Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Date: 04/07/2006 Issue date: 04/07/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: 736 Primer Locquic Primer NF Item No. : / IDH No Product type: Accelerator Region: United States Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut Contact Information: Telephone: (860) Emergency telephone: (860) Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER Trichloroethylene ppm STEL 100 ppm TWA ppm TWA 200 ppm Ceiling Isopropyl alcohol ppm TWA 400 ppm STEL 400 ppm TWA 980 mg/m³ TWA Carbon dioxide Aldehyde-amine condensate ppm STEL 5000 ppm TWA 5000 ppm TWA exposures < 10,000 ppm to be cited de minimus 9000 mg/m³ TWA HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: 2* Color: Amber FLAMMABILITY: 2 Odor: Sharp PHYSICAL HAZARD: 1 Personal Protection: See Section 8 WARNING: COMBUSTIBLE LIQUID HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE ALLERGIC SKIN REACTION. CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION Relevant routes of exposure: Inhalation, Skin contact, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Irritating to skin. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Contact with eyes will cause irritation. Moderately toxic by ingestion. Eye, skin, and respiratory disorders. See Section 11 for additional toxicological information. Item No. : / IDH No Product name: 736 Primer Locquic Primer NF 1 of 4

2 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If discomfort persists seek medical attention. Wash with soap and water. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. If conscious, drink plenty of water. Do not induce vomiting. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 75.5 C (168 F) (Base only) Foam, dry chemical or carbon dioxide. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. Oxides of carbon. Hydrogen chloride. Phosgene. Irritating organic vapors. Toxic chlorides. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Remove all ignition sources. Ensure adequate ventilation. Soak up with inert absorbent. Store in a closed container until ready for disposal. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of ignition. Store away from heat, sparks, flames, or other sources of ignition. For safe storage, store at or below 49 C (120 F). Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Chemical resistant, impermeable gloves. Solvent resistant gloves such as Viton, poly (vinyl alcohol), or equivalent is recommended. Silver Shield gloves. Safety goggles or safety glasses with side shields. See Section 2 for exposure limits. Item No. : / IDH No Product name: 736 Primer Locquic Primer NF 2 of 4

3 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Amber Odor: Sharp Vapor pressure: Approximately 100 mmhg at 21 ºC (70 F) ph: Not applicable Boiling point/range: C ( F) Melting point/range: Specific gravity: 1.3 at 26.6ºC (80ºF) Vapor density: Approximately 4.5 Evaporation rate: Solubility in water: Slightly soluble Partition coefficient (n-octanol/water): VOC content: 95.6%; 1243 grams/liter (EPA Method 24) 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Stable. Will not occur. Oxides of carbon. Phosgene. Hydrogen chloride. Irritating organic vapors. Toxic chlorides. Strong oxidizers. Bases. Metals. Reducing agents. Strong alkalis. Caustics. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). 11. TOXICOLOGICAL INFORMATION Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Trichloroethylene Suspect Carcinogen Group 2A Yes Isopropyl alcohol Carbon dioxide Aldehyde-amine condensate Literature Referenced Target Organ & Other Health Effects Hazardous components Trichloroethylene Isopropyl alcohol Carbon dioxide Aldehyde-amine condensate Health Effects/Target Organs Behavioral, Cardiac, Central nervous system, Irritant, Kidney, Liver, Some evidence of carcinogenicity Allergen, Blood, Central nervous system, Irritant, Kidney, Liver, Brain, Spleen Central nervous system No data 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. D040: Trichloroethylene Item No. : / IDH No Product name: 736 Primer Locquic Primer NF 3 of 4

4 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR): Aerosols, non-flammable Hazard class or division: 2.2 ( 6.1 ) Identification number: UN 1950 Exceptions: Consumer Commodity ORM-D (Not more than 1 Liter) International Air Transportation (ICAO/IATA): Aerosols, Non-Flammable, containing substances in Division 6.1, Packing Group III Hazard class or division: 2.2 (6.1) Identification number: UN 1950 WaterTransportation (IMO/IMDG): Aerosols Hazard class or division: 2.2 ( 6.1 ) Identification number: UN1950 Exceptions: Limited quantity (Not more than 120 m L) United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.. CERCLA/SARA Section 302 EHS:. CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Trichloroethylene (CAS# ). California Proposition 65: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. A, B.3, D.1.B, D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 9 Prepared by: Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : / IDH No Product name: 736 Primer Locquic Primer NF 4 of 4

