MATERIAL SAFETY DATA SHEET Drawn up/updated: /

Transcription

1 MATERIAL SAFETY DATA SHEET Drawn up/updated: / Identification of the product and the company 1.1 Product s identification Zinc Oxide 1.2.Application feed additive, industrial raw material 1.3 Data of Company - manufacturer Przedsiębiorstwo ARKOP Sp. z o.o Bukowno ul. Kolejowa 34 A; POLAND tel.: , fax.: REGON P Responsible person Environmental specialist Msc. Arkadiusz Krzystanek tel arkadiusz.krzystanek@arkop.pl 1.4 Emergency telephone To company: (working hours: ) Emergency: 112 Fire department: Hazards identification 2.1 Substance classification GHS Classification Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects EC Classification N Environmentally hazardous product R: R50/53 - Very toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment 2.2 Labelling GHS Labelling Index no: Hazard pictograms Signal word Warning Hazard statements H410: Very toxic to aquatic life with long lasting effects. Precautionary statements P273: Avoid release to the environment. Page 1 of 8

2 EU directives labelling_ Symbol(s): N Warning sings: N Environmentally hazardous product R-phrases: 50/53 Environmentally hazardous product. Very toxic to aquatic organisms, may cause long-term adverse effects in aquatic environment. S-phrases: This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instruction /Material Safety Data Sheet. EC Number: EC Label 2.3 Another hazards 3. Composition / Information on ingredients: Synonyms: Zinc Oxide feed grade with Zn content 72 to 78%; Zinc Oxide technical grade CAS Number: Molecular mass: 81,37 Chemical formula: ZnO EC Number: Index Number: First Aid Measures 4.1 First Aid Measures description After inhalation: fresh air, consult doctor if feeling unwell After skin contact: wash off with water. After eyes contact: rinse out with water. After ingestion: contact the doctor if feeling unwell 4.2 Most important acute and late results of exposure After inhalation: possible symptoms of metal vapours disease after long inhalation After skin contact: light irritation After eyes contact: light irritation After ingestion: possible symptoms of poisoning after ingestion 4.3 Instructions for immediate medical aid and special treatment of victim Contact with the doctor in case victim feeling unwell after material inhalation or ingestion. Use first aid measures before doctor s arrival. 5. Fire-Fighting Measures 5.1 Suitable extinguishing measures Use extinguishing measures appropriate to other materials stored, appropriate to local circumstances and the surrounding environment. 5.2 Specific hazards during fire fighting: non-flammable substance. Ambient fire may Page 2 of 8

3 liberate hazardous vapours. Prevent fire extinguishing water from contaminating surface water or the ground water system. 5.3 Special protective equipment for fire-fighters: wear gas-tight protective clothing and respiratory protection equipment. 6. Accidental release measures 6.1 Personal precautions, protective equipment and procedures Avoid contamination with substance. Avoid dust inhalation. Ensure appropriate ventilation. Wear protective equipment Environmental precautions. Do not empty into drains. 6.3 Methods and materials for preventing and cleaning up pollution. Pick up dry substance mechanically. Avoid dust generation. Clean up contaminated area. Forward to disposal. Prevent access to water, sewers and soil 6.4 Use protective equipment mentioned in paragraph 8. Collected material considered as waste. Proceed according to paragraph Handling and storage 7.1 Advice on safe handling - Ensure sufficient air exchange (ventilation) Act according to good manufacturing practice and general rules of safety & hygiene handling the chemical substances. Use protective equipment mentioned in paragraph 8. Do not empty into drains. Observe label precautions. 7.2 Safe storage precautions, including all information about mutual incompatibilities tightly closed containers, dry place, up to 10 layers 7.3 Further information on storage conditions without limitations. 8. Exposure controls / personal protection 8.1 Control Parameters: (NDS, NDSCh, NDSP) - (in calculation to Zn- smokes), NDS: 5 mg/m 3, NDSCh: 10 mg/m Exposure control: Use appropriate systems of general and exhaust ventilation ensuring concentration of the product in air below set requirements (minimal air exchange 10 times / hour). It is suggested to equip workplace with shower and water spray for eyes rinsing. Design and manufacture of personal protection measures should ensure appropriate chemical protection and exclude all potential danger and inconveniences in foreseen workplaces. Personal protective equipment: Protective equipment should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. Respiratory protection Necessary when dust are generated Recommended Filter type: Filter P2 (acc. To DIN 3181) for solid and liquid particles of harmful substances Hand protection Full contact: Page 3 of 8

