TECHNOLOGIES ADDING VALUE ON BIOGAS TAIYO NIPPON SANSO CORPORATION NOX / GASALAM. Biogas Asia Pacific Forum June 2013 Kuala Lumpur, Malaysia

Transcription

1 TECHNOLOGIES ADDING VALUE ON BIOGAS TAIYO NIPPON SANSO CORPORATION NOX / GASALAM Biogas Asia Pacific Forum June 2013 Kuala Lumpur, Malaysia 1

2 Brief Introduction of Taiyo Nippon Sanso Found in 1910 First Asian Industrial Gas Company App. 10,000 employees Subsidiaries in Europe, USA & Asia Business Field Industrial Gases Electronics Medical Care Stable Isotopes Gas Related Equipments Plant & Engineering Others 2

3 Overview of our Biogas business We are focusing much on industrial gas market from this process. With our advanced technology, we are planning to take out BioMethane and BioCarbon Dioxide to sell out in the markets nearby. Moreover, some biogas plants would accommodate generator to produce electricity. Biomass BioCarbon Dioxide (CO2) Our target markets Cutting / Welding Beverage Electronics Digesting & Purifying system BioMethane (CH4) Biofuel Electricity Electricity residue Local grid Fertilizer

4 Our Target Areas Our primal target areas: Southeast Asia starting from Indonesia and Malaysia (rich sources of biomass and potential customers of industrial gases) With renewable and distributed bioenergy and broad networks of TNSC group, we are also planning to explore more industrial gas businesses throughout southeast Asia. API Vietnam Japan Gas INGASCO Taiyo Nippon Sanso Philippines NOSB Nippon Oxygen NOX TGC Leeden

5 Introduction of Purification process Biogas Purification System Biogas made into Bio-Carbon Dioxide, Bio-Methane, Electricity, and More

6 Introduction TNSC (Taiyo Nippon Sanso Co.) has been one of a top manufacturer of PSA equipment over 30 years, and has 2,000 sets of track records. Reliable Biogas PSA equipment is among our line-up using this technology. TNSC Presence/Technologies in Biogas Business Biogas Purification/Separation Equipment's Methane VPSA, PSA Siloxane Removal Compact Storage System of Methane Biogas Utilization System Dairy Farm Model Injection to Town Gas Line

7 Our Presence in Biogas Business Biogas Digester Biogas Gas Boiler Biogas Purifiers, Separation & Supply TAIYO NIPPON SANSO Power Generator CNG Cylinder CNG Vehicle 7

8 Basic Scheme of Our Solution TAIYO NIPPON SANSO TSA PSA TANK Food factory Dairy Farm Sewage plant Impurity Removal /Siloxane Methane Concentration ( 98%) Adsorption Storage Tank Gas Line CNG Vehicle Trouble prevention Increasing calorie by concentrate Decrease of cost and foot print Power Generator 8

9 Methane VPSA High Methane Recovery Rate Model Tank Compressor Adsorption Column Methane Raw Material Dryer Power Consumption Rate 0.4 kw/nm 3 Vacuum Pump Carbon Dioxide Biogas Prod. CH 4 Device size Flow Rate Flow Rate Concentration Pressure W D H [Nm 3/ hr] [Nm 3 /hr] [%] [kpag] [m]

10 Biogas Utilization System Methane Fermentation At Dairy Farm CH 4 :60% CO 2 :40% H 2 S:200ppm H 2 S:<10ppm CH 4 :98% Advanced Utilization Boiler Generator Gas Consumption equip (Town Gas spec) Desulfurization tower Concentration (PSA) TNSC Retention Tank Booster Compressor 20MPaG CNG Vehicle Cylinder 10

11 Injection to Town Gas Line Food Waste Disposal Plant Biogas CH 4 =60% CO 2 =40% 200Nm 3 /h Purification and Unit calorie adjustment TNSC CH 4 VPSA CH 4 98% Town Gas Line Town Gas 100 Nm 3 /h 11

12 Maximizing use of Biogas Dairy farm Injection to city gas line Methane Gas CNG Vehicle Sewage plant Transport Food Waste plant Methane VPSA Equip. Carbon Dioxide Gas Transport Use for Industry and household Use for Industry and household 12

13 Gases Recovery PSA for Biogas TNSC developed gas separation technology for supplying both CH4 and CO2 with high purity and with high recovery rate. With this technology, we can supply gases and utilities using the gases to areas such as islands and isolated regions. 13

