GHS/CLP) of the pure substance. Acute Tox.2 (Oral), H300 Acute Hazard M. Aquatic 1, H400 Chronic Hazard M. Aquatic 1, H410 These products contain monoclonal antibodies, 0,01 M Sodium Phosphate Buffer, Bovine Serum Albumin as stabilizer and 0.1 % Sodium Azide as preservative. Other components are NOT considered hazardous. 4.- FIRST AID MEASURES Description of first aid measures Ingestion: If swallowed, wash out mouth with water. Seek medical attention. Skin contact: In case of contact, immediately wash skin with soap and generous amount of water. Eye contact: In case of contact, immediately flush eyes with generous amount of water. Assure an adequate flushing by separating the eyelids with fingers. If exposure symptoms develop, seek medical attention Most important symptoms and effects, both acute and delayed If swallowed may produce nauseas, headaches and vomits. Prolonged skin contact may cause redness and irritation. Eye contact may cause severe irritation Indication of any immediate medical attention and special treatment needed There are not additional recommendations, if swallowed and discomfort situation contact a medical center immediately. 5.- FIREFIGHTING MEASURES Extinguishing media No restrictions. Use extinguishing media appropriate to surrounding fire conditions Special hazards arising from the substance or mixture Sodium azide upon thermal decomposition may emit toxic gases, including nitrogen oxides. However, due to the composition and volume of this product, combustion products generated from it are not expected to present a significant hazard Advice for firefighters Firefighting procedures. Page 3 de 8
4 Use of breathing apparatus to protect against carbon monoxide & nitrous oxides. 6.- ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Exercise appropriate precautions to avoid direct contact with skin or eyes. Protective Equipment: Use of personal protective equipment, which may include latex gloves, eye protection, and lab coats, during the use of any laboratory reagent Environmental precautions In high qualities, not allow spill reaches general drains, sewers or water courses. In low doses, solutions may also be rinsed into a general drainage system provided it is acceptable according to applicable regulations Methods and material for containment and cleaning up Solutions containing sodium azide may be absorbed using a paper towel or absorbent pad Reference to other sections See section 8 Exposure controls/individual protection 7.- HANDLING AND STORAGE Precautions for safe handling Wash hands and other exposed areas with soft soap and water before eating, drinking, smoking and leaving work Conditions for safe storage, including any incompatibilities Keep all containers tightly closed. Store and handle as described in the product s specifications sheet Specific end use(s) Specific use (s) of this product are located in the section EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Threshold limit value (pure form): 300µg/m Sodium Azide in accordance Page 4 de 8
5 IOELV (EU) 98/24/EC Daily Exposure value (ED): 0,1 mg/m³ Short Exposure value (EC) duration: 0,3 mg/m³ Via dermal, VLI Exposure controls Eye protection: Chemical safety glasses or goggles. Hand protection: Latex gloves. Body protection: Protective work clothing. Respiratory protection: None required if used in a laboratory with an adequate airexchange HVAC. General hygiene measures: Wash thoroughly after handling. 9.- PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance: Colorless Evaporation rate: N/A Solubility (ies): Water-soluble Melting point: N/A Specific Gravity: N/A ph: N/A Vapor Pressure: N/A Odor: None Boiling point: N/A Physical state: Liquid Vapor Density: N/A Other information There is no more relevant information 10.- STABILITY AND REACTIVITY Reactivity N/A Chemical stability Stable when used under normal conditions and within the scope of the intended application Possibility of hazardous reactions Page 5 de 8
6 Avoid polymerization Conditions to avoid Do not allow solutions containing sodium azide to concentrate. Avoid acidic ph conditions Incompatible materials Avoid contact with metals Hazardous decomposition products N/A 11.- TOXICOLOGICAL INFORMATION Information on toxicological effects To the best of our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated at product concentrations for the following situations: Skin Contact: May cause local discomfort. Skin Absorption: May cause local discomfort. Eye Contact: May cause irritation. Inhalation: May cause irritation. Ingestion: May be harmful if swallowed. Target organs: Lung, Kidney, Gastrointestinal System, Skin ECOLOGICAL INFORMATION Toxicity Sodium Azide (pure form): Orl-rat LD50: 27 mg/kg Skn-rbt LD50: 0 mg/kg Orl-hmn TDLo: 710 µg/kg Inv-mus LD50: 19 mg/kg Persistence and degradability There is not additional relevant information Bioaccumulative potential There is not additional relevant information Page 6 de 8
7 12.4.-Mobility in soil This product is water-soluble and may spread in water systems. This product is not particularly volatile Results of PBT and vpvb assessment Other adverse effects There is not additional relevant information 13.- DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste in accordance to applicable national, regional, or local regulations. If the disposal of these solutions through general drainage is acceptable according regulations, flush with large volumes of water to prevent the build-up of azides in the plumbing TRANSPORT INFORMATION. IATA: At product concentrations, this material is not subject to a hazard classification in accordance with IATA Dangerous Goods Regulations UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards Special precautions for user Page 7 de 8
8 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code 15.- REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture TSCA Inventory Item: This product complies with all TSCA inventory requirements. SARA Listed: No OSHA Status: Specified product concentrations listed on this MSDS are NOT classified as hazardous. Labelled according to the Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures and the Commission Regulation (EU) No 453/2010 of the European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) Chemical safety assessment 16.- OTHER INFORMATION. Some products are for laboratory use only. Not for drug, household or other uses. Others are for in-vitro diagnosis. See corresponding technical file. Interpretation of the results is solely the responsibility of the user. There are no warranties, expressed or implied, which extend beyond this description. The information contained in this sheet is believed to be accurate, but it is responsibility of the user to determine the applicability of this data to the formulation of necessary safety precautions. Cytognos, S.L. shall not be held responsible for any damages and resulting from the use of above product or the information contained in this MSDS Sheet. Page 8 de 8
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