4 Glove material: nitrile rubber Glove thickness: 0,11 mm Break trough time: >480 min Splash contact: Glove material: nitrile rubber Glove thickness: 0,11 mm Break trough time: >480 min The protective gloves to be used must comply with the specification of EC directive 89/686/EEC and / or resultant standard EN374, eg. KCL 741 Dermatril L (full contact), KCL 741 Dermatril L (splash contact). The breakthrough times stated above were determined by KCL in laboratory tests acc. To EN 374 with samples of the recommended glove types. This recommendation applies only to the product stated in the safety data sheet and supplied by us as well as to the purpose specified by us. When dissolving or mixing with other substances and under conditions deviating from those stated in PN-EN374-3:1999 please contact the supplier of CE-approved gloves. Eye protection Safety glasses Hygiene measures Change contaminated clothing. Wash hands after working with substance. 9. Psychical and chemical properties 9.1 Basic psychical and chemical properties Appearance: solid, fine grinded Colour: grey, olive, dark green, brown Odour: odourless ph: ~ 7 (50 g/l H 2 O as suspension, 20 C) Melting temperature: ~ 1970 C Boiling temperature: no data available, sublimation point ~ 1800 C Self ignition temperature: not combustible Ignition temperature: not applicable Danger of explosion / range: not applicable low: high: Vapour pressure: no data available Density: 5,47 g/cm 3 (20 0 C) Bulk density : kg/m 3 Solubility: in water: ~ 1,6 mg/l (20 C) in organic solvents: no data available 9.2 Another information Solubility in fats: no data available Melting temperature: ~ C 10. Stability and reactivity 10.1 Reactivity - not reactive 10.2 Stability - Stable in normal circumstances 10.3 Hazardous reactions existence - may violently react with hydrogen peroxide and magnesium Page 4 of 8

5 10.4 Conditions to avoid - none 10.5 Incompatibles materials - none 10.6 Hazardous decomposition products: no data available 11. Toxicological information 11.1 Toxicological results information Acute toxicity: LD50 (orally, rat): 7950 mg/kg, LC0 (inhale, rat): 5mg/m 3 /3h, LDL 0 (orally, human): 500 mg/kg, LC 50 (inhale, mouse): 2500 mg/m 3. Skin irritation Slight irritation Eye irritation Slight irritation Sensitisation Human experience Result: negative (IUCLID) Genotoxicity in vitro Mutagenicity (mammal cell test): Result: positive (IUCLID) Ames test Result: negative (IUCLID) Further information The following applies to zinc compounds in general: only slightly absorbable via the gastrointestinal tract. Astringent effect on mucous membranes. Metal-fume fever after inhalation of large quantities. Further data Handle in accordance with good industrial hygiene and safety practice. 12. Ecological information 12.1 Ecotoxicity Toxicity to fish LC50 Species: Oncorhynchus mykiss (rainbow trout) Dose: 1,1 mg/l Exposure time: 96 h (ECOTOX Database) Toxicity to daphnia and other aquatic invertebrates EC50 Species : Daphnia magna (Water flea) Dose: > mg/l Exposure time: 48 h (ECOTOX database) Toxicity to algae IC50 Species: Pseudokirchnehella subcapitata (green algae) Dose: 0,17 mg/l Exposure time: 72 h 12.2 Persistence and degradability - Biodegradability The methods for determining the biological degradability are not applicable to inorganic Page 5 of 8