14 Example for Biogas use in Southeast Asia Waste fluid of palm oil Biomass Bio CH 4 Boiler Electricity Biogas:1000m 3 /h PSA Compressor Car, Cylinder Digester H 2 S removal Bio CO 2 Compressor Cylinder (Welding) Liquefication LCO 2 14

15 Material Balance Separated Gas Biogas 1.Mass Flow:1,000Nm 3 /h 2.Pressure:0kPaG 3.Contents : CH 4 /60%+CO 2 /40% CO 2 MF:300Nm 3 /h P:0kPaG CO 2 =99% CH 4 MF:600Nm 3 /h P:100kPaG CH 4 =90% Vent Gas MF:100Nm 3 /h P:0kPaG

16 Summary TNSC is commercializing the equipment for using biogas effectively. Methane PSA, Refining Equipment, and Adsorption type Methane Storage Tank With these technologies, we can help the biogas related society in Southeast Asia by maximizing the value of the gases. PSA for Methane and Carbon Dioxide separation high concentration and a high recovery rate will be a robust tool. We can supply methane and Carbon Dioxide to areas such as islands and isolated regions

17 Thank you Terima Kasih 17

18 REFERENCE 18

19 Overall Process to Biogas To achieve this biogas business, we are designing the integrated biogas processing system. With our partner GasAlam, owning advanced technology and network in plantation and digesting process, TNSC will take advantage of its knowhow and achievement in purifying system to generate industrial gases. Fresh Waste Biomass Slurry Conveyor / Pump Gas Holder Digester Biogas Gas Blower Heat Exchanger Flare Gas Engine Heat Cooling Unit Flue Gas G Generato r Electricity Advanced purifier markets Circulate Material Recirculation Pumps Digested Material Clarifier Composting Compost Biogas CH4, CO2

20 Key Advantages of our project For Factories with biomass waste -access for electricity, biofuel (CH4), hot water, BioMethane -rent for process facility utilizing space For Biogas process facility/equipment manufacturer -Business chances with TNSC/GasAlam advanced technologies and sales networks For All -Better access of BioCarbon Dioxide, BioMethane, Electricity, Hot Water -Better local/global life environment with ecological process -Boost demand and business opportunities -Expand renewable energy business field and contribute to the administration s energy policy

21 Methane PSA Compact-Low Initial Cost Model Compressor Raw Material Dryer Adsorption Column Tank Carbon Dioxide Methane Biogas Flow Rate [Nm 3 /hr] 12 Prod Methane Gas Conc.[%] 98 or higher Prod Flow Rate [Nm 3 /hr] 5.0 or higher Prod Pressure [MPaG] 0.3 Power Consumption Rate [kwh/nm 3 ] 0.6 Equip occupation area W D [m]

22 Siloxane Removal Process Biogas from sewage disposal in Japan contains several ppm of SILOXANES. Burning SILOXANES results Silicon Oxide to cause clog in engine and/or boiler. Silicon Oxide in Cylinder of Engine [Example] D4: Octamethylcyclotetrasiloxane Digester Tank Gas Tank Electricity Biogas Hot Water Sewage Disposal Plant Siloxane Remover Micro-Gas-Turbine Generator 22

23 Siloxane Removal Equipment Heater Self-regenerating Gas Adsorption Regeneration Biogas Product Gas Exhaust Gas Biogas throughput 60Nm 3 /h Biogas siloxane concentration 20ppm or lower (D3, D4, D5) *1 Product gas siloxane concentration 0.1ppm or lower Equipment size W 1200 D 1000 H 1700 mm *1 D3: [(CH 3 ) 2 SiO] 3, D4: [(CH 3 ) 2 SiO] 4, D5: [(CH 3 ) 2 SiO] 5 23

24 Compact Storage System of Methane Digester Tank Tank 0.9MPaG 1/25 volume Activated carbon CH 4 PSA Compressor Filling tank Amount of methane Inside volume of tank Device size 100 Nm 3 4 m 3 Φ mm 300 Nm 3 12 m 3 Φ mm 500 Nm 3 20 m 3 Φ mm 24

25 Example of delivery track record Purification Model Biogas Flow Rate [Nm 3 /hr] Prod. Methane Conc. [%] Sewage Plant VPSA Dairy Farm VPSA Dairy Farm PSA Coal Mine PSA Food Waste Plant VPSA

26 CO2 Recovery PSA Process Compressed Bio Gas Vent gas Material Tank or Digresser CH 4 or Electricity CH 4 CH 4 90% CO 2 CO 2 CH 4 :60% (50~70%) CO 2 :40% (50~30%) CO 2 Welding gas CO 2 99% Biogas GP VP CO 2 GP2 26