Agrochemical: component Mixture Name Product identifier % Classification (GHS-US)

Transcription

1 Date of issue: 03/19/2015 Revision date: 05/21/2015 Supersedes: 03/19/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture : Slammer 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Power-Line Products th Street - Acequia Rupert, ID USA T F Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture : Adjuvant, Spreader, Sticker Agrochemical: component : 24 Hour Emergency HAZMAT Response (800) ; EPA National Response Center (800) Classification (GHS-US) Eye Irrit. 2B Full text of H-phrases: see section 16 H Label elements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning : H320 - Causes eye irritation : P264 - Wash hands, face thoroughly after handling P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification (GHS-US) * (CAS No) Trade Secret Eye Irrit. 2B, H320 Aquatic Chronic 2, H411 * (CAS No) Trade Secret Acute Tox. 4 (Inhalation:dust,mist), H332 Eye Irrit. 2B, H320 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. 05/21/2015 EN (English US) Page 1

2 First-aid measures after skin contact First-aid measures after eye contact : Wash skin with plenty of water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Dry skin. Symptoms/injuries after eye contact : mild eye irritation. Symptoms/injuries after ingestion : Abdominal pain. Risk of aspiration pneumonia Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Reactivity : The product is non-reactive under normal conditions of use, storage and transport Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8 Exposure controls/personal protection" " Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Other information 6.4. Reference to other sections : Take up liquid spill into absorbent material. : Dispose of materials or solid residues at an authorized site. For further information refer to section 8 : Exposure-controls/personal protection"". SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Slammer ACGIH OSHA : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool. ACGIH 05/21/2015 EN (English US) 2/6

3 OSHA ACGIH OSHA 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves. : Safety glasses. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold ph Melting point Freezing point : Liquid : Colorless to pale yellow liquid. : Colourless to light yellow : mild : Not Applicable : Boiling point : > 140 C Flash point : > 199 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Specific gravity / density Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information SECTION 10: Stability and reactivity Reactivity : < 0.1 mbar : 0.91 g/ml : Insoluble in water. Water: Solubility in water of component(s) of the mixture : : The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions. 05/21/2015 EN (English US) 3/6

4 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (ppm) 0 ATE US (gases) ppmv/4h ATE US (dust, mist) mg/l/4h LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (gases) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 EC50 Daphnia mg/kg mg/kg 1.15 ppm/4h mg/kg body weight mg/kg body weight ppmv/4h ph: Not Applicable : Causes eye irritation. ph: Not Applicable 3 - Not Classifiable : Dry skin. : mild eye irritation. : Abdominal pain. Risk of aspiration pneumonia. : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment mg/l Similar material mg/l 48 h similar material 05/21/2015 EN (English US) 4/6

5 ErC50 (algae) LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 Threshold limit algae mg/l 5 mg/l (96 h; Gasterosteus aculeatus; Intermittent flow) >= 9-21 mg/l 48 h 500 mg/l (Selenastrum capricornutum; Chronic) 7 mg/l (96 h; Leuciscus idus) 500 mg/l (Selenastrum capricornutum; Cell numbers) Persistence and degradability Persistence and degradability Not readily biodegradable in water Bioaccumulative potential BCF fish 1 Not Estabilished BCF fish 1 0 (5.9-48) Log Pow > Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations : Prevent liquid from entering sewers, watercourses, underground or low areas. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information Other information : Adhesives, Adjuvants, Spreaders or Stickers, Liquid NMFC Item 4612, LTL Class 60. ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Slammer Not listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory 05/21/2015 EN (English US) 5/6

6 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations US State regulations SECTION 16: Other information Revision date : 05/21/2015 Full text of H-phrases: Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category Eye Irrit. 2B Serious eye damage/eye irritation Category 2B H320 Causes eye irritation H332 Harmful if inhaled H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) All information contained in this is furnished free of charge and is intended for your evaluation. In our opinion the is, as of the date of this, reliable, however, it is your responsibility to determine the suitablity of the information for your use. You are advised not to construe the informatio as absolutely complete since additional information may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or governament regulations. Theerefore you should use this information only as a supplement to other information gathered by you, and you must make independent determinations of the suitability and completeness of the information from all sources to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee is expressed or implied as to the results to be obtained based upon your use of the information. 05/21/2015 EN (English US) 6/6