Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Date: 11/12/2007 Issue date: 11/12/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE Natural Blue BIODEGRADABLE Item No. : / IDH No CLEANER & Product Use: Cleaner Region: Canada Company address: Henkel Canada Corporation 2225 Meadowpine Boulevard Mississauga, Ontario L5N 7P2 Contact Information: Telephone: (905) Emergency telephone: (905) Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER Tetrasodium ethylenediamine 1-5 C12-15 Ethoxylated alcohols ppm TWA 150 ppm STEL Non hazardous components Water > 50% 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Physical state: Liquid WHMIS hazard class: D.2.A, D.2.B Color: Blue Odor: CAUTION: Pine MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Skin, Inhalation, Eyes, Ingestion Prolonged or repeated inhalation of excessive amounts of oil mist or vapors may cause irritation of the respiratory tract. Repeated contact may cause skin irritation Contact with eyes will cause irritation. Ingestion may cause stomach ache and vomiting. Existing conditions aggravated by exposure: known 1 of 5

2 See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Notes to physician: Not hazardous by inhalation Immediately flush skin with plenty of water (using soap, if available). Wash clothing before reuse. Get medical attention if symptoms develop and persist. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Do not induce vomiting. Rinse mouth. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Get medical attention if symptoms develop and persist.. 5. FIRE-FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Sensitivity to mechanical impact: Sensitivity to static discharge: Does not ignite. Use media appropriate for surrounding material. known ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: known Soak up with inert absorbent. Flush with water. 7. HANDLING AND STORAGE Handling: Storage: Incompatible products: Avoid contact with skin and eyes. No special procedures.. For information on product shelf life contact Henkel Canada Customer Service at (905) EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. No personal respiratory protective equipment normally required. Do not inhale aerosol. Chemical resistant, impermeable gloves. 2 of 5

3 Eye/face protection: Chemical splash goggles or safety glasses with side shields. Physical state: Liquid Color: Blue Odor: Pine Odor Threshold: Vapor pressure: ph: 10.6 Boiling point/range: Greater than 100 C (212 F) Melting point/range: Specific gravity: 1.0 Vapor density: Evaporation rate: Faster than ether Solubility in water: Soluble. Partition coefficient (n-octanol/water): VOC content: 4.65%; 46.5 grams/liter See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable. Will not occur. known. known. 11. TOXICOLOGICAL INFORMATION Product toxicity data: Toxicologically synergistic products:. Refer to the following for Irritancy of Product, Sensitization to Product, icity, Reproductive Toxicity, Teratogenicity, and Mutagenicity. 3 of 5

4 Ingredient Toxicity Data & Status Hazardous components LD50s & LC50s Other LD50s and LC50s NTP IARC OSHA ACGIH - s Tetrasodium ethylenediamine No No No No = 1658 mg/kg C12-15 Ethoxylated alcohols No No No No = 2 g/kg No No No No Dermal LD50 (Rabbit) = mg/kg = 5200 mg/kg Inhalation LC50 (Rat) = 54.6 mg/l Inhalation LC50 (Rat) > 24 mg/l = 7200 mg/kg = 1600 mg/kg No No No No No No No No No No No No Literature Referenced Target Organ & Other Health Effects Hazardous components Tetrasodium ethylenediamine C12-15 Ethoxylated alcohols Health Effects/Target Organs No Target Organs No Target Organs Central nervous system,, Developmental 12. ECOLOGICAL INFORMATION Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this material; however, commonly available data on the material indicate that uncontrolled releases to soil, groundwater, or surface waters could entail acute and/or chronic ecological effects, depending on the quantity and concentration of such releases. Releases of volatile components to the atmosphere are not believed to entail significant ecological consequences provided such releases are within the exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which may occur should be contained and cleaned up immediately in accordance with Section DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Dispose of according to Canadian and local regulations. 14. TRANSPORT INFORMATION The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. 4 of 5

5 Canada Transportation of Dangerous Goods - Ground: Hazard class or division: International Air Transportation (ICAO/IATA): Hazard class or division: WaterTransportation (IMO/IMDG): Hazard class or division: Marine pollutant: 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List. United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 2, 3 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Product Regulations. Prepared by: Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. 5 of 5