Issue Date: 18-Jan-2009 Revision Date: 15-Apr-2014 Version 1 1. IDENTIFICATION. Spray Cleaner Degreaser. Liquid cleaner, degreaser, solvent.

Transcription

1 Safety Data Sheet Issue Date: 18-Jan-2009 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # Spray Cleaner Degreaser WC-027 Product Code #43 Recommended use of the chemical and restrictions on use Recommended Use Liquid cleaner, degreaser, solvent. Details of the supplier of the safety data sheet Supplier Address Wepak Corporation 314 W. Bland St. Charlotte, NC Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) HAZARDS IDENTIFICATION Appearance Clear green liquid Physical State Liquid Odor Almond Classification Hazards Not Otherwise Classified (HNOC) Causes mild skin irritation Page 1 / 7

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Proprietary D-Sodium Silicate Solution Proprietary Nonylphenoxypoly-(Ethyleneoxy) Ethanol Proprietary Proprietary **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Wash off immediately with plenty of water. Remove to fresh air. Dilute with milk or water. Neutralize by taking 2 tablespoons of vinegar. Most important symptoms and effects Symptoms Direct contact with eyes may cause temporary irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Water. Foam. Dry chemical. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical None known. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Page 2 / 7

3 Methods for Clean-Up Flush area with water. Contain and collect with an inert absorbent and place into an appropriate container for disposal. Dispose of in accordance with federal, state and local regulations. Precautions for safe handling 7. HANDLING AND STORAGE Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m 3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m 3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m 3 Appropriate engineering controls Ceiling: 2 mg/m 3 TWA: 2 mg/m 3 (vacated) Ceiling: 2 mg/m 3 IDLH: 10 mg/m 3 Ceiling: 2 mg/m 3 Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Wear eye/face protection. Wear suitable gloves. Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Clear green liquid Odor Almond Color Green Odor Threshold Property Values Remarks Method ph 11 Melting Point/Freezing Point Not available Boiling Point/Boiling Range 100 C / 212 F Flash Point None Evaporation Rate Not available Flammability (Solid, Gas) n/a-liquid Page 3 / 7

4 Upper Flammability Limits None Lower Flammability Limit None Vapor Pressure Vapor Density Not available Specific Gravity 1.06 (1=Water) Water Solubility Completely soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. 10. STABILITY AND REACTIVITY Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Avoid contact with eyes. Causes mild skin irritation. Avoid breathing vapors or mists. Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 470 mg/kg ( Rat ) = 2270 mg/kg ( Rat ) = 220 mg/kg = 2.21 mg/l ( Rat ) 4 h = 450 ppm ( Rabbit ) ( Rat ) 4 h D-Sodium Silicate Solution = 1153 mg/kg ( Rat ) > 4640 mg/kg ( Rabbit ) - Page 4 / 7

5 Nonylphenoxypoly-(Ethyleneoxy) - = 1800 µl/kg ( Rabbit ) - Ethanol Trade Secret = 8471 mg/kg ( Rat ) = 1350 mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Not classifiable as a human carcinogen. Chemical Name ACGIH IARC NTP OSHA Ethylene Glycol Monobutyl A3 Group 3 Ether Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 IARC components are "not classifiable as human carcinogens" Numerical measures of toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Ethylene Glycol Monobutyl 1490: 96 h Lepomis Ether macrochirus mg/l LC50 static 2950: 96 h Lepomis macrochirus mg/l LC50 D-Sodium Silicate Solution Trade Secret : 96 h Lepomis macrochirus mg/l LC : 96 h Brachydanio rerio mg/l LC50 semi-static : 96 h Poecilia reticulata mg/l LC : 96 h Oncorhynchus mykiss mg/l LC50 static Crustacea : 24 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 216: 96 h Daphnia magna mg/l EC : 24 h Daphnia magna Straus mg/l EC : 48 h Daphnia magna mg/l EC50 Static Persistence/Degradability. Bioaccumulation. Mobility Chemical Name Partition Coefficient 0.81 Page 5 / 7

6 Other Adverse Effects Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Nonylphenoxypoly-(Ethylene oxy) Ethanol Included in waste stream: K060 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Toxic Corrosive 14. TRANSPORT INFORMATION Note DOT IATA IMDG Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations Page 6 / 7

7 CERCLA SARA 313 Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ Chemical Name CAS No Weight-% SARA Threshold Values % - Proprietary 1.0 CWA (Clean Water Act) Component ( Proprietary ) CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 1000 lb X US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X X X X 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards 2 Flammability Flammability 1 Instability Physical Hazards 0 Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 18-Jan Apr-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7