5 Material Safety Data Sheet Revision Date: 01/26/2006 Issue date: 02/04/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No. : Product type: Anaerobic Adhesive Region: United States Company address: Contact Information: Henkel Corporation Telephone: Trout Brook Crossing Emergency telephone: Rocky Hill, Connecticut Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER Hydroxyalkyl methacrylate ppm TWA; 3 ppm STEL Acrylic acid ppm TWA (skin) 10 ppm TWA; 30 mg/m³ 1 ppm TWA (skin); 3 ppm STEL (skin) Cumene hydroperoxide Polyglycol dimethacrylate Methacrylic acid ppm (6 mg/m 3 ) Skin (WEEL) ppm TWA 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Liquid HEALTH: 2* Color: Clear Amber FLAMMABILITY: 1 Odor: Sharp PHYSICAL HAZARD: 1 Personal Protection: See Section 8 WARNING: HMIS: CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF SWALLOWED OR INHALED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Item No. : Vapors and mists will irritate the respiratory tract and nasal passages. May cause allergic skin reaction. Irritating to skin. 1 of 5

6 Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation. Ingestion: May be harmful if swallowed. Existing conditions aggravated by exposure: Eye, skin, and respiratory disorders. Acrylic acid: Respiratory disorders. Lung disease. See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If symptoms develop and persist, get medical attention. Wash with soap and water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if symptoms occur. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Do not induce vomiting. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: Greater than 93ºC (200ºF) Tagliabue closed cup Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Oxides of nitrogen. Irritating organic vapors. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Ensure adequate ventilation. Soak up with inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. Use only with adequate ventilation. For safe storage, store at or below 38 C (100 F). Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Item No. : of 5

7 Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves. Safety goggles or safety glasses with side shields. See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Clear Amber Odor: Sharp Vapor pressure: Less than 10 mm Hg at 27ºC (80ºF) ph: Not applicable Boiling point/range: Greater than 149ºC (300ºF) Melting point/range: Specific gravity: 1.08 Vapor density: Evaporation rate: Solubility in water: Slight Partition coefficient (n-octanol/water): VOC content: %; grams/liter 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Stable. Will not occur. Oxides of carbon. Oxides of nitrogen. Phenols. Irritating organic vapors. Strong oxidizers. Strong reducing agents. Amines. Strong acids. Heavy metals. Peroxides. Free radical initiators. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). 11. TOXICOLOGICAL INFORMATION Product toxicity data: Acute LD50 (oral) :Greater than mg/kg(rat). Acute LD50 (dermal) :Greater than 5000 mg/kg (rabbit). Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Hydroxyalkyl methacrylate Acrylic acid Cumene hydroperoxide Polyglycol dimethacrylate Methacrylic acid Item No. : Literature Referenced Target Organ & Other Health Effects 3 of 5

8 Hazardous components Hydroxyalkyl methacrylate Acrylic acid Cumene hydroperoxide Polyglycol dimethacrylate Methacrylic acid Health Effects/Target Organs Allergen, Irritant Allergen, Irritant Allergen, Irritant Allergen, Corrosive, Irritant, Kidney, Liver Allergen, Central nervous system, Corrosive, Irritant, Mutagen Allergen, Irritant Allergen, Corrosive, Irritant 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR): Unrestricted Hazard class or division: Identification number: International Air Transportation (ICAO/IATA): Unrestricted Hazard class or division: Identification number: WaterTransportation (IMO/IMDG): Hazard class or division: Identification number: Marine pollutant: Unrestricted Item No. : of 5

9 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: 4-Methoxyphenol ( ). CERCLA/SARA Section 302 EHS: above reporting de minimus. CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Acrylic acid (CAS# ). Cumene hydroperoxide (CAS# ). California Proposition 65: This product contains a chemical known to the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 9 Prepared by: Kyra Kozak Woods, Product Safety and Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : of 5