Safety Data Sheet. according to Regulation (EC) No 1907/2006. UV-Plus Purifier

Transcription

1 Page 1 of 9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Uses advised against professional use. The UV Plus Purifier is a gas cleaning system for exclusive use in SPECTRO OES products. not known 1.3. Details of the supplier of the safety data sheet Company name: SPECTRO Analytical Instruments GmbH Street: Boschstr. 10 Place: D Kleve Responsible Department: info@tge-consult.de 1.4. Emergency telephone number: International: SPECTRO NCEC North America: Further Information The product is classified as a device. Providing the Safety Data Sheet takes place on a voluntary basis for information purposes. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Indications of danger: N - Dangerous for the environment R phrases: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. GHS classification Hazard categories: Self-heating substance or mixture: Self-heat. 1 Hazardous to the aquatic environment: Aquatic Acute 1 Hazardous to the aquatic environment: Aquatic Chronic Label elements Precautionary statements P273 Avoid release to the environment. Additional advice on labelling Not required because hazardous substances are incorporated in the material and there is no risk in case of skin contact, inhalation or ingestion as long as the material is properly handled and stored. (67/548/EEC VI 9.3 ; EC 1272/2008 I ) There is no requirement for the product to be specially labelled according to EC directives or the corresponding national laws Other hazards This article doesn't contain dangerous substances or preparations intended to be released under normal or reasonably foreseeable conditions of use. SECTION 3: Composition/information on ingredients 3.2. Mixtures

2 Page 2 of 9 Chemical characterization Catalyst. The UV Plus Purifier is a gas cleaning system for exclusive use in OES SPECTRO products. Hazardous components EC No CAS No Index No REACH No Chemical name Classification GHS classification Quantity activated Copper Oxide Self-heat. 1; H251 Copper oxide N - Dangerous for the environment R50-53 Aquatic Acute 1, Aquatic Chronic 1; H400 H410 Bariumoxide Xn - Harmful R20/22 Acute Tox. 4, Acute Tox. 4; H302 H332 < 50 % < 50 % < 3 % Full text of R and H phrases: see Section 16. zinc oxide N - Dangerous for the environment R50-53 Aquatic Acute 1, Aquatic Chronic 1; H400 H410 Further Information Product does not contain listed SVHC substances. < 1 % SECTION 4: First aid measures 4.1. Description of first aid measures General information In case of accident or if you feel unwell, seek medical advice immediately (show safety data sheet if possible). After inhalation In case of accident by inhalation: remove casualty to fresh air and keep at rest. In all cases of doubt, or when symptoms persist, seek medical advice. After contact with skin In the event of a damaged container. If material escapes: After contact with skin, wash immediately with: Water. In all cases of doubt, or when symptoms persist, seek medical advice. After contact with eyes In the event of a damaged container. If material escapes: Rinse immediately carefully and thoroughly with eye-bath or water. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion In the event of a damaged container. If material escapes: Rinse mouth thoroughly with water. Let water be swallowed in little sips (dilution effect). In all cases of doubt, or when symptoms persist, seek medical advice.. Most important symptoms and effects, both acute and delayed No information available.

3 Page 3 of Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media The product itself is not combustible. In the event of a damaged container. If material escapes: D powder. Dry sand. Unsuitable extinguishing media Water Special hazards arising from the substance or mixture Can be released in case of fire: Gas/vapours, harmful Advice for firefighters Wear a self-contained breathing apparatus and chemical resistant suit. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Extinguishing materials should be selected according to the surrounding area. Use water spray/stream to protect personnel and to cool endangered containers. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Warning: May cause fire. In case of fire, use fire extinguisher class D Environmental precautions Do not empty into drains or the aquatic environment. In case of gas being released or leakage into waters, ground or the drainage system, the appropriate authorities must be informed Methods and material for containment and cleaning up Dispose of only deactivated catalyst residues. Pick up carefully when dry. Avoid contact with water. Treat the assimilated material according to the section on waste disposal. Clean contaminated objects and areas thoroughly observing environmental regulations Reference to other sections See protective measures under point 7 and 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Protect containers against damage. Advice on protection against fire and explosion Protect containers against damage. Usual measures for fire prevention Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels

4 Page 4 of 9 Advice on storage compatibility Further information on storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Copper, dusts and mists (as Cu) - 1 TWA (8 h) WEL Additional advice on limit values 8.2. Exposure controls Appropriate engineering controls No special measures are necessary. Protective and hygiene measures No special measures are necessary. Eye/face protection Eye protection: not required. Hand protection Hand protection: not required. Respiratory protection Origin - 2 STEL (15 min) WEL With correct and proper use, and under normal conditions, breathing protection is not required. Use a positive-pressure air-supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. Environmental exposure controls No special precautionary measures are necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Initial boiling point and boiling range: Flash point: Explosive properties Lower explosion limits: solid Test method

5 Page 5 of 9 Upper explosion limits: Ignition temperature: Oxidizing properties In the event of a damaged container. If material escapes: Self-heating substances and mixtures May cause fire. Vapour pressure: Water solubility: Viscosity / dynamic: Solvent content: SECTION 10: Stability and reactivity Reactivity No information available Chemical stability Stable under normal storage and handling conditions Possibility of hazardous reactions No information available Conditions to avoid Protect against: UV-radiation/sunlight. heat. 0% - Data concerning the Directive 1999/13/EC on the limitation of emissions of volatile organic compounds (VOC-RL) Incompatible materials Substances or mixtures which, in contact with water emit flammable gases. Combustible substance. Oxidizing agents. Emission of air/oxygen Hazardous decomposition products Can be released in case of fire: Gas/vapours, harmful. SECTION 11: Toxicological information Information on toxicological effects Toxicocinetics, metabolism and distribution No data available. Acute toxicity

6 Page 6 of 9 Acute toxicity CAS No Chemical name Exposure routes Copper oxide oral Method Dose Species Source LD50 >2500 mg/kg Rat. ECHA dossier dermal LD50 >2000 mg/kg Rat. ECHA dossier Bariumoxide oral zinc oxide ATE 500 mg/kg inhalative vapour ATE 11 mg/l inhalative aerosol ATE 1,5 mg/l oral LD50 > 5000 mg/kg Rat. IUCLID Irritation and corrosivity Sensitising effects Copper oxide: no danger of sensitization. literature infomation: ECHA Dossier STOT-single exposure Severe effects after repeated or prolonged exposure No information available. Carcinogenic/mutagenic/toxic effects for reproduction Copper oxide: Ames test negative. literature infomation: ECHA Dossier Aspiration hazard Specific effects in experiment on an animal No data available. SECTION 12: Ecological information Toxicity No data available Persistence and degradability The methods for determining the biological degradability are not applicable to inorganic substances Bioaccumulative potential No indication of bio-accumulation potential Mobility in soil No data available Results of PBT and vpvb assessment The components in this formulation do not meet the criteria for classification as PBT or vpvb. Further information Do not empty into drains or the aquatic environment.

7 Page 7 of 9 SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Must not be disposed with household waste. Refer to manufacturer/supplier for information of recovery/recycling. Contaminated packaging SECTION 14: Transport information Land transport (ADR/RID) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide) II Classification code: S4 Special Provisions: 274 Limited quantity: 0 Transport category: 2 Hazard No: Tunnel restriction code: 40 D/E Other applicable information (land transport) Excepted quantity: E2 Inland waterways transport (ADN) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: II Hazard label: SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide) Classification code: S4 Special Provisions: 274 Limited quantity: 0 Other applicable information (inland waterways transport) Excepted quantity: E2 Marine transport (IMDG) UN number: UN UN proper shipping name: Transport hazard class(es): SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide)

8 Page 8 of Packing group: Hazard label: II Marine pollutant: YES Special Provisions: 274 Limited quantity: 0 EmS: F-A, S-J Other applicable information (marine transport) Excepted quantity: E2 Air transport (ICAO) UN number: UN UN proper shipping name: Transport hazard class(es): Packing group: Hazard label: SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide) II Special Provisions: Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: A3 Forbidden Other applicable information (air transport) Passenger-LQ: Forbidden Excepted quantity: E Environmental hazards ENVIRONMENTALLY HAZARDOUS: yes kg kg Danger releasing substance: Special precautions for user refer to chapter 6-8 Copper oxide Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 1999/13/EC (VOC): Additional information Not subject to regulation 96/82/EC. National regulatory information 0%; VOC Directive 2004/42/EC: 0 g / L

9 Page 9 of 9 Water contaminating class (D): 1 - slightly water contaminating Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Changes Rev. 1,0 Initial release Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent NOAEL: No observed adverse effect level Full text of R phrases referred to under Sections 2 and 3 20/22 Harmful by inhalation and if swallowed. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 53 May cause long-term adverse effects in the aquatic environment. Full text of H statements referred to under Sections 2 and 3 H251 Self-heating: may catch fire. H302 Harmful if swallowed. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)