Version: 3. Identification of the Substance/Mixture and of the Company/Undertaking. 39 Bis Rue Du Moulin Rouge Charmont Sous Barbuise

Transcription

1 Revised edition: Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Spike-Lavender Oil Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Tel./Fax.: Internet: Importer: Emergency No. Mon-Droguiste.Com 39 Bis Rue Du Moulin Rouge Charmont Sous Barbuise Tel +33 (0) Fax +33 (0) contact@mon-droguiste.com Emergency No.: ORFILA : SAMU : 15 - Pompiers : 18 - Médecins de garde : 15 Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H226 Cat.: 3 H302 Cat.: 4 H319 Cat.: 2 H411 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 R10 Harmful (Xn) R22 Irritating (Xi) R36 Hazardous to the R51 environment (N) R53 Flammable liquids, category 3 Acute toxicity (oral), hazard category 4 Eye irritation, category 2 Chronic aquatic toxicity, category 2 Flammable liquid and vapour. Harmful if swallowed. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. Flammable. Harmful if swallowed. Irritating to eyes. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Safety Phrases: Possible Environmental Effects: 2

2 2. 2. Label Elements Page 2 Classification according to EC Regulation 1272/2008 Hazard designation: GHS02-1 GHS07 GHS09 Signal word: Hazard designation: Safety designation: H226 H302 H319 H411 P210 P233 P243 P261 P271 P280 Warning Flammable liquid and vapour. Harmful if swallowed. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. Keep container tightly closed. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/ clothing/ eye/ face protection Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Essential oil Hazardous Ingredients: Camphene (Xi,N; R11-51/53; H ) ca. 9% CAS-Nr: EINECS-Nr: Terpinyl acetate ca. 5% CAS-Nr: EINECS-Nr:

3 Cedar wood oil (Xn; R65; H304) Terpineol (Xi; R43; H317) Pine oil (Xi; R36-38; H304) Turpentine oil (N, Xn; R10-20/21/22-36/ ; H ) Camphor (Xi; R11-36/37/38; H ) Dipenten; Cineole; Limonen (Xi,N; R /53; H ) Myrcene (Xn,N; R /53-65; H ) Acetophenone (Xn; R22-36; H ) ca. 3.5% ca. 27% ca. 20% ca. 20% ca. 2% ca. 15% ca. 1% < 1% Page 3 CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: CAS-Nr: EINECS-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Take affected persons out into the fresh air. Supply fresh air and keep patient calm. Get medical help. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. After ingestion: Drink plenty of water. Get medical help in case of discomfort. Most important Symptoms and Effects, both Acute and Delayed 4

4 4. 2. Page 4 Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. CO2, extinguishing powder, sand or earth Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: No special hazards. Wear self-contained respiratory protective device Further information: Cool exposed containers with water spray. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Provide adequate ventilation. Keep away from sources of ignition. Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent, saw dust) and dispose accordingly. See Section 13 for information on disposal. Instructions on safe handling: Avoid the formation of aerosol. Avoid contact with eyes. 5

5 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Page 5 Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a cool and well ventilated location. Avoid pollution of soil. Keep away from sources of ignition - do not smoke. Do not store together with: foodstuffs and animal feed. 3: Flammable liquids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled None known Parameters to be controlled (DE): Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Avoid contact with eyes. In case of long-term or higher exposure. Protective gloves Protective glove material: 6

6 Eye protection: Safety glasses with protective shields (EN 166). Page 6 Body protection: Protective clothing Environmental precautions: Do not allow entering sewerage system. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: liquid yellowish aromatic not determined not available not available Flash point: 57 C Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): not available no information available no information available not determined g/cm3 (20 C) not miscible not determined Auto-ignition temperature: > 200 C Decomposition temperature: 7

7 Viscosity, dynamic: not available Page Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: not available no information available not determined No further information. Stable if used according to specifications. Stable if used according to specifications. Unknown. Avoid heat and sources of ignition. Formation of highly flammable fumes/vapors. > 5000 mg/kg (rat) LD50, dermal: 8

8 LC50, inhalation: Page 8 Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Non irritating Non-irritating to eyes No information available Slightly sensitizing Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: LC50: 15.7 mg/l (48h, Leuciscus idus) EC50: > 40,4 mg/l (24h, Daphnia magna) EC20: 0.62 mg/l (0.5h; Pseudomonas fluorescens) Algae toxicity: Persistency and Degradability Bioaccumulation Mobility 9

9 Results of PBT- und vpvp Assessment Other Adverse Effects Page 9 Water hazard class: Harmful for fish and bacteria. Behaviour in sewage systems: Further ecological effects: Do not let product enter waterways or sewage system AOX Value: Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA 1993 UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ENTZÜNDBARER FLÜSSIGER STOFF, N.A.G. (Terpenin, Öl) FLAMMABLE LIQUID, N.O.S. (Turpentine, oil) ADR Class: 3 Hazard no.: 3 Classification code: Tunnel no.: F1 D/E IMDG Class (sea): 3 Hazard no.: 3 EmS No.: F-E, S-E IATA Class: Hazard no.: 3 Packaging Group ADR/RID: III IMDG: III IATA: III 10

10 Environmental Hazards Special Precautions for User Page 10 Labelling according ADR/RID: fish and tree Labelling according IMDG: fish and tree Classification as environmentally hazardous according IMDG: no not applicable Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.