Fluorescent Pigment Violet
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1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Fluorescent Pigment Violet Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Fluorescent pigment for the production of paint, printing inks and coatings Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Consumer use, cosmetics, body care products, food coloring Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: EUH208 May produce an allergic reaction. Safety designation: Take precautionary measures against static discharge. 2
2 P243 P261 P262 P270 P271 P273 P281 P285 P391 Page 2 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. Collect spillage Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Contains formaldehyde: can cause allergic reactions. Formaldehyde can be released when heated. This produkt is a mixture. Chemical Characterization: Information on Components / Hazardous Ingredients: Formaldehyde (T, Carc.Cat.3; R23/24/ ; H ); REACH Reg.No xxxx <0.1 % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Avoid contact with eyes, skin and clothes. Supply fresh air and seek medical advice in case of complaints. Remove contaminated clothing. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes. Seek medical attention if irritation persists After ingestion: Most important Symptoms and Effects, both Acute and Delayed No special measures required. Symptoms: No further information available. Effects: 3
3 No further information available Indication of any Immediate Medical Attention and special Treatment needed Page Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, carbon dioxide, extinguishing powder, water, water mist Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of irritating gases/vapors. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water Personal precautions: Environmental Precautions Avoid contact with skin and eyes. Do not ingest or inhale. Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Protective clothing, see Section 8. The usual precautionary measures are to be adhered to when handling chemicals. Avoid formation of dust. Provide adequate ventilation. Hygienic measures: Do not eat or drink during work. Do not smoke. 4
4 7. 2. Conditions for Safe Storage, including any Incompatibilities Page 4 Storage conditions: Store in tightly sealed containers in a dry room. Protect against overheating. Requirements for storage areas and containers: Information on fire and explosion protection: Do not store together with: oxidants. Take measures to prevent electrostatic discharge Storage class (VCI): Further Information: Specific End Use(s) When the product is applied at higher temperatures, formaldehyde is released. Provide adequate ventilation Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled: Formaldehyde (CAS ); TWA: 0.3 ppm, 0.37 mg/m3; 2 (I) Formaldehyde (CAS ); TWA, STEL: GB (EH40): 2 ppm, 2.5 mg/m3 ; FR (VLEP): 0.5 ppm, 1 ppm; NL (MAC): 0.15 ppm, 0.5 mg/m3 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Dust mask. Protective gloves (EN 374) Rubber or plastic gloves. 5
5 Safety glasses with protective shields (EN 166). Page 5 Body protection: Protective clothing Environmental precautions: No special measures required. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: powder violet neutral not available no information available no information available Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: insoluble Decomposition temperature: 6
6 No data available. Page Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity no information available not determined Stable if used according to specifications. Hazardous polymerisation will not occur. Avoid dusting near sources of ignition. Avoid heat. Avoid heat. Strong acids, strong bases and strong oxidizing agents. Carbon oxides, nitrogen oxides, sulfuric oxide, toxic fumes/vapors. LD50, oral: Formaldehyde: 600 mg/kg (rat) 7
7 LD50, dermal: Formaldehyde: 270 mg/kg (rabbit) Page 7 LC50, inhalation: Formaldehyde: mg/l (4h; rat) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Irritating to skin. Irritating to eyes. Can cause irritation of the respiratory system. Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: No relevant data found. No relevant data found. Formaldehyde: Carc. 1B (EC) No relevant data found. Formaldehyde: LC50: mg/l flow-through (96h; Pimephales promelas); LC50: 1510 µg/l static (96h; Lepomis macrochirus); LC50: 41 mg/l static (96h; Brachydanio rerio); LC50: 0,032-0,226 ml/l flow-through (96h, Oncorhynchus mykiss); LC50: mg/l static (96h, Oncorhynchus mykiss); LC50: mg/l static (96h; Pimephales promelas) Formaldehyde: LC50: 2 mg/l (48h; Daphnia magna); EC50: mg/l static (48h; Daphnia magna) no information available Algae toxicity: 8
8 Persistency and Degradability Bioaccumulation Formaldehyde: logpow Mobility Product is not water soluble Results of PBT- und vpvp Assessment No data available Other Adverse Effects Page 8 Water hazard class: 2 (German Regulation) (Assessment by list): hazardous. Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: In accordance with current regulations, product may be taken to an incineration plant. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IMDG Class (sea): 9
9 Hazard no.: Page 9 EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information The product/preparation is registered in the following national inventories: EINECS (EU), TSCA (US), AICS (AUS), DSL/NDSL (CA), PICCS (PH), KECL (KR), ENCS (JP), IECSC (CN) EC. REACH, Annex XIV, Candidate List of Substances of very High Concern (SVHC): not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.
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