6 substances Bioaccumulation ability - chemical safety report has not been conducted 12.4 In soil mobility - chemical safety report has not been conducted 12.5 PBT vpvbc properties results - chemical safety report has not been conducted 12.6 Additional adverse effects Toxic for aquatic organisms. may cause long-term adverse effects in aquatic environment. Prevent access to water, sewer and solid. Inorganic substance. Do not cause biological deficiency of oxygene. 13. Disposal considerations 13.1 Disposal methods Disposal classified and considered as others than hazardous. Packaging must be disposed in compliance with respective national-specific regulations or must be passed to a packaging return system. Returning packaging to the Seller. Company ARKOP Sp. z o.o. dispose or recover chemical substances & their packaging bought in Company ARKOP Sp. z o.o. Materials & packaging deliveries have to be agreed each time with the Company ARKOP Sp. z o.o. Utilization of the wastes has to be done by specialized companies. Single-use packaging should be treated as waste. Disposal of collected wastes should be agreed with appropriate authorities. 14. Transport information 14.1 UN Number: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Labels & plates Transport hazard class - Class: 9, Hazard number Packing group - III, Packing instructions P, IBC, LR, R 14.5 Environment hazard Environmentally hazardos substance 14.6 Special safety pracautions Special regulations. Land transport 274, 601, CV13, V13 Cistern code SGAV, LGBV, AT Tunel code E 14.7 Bulk transport allowed special regulations W1, BK1, BK2 Another information Road transport RID/ADR Packign group : III. Class: 9,Tunells E, Label number 9 Hazard sign: 90 Sea transport: Packing group: III. Ems F-A S-F Class: 9 Page 6 of 8

7 Air transport UN/ID No 3077 PG III Transport - covered transport means, max. number of transported layers Regulatory information 15.1 Specific substance regulation for safety, health and environmental protection. Substance classification GHS Classification Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects EC Classification N Environmentally hazardous product R: R50/53 - Very toxic for aquatic organisms, may cause long-term adverse effects in the aquatic environment Labelling GHS Labelling Index no: hazard pictograms Signal word Warning Hazard statements H410: Very toxic to aquatic life with long lasting effects. Precautionary statements P273: Avoid release to the environment. EU directives labelling Symbol(s): N Warning sings: N Environmentally hazardous product R-phrases: 50/53 Page 7 of 8 Environmentally hazardous product. Very toxic to aquatic organisms, may cause long-term adverse effects in aquatic environment.

8 S-phrases: This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instruction /Material Safety Data Sheet. EC Number: EC Label Major Accident Hazard Legislation: 96/82/EC Update: 2003 Dangerous for the environment 9a Quantity 1 : 100t Quantity 2: 200 t REACH PRE-Registration no: EU Legislation EC Regulation 1272/2008/EC from 16 December 2008 r for substances and mixtures classification, labelling and packaging amending and repealing directives 67/548/EEC and 1999/45/EC and amending EC Regulation 1907/2006 of European Parliament and Council for registration, assessment, authorization and applied restrictions for chemicals (REACH), creation of European Agency for Chemicals, amending directive 1999/45/EC and repealing Concuil regulation EEC 793/93 i and Commission Regulation (EC) 1488/94, and Council directive 76/769 EEC and Commission directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/ EC Chemical safety assessment - has not been conducted_ 16. Other information Actualization according to amended legislation R Risk phrases Index: R 50/53 - Very toxic to aquatic organisms; may cause long term adverse effects in the aquatic environment. H statements index: H410: Very toxic to aquatic life with long lasting effects. The information contained herein is based on our present knowledge and experiences concerning safety use of the product. The information can be only considered as advice for safe handling of the product. Main sources: ULMANN'S ENCYCLOPEDIA OF INDUSTRIAL CHEMISTRY THE MERCK INDEX, THIRTEENTH EDITION THE VAPOUR PRESSURE OF PURE SUBSTANCES, ELSEVIER, S.P.C SAFETY DATA SHEETS CIOP INORGANIC CHEMISTRY - BIELANSKI REGISTRY TOXIC EFFECTS OF CHEMICAL SUBSTANCES INDUSTRIAL HYGIENE AND TOXICOLOGY Page 8 of 8