Version: 5.0. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 5.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: ORASOL Red 395 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent for dye and varnish industry. Coloring agent for industrial purposes Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H400 Cat.: 1 H410 Cat.: 1 Classification according to EC Regulation No. 67/548 or No. 1999/45 Hazardous to the R50 environment (N) R53 Acute aquatic toxicity, hazard category 1 Chronic aquatic toxicity, hazard category 1 Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: 2

2 Page 2 GHS09-1 Signal word: Hazard designation: Safety designation: H400 H410 P273 P391 P501 Warning Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Avoid release to the environment. Collect spillage Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture This product is capable of dust explosion under certain circumstances. Chemical Characterization: Metal complex dye similar to C.I. Solvent Red 122. Hazardous Ingredients: Amine, C10-14-branched and linear Alkyl-,bis[2,4- dihydro-4[(2-hydroxy-5-nitrophenyl)azo]-5-methyl- 2-phenyl-3H-pyrazol-3-onato(2-)]chromate(1-) (N; R50/53; H400-H410) Amines, C10-14-branched and linear Alkyl-, bis [2,4-dihydro-4[(2-hydroxy-5-nitrophenyl)azo]-5- methyl-2-phenyl-3h-pyrazol-3-onato(2-)]chromate (1-) (1:1) (Xn; R22; H302) % 4-6 % CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air. In case of complaints consult a physician. Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eyes with plenty of water for at least 15 minutes. 3

3 Page 3 After ingestion: Rinse mouth with water and drink plenty of water Most important Symptoms and Effects, both Acute and Delayed Symptoms: Effects: No further information available. No further information available Indication of any Immediate Medical Attention and special Treatment needed Treatment: Treat symptomatically Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Extingishing powder, foam. Carbon dioxide (CO2) Special Hazards arising from the Substance or Mixture Special hazards: In case of fire: hazardous vapors may be released. Development of fumes/aerosol Advice for Firefighters Protective equipment: Further information: Wear self-contained respiratory protective device. Avoid formation of dust: risk of dust explosion. Dispose of fire debris and contaminated extinguishing water in accordance with local regulations Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Avoid formation of dust, wear protective clothing Environmental Precautions Environmental precautions: Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and Material for Containment and Cleaning Up Methods and material: Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Clean up mechanically. Avoid dust formation. 4

4 Reference to other Sections Handling and Storage Precautions for Safe Handling Page 4 Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Instructions on safe handling: Respiratory protection when handling without exhaust system Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry and cool room. No special measures necessary. Avoid dust formation. Protect against electrostatic charging. Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): No exposure limits for this product. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke 5

5 Page 5 during work. Wash hands before breaks and at the end of work. Respiratory protection: Hand protection: Protective glove material: Eye protection: Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). Chemical protective gloves (EN 374 (Europe), F739 (US)). The manufacturer s directions for use should be observed because of the great diversity of types. Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Body protection: Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: powder red odorless ca. 7 (20 C) Melting temperature: C Boiling temperature: Flash point: Evaporation rate: This product is a non-volatile solid. Flammability (solid, gas): not easily flammable Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: 6

6 Vapor density: This product is a non-volatile solid. Page Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid 1.4 g/cm3 (20 C) insoluble 200 C, 0.76 kj/g (DDK) > 75 C (SADT, Test H.4, ) Product is not explosive. Risk of dust explosion. not oxidizing kg/m3 In many organic solvents. Minimum ignition energy: > 10 - < 30 mj Hygroscopy: not hygroscopic No decomposition if used according to specifications. Stable if used according to specifications. Risk of dust explosion. Conditions to avoid: Avoid formation of dust. 7

7 Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity see section 9 None known. Page 7 None if stored and handled according to specifications. LD50, oral: LD50, dermal: LC50, inhalation: > 5000 mg/kg (rat) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Non irritating (rabbit) Non-irritating to eyes (rabbit) No information available Product shows a mutagenic effect in a test with bacteria. No data available. No data available. Single exposure: no information available. Repeated exposure: no information available. Additional toxicological information: Aspiration hazard: 12. Ecological Information 8

8 Aquatic Toxicity Page Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): not determined EC50: mg/l (48h, Daphnia magna) EC20: > 1000 mg/l (active sludge) No impairment of the biodegradability of active sludge expected when small amounts are discharged in biological sewage plants. not determined Not readily biodegradable. Very insoluble product and can thus be removed from water mechanically in suitable effluent treatment plants. According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. 3, hazardous Treatment and discharge of waste water into biological treatment plant should be carried out according to official national and local regulations. The product contains chromium bound as a complex. In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. Uncleaned packaging: Uncontaminated packaging may be recycled. 9

9 Page 9 Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA 3077 UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (enthält C.I. Solvent Red 122) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains C.I. Solvent Red 122) ADR Class: 9 Hazard no.: 9 Classification code: Tunnel no.: M7 E IMDG Class (sea): 9 Hazard no.: 9 EmS No.: F-A, S-F IATA Class: Hazard no.: 9 Packaging Group ADR/RID: IMDG: III III IATA: Environmental Hazards Special Precautions for User III Labelling according ADR/RID: fish and tree Labelling according IMDG: fish and tree Labelled with "P" according 2.10 IMDG: yes none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not evaluated Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 3, very hazardous for water (German Regulation) Local regulations on chemical accidents: 10

10 Employment restrictions: Page Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not yet been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.