MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Ideal FG Oil 32 Version # 01 Revision date CAS # Manufacturer information 2. Hazards Identification Mixture Calumet Specialty Products Partners, L.P Waterfront Pkwy E. Dr. Suite 200 Indianapolis, IN United States Technical Services CHEMTREC International Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Potential environmental effects This product is considered not hazardous under 29 CFR (Hazard Communication). t applicable. Ecological injuries are not known or expected under normal use. 3. Composition / Information on Ingredients n-hazardous components CAS # Percent White mineral oil Polybutene (Isobutylene/butene copolymer) AMINES, C11-14-BRANCHED ALKYL, MONOHEXYL AND DIHEXYL PHOSPHATES BENZENAMINE, N-PHENYL-, REACTION PRODUCTS WITH 2,4,4-TRIMETHYLPENTENE DIPHENYLAMINE OCTAMETHYLCYCLOTETRASILOXANE First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion General advice Rinse with water. Get medical attention if irritation develops and persists. Rinse skin with water/shower. Get medical attention if irritation develops and persists. If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If you feel unwell, seek medical advice (show the label where possible). 5. Fire Fighting Measures Flammable properties t flammable by OSHA criteria. t combustible by OSHA criteria. 1 / 5

2 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Protective equipment and precautions for firefighters Fire fighting equipment/instructions Hazardous combustion products Water fog. Foam. Carbon dioxide (CO2). Dry chemicals. Water. Do not use water jet as an extinguisher, as this will spread the fire. Wear suitable protective equipment. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. May include oxides of nitrogen. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Prevent further leakage or spillage if safe to do so. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Scrub the area with detergent and water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. 7. Handling and Storage Handling Storage DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid prolonged or repeated contact with skin. Use only in well-ventilated areas. Handle and open container with care. Keep away from heat and sources of ignition. Use care in handling/storage. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Type Value DIPHENYLAMINE ( ) Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations TWA 10 mg/m3 Chemical goggles are recommended. rmal work clothing (long sleeved shirts and long pants) is recommended. personal respiratory protective equipment normally required. Handle in accordance with good industrial hygiene and safety practice. 9. Physical & Chemical Properties Appearance Physical state Form Color Odor Odor threshold ph Vapor pressure Bright and clear liquid. Liquid. Liquid. Colorless to pale straw. Slight Hydrocarbon t Applicable 2 / 5

3 Vapor density Boiling point Melting point/freezing point Solubility (water) Negligible Specific gravity Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Pour point Other data Density Kinematic viscosity Kinematic viscosity temp > 350 F (> C) > 600 F (> C) < 10 F (< C) g/cm3 < 238 mm²/s ; Kinematic viscosity 104 F (40 C) 104 F (40 C) 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological Information Material is stable under normal conditions. Heat, flames and sparks. Avoid temperatures exceeding the flash point. Nitrogen oxides (NOx). Toxicological data Test Results DIPHENYLAMINE ( ) Carcinogenicity ACGIH Carcinogens Further information 12. Ecological Information Acute Oral LD50 Guinea pig: 300 mg/kg Acute Oral LD50 Mouse: 1750 mg/kg Acute Oral LD50 Rat: 2 g/kg This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. A4 t classifiable as a human carcinogen. This product has no known adverse effect on human health. Ecotoxicological data DIPHENYLAMINE ( ) Test Results EC50 Water flea (Daphnia magna): mg/l 48 hours LC50 Fathead minnow (Pimephales promelas): mg/l 96 hours * Estimates for product may be based on additional component data not shown. Ecotoxicity Persistence and degradability 13. Disposal Considerations Disposal instructions This product has no known eco-toxicological effects. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose in accordance with all applicable regulations. 3 / 5

4 Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information DOT NON-BULK t regulated as dangerous goods. DOT BULK t regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. CERCLA/SARA Hazardous Substances - t applicable. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) t regulated DEA Essential Chemical Code Number t regulated Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) t regulated DEA Exempt Chemical Mixtures Code Number t regulated US EPCRA (SARA Title III) Section Toxic Chemical: De minimis concentration 1.0 % US EPCRA (SARA Title III) Section Toxic Chemical: Listed substance Listed. US TSCA Section 12(b) Export tification: Export tification requirement/de minimis concentration CERCLA (Superfund) reportable quantity ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Section 311 hazardous chemical Inventory status Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard % One-Time Export tification only. Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 4 / 5

5 State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - New Jersey Community RTK (EHS Survey): Reportable threshold 500 LBS US - Pennsylvania RTK - Hazardous Substances: Listed substance 16. Other Information Further information HMIS ratings Health: 0 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 0 Flammability: 1 Instability: 0 Disclaimer Issue date This data sheet contains changes from the previous version in section(s): Listed. HMIS is a registered trade and service mark of the NPCA. The information in the sheet was written based on the best knowledge and experience currently available. First Aid Measures: Eye contact First Aid Measures: Skin contact Accidental Release Measures: Methods for cleaning up Physical & Chemical Properties: Appearance Physical & Chemical Properties: Color Physical & Chemical Properties: Odor Chemical Stability & Reactivity Information: Conditions to avoid Disposal Considerations: Contaminated packaging 5 / 5