Scaling Down Ammonia Production Modular solutions for constructability. Carrie Lalou Linde Engineering North America October 16, 2017
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1 Scaling Down Ammonia Production Modular solutions for constructability Carrie Lalou Linde Engineering North America October 16, 2017
2 Linde Engineering - Hydrogen & Synthesis Gas product line Served market sectors Hydrogen Refining Ammonia Chemicals Carbon Monoxide Formic Acid Acetic Acid MDI TDI Polycarbonates DMF Formamide Propionic Acid Synthesis Gas Methanol Iron ore reduction Liquid Fuels Oxoalcohols Fatty Acids SNG DME Acetic Acid Carbon Dioxide EOR Food Processing Sequestration Welding Cooling Freezing Methanol Fuel DME Acetic Acid MTO MTP Ammonia Fertilizer Explosives Chemicals Sulfur Base Chemicals 2
3 Why are we talking about NH 3 today? US - most efficient & environmentally friendly NH 3 production; historically imports from areas with fewer regulations and less efficient operations Last decade: 26 US plants closed due to high NG prices; imports increased to highest levels; Offshore plants were constructed based on low cost NG saw the restart of many US plants; $1.9B invested per year from in updating, debottlenecking, expanding and restarting existing NH 3 facilities Planned new NG based NH 3 production in North America Installed NH3 Capacity, MM mtpa New NH3 Capacity, MM mtpa Planned new capacity will offset remaining imports Sources: The Fertilizer Institute, ammoniaindustry.com, Agrium website; USGS Nitrogen Outlook 3
4 Getting the products to the users Footer 4 The CF Industries logo is a registered trademark of CF Industries Holdings, Inc.; KEYTRADE is a registered trademark of Keytrade AG; ICIS is a registered trademark of Reed Business Information Limited.
5 Over ground NH 3 transportation costs are prohibitive In the US, consumers of NH 3 based fertilizers are mostly mid-continent i.e. the Corn Belt (88% of domestic NH 3 consumption is fertilizers) US NH 3 and other fertilizers are generally produced in the Gulf coast where the cheapest, most abundant gas is located Rail costs are escalating; insurance costs are sky-high US export market may soon be more attractive than over-ground sale to mid-continent users; while ocean freight for NH 3 tankers can add ~$50/tonne, it is still competitive in overseas market where NG is >$3/mmbtu. SNAPSHOT September 2016: NG (Texas - Industrial) = NG (Kansas - Industrial)= NG (Nebraska - Industrial)= NG (Iowa - Industrial) = NH 3 USGC (NOLA) = NH 3 US Southern Plains = NH 3 US Corn Belt = $3.15/kscf $3.69/kscf $4.08/kscf $4.96/kscf $245/mt $299/mt $367/mt ~$1.80/kscf spread ~$120/mt spread (~$45/mt is from NG) 27/10/2017 Sources: USGS N 2 (Fixed) Ammonia report; DuncanSeddon.com; The Fertilizer Institute; Market Realist; EIA; 5
6 Linde solution bringing NH 3 production to the consumers 27/10/2017 6
7 Drive cost out by reducing on-site construction Building with modularized and containerized plants Modularized hydrogen plants Capacity: 300 to 28,000 Nm 3 /hr Ultra small-scale, skidded H 2 plant with capacities up to 300 Nm 3 /hr LCO MTPD Modularized CO 2 plants Modularized plants for sulfur recovery (SRU) 7
8 Linde Ammonia Concept (LAC) Light & heavy hydrocarbon feedstocks A combination of proven technologies Hydrocarbon Feed Air H 2 Unit N 2 Unit Pure H 2 Pure N 2 Ammonia Synthesis NH 3 Generation of an inert-free ammonia synthesis gas from inert free H 2 + N 2 Adjustable CO 2 /NH 3 product ratios Feedstock flexibility from light hydrocarbon feedstocks (LAC.L) to heavy hydrocarbon feedstocks (LAC.H) Flexibility for valuable by-products and process integration Linde-owned technologies: Air Separation Reforming Technologies Rectisol Wash unit Pressure Swing Adsorption Isothermal Shift Conversion Catalytic Oxidation Nitrogen Wash Units 8
9 Linde s Hydro-Chem Standardized and modularized H 2 plants Degree of Standardization Balance of the Plant Box Reformer Container Highly Modularized Standard Design Packages Containerized "HydroPrime " Modularized Can Reformer Modularized Box Reformer Box Reformer Standard Concept ~ 0,295 MMSCFD ~ 330 Nm³/h ~15 MMSCFD ~ Nm³/h ~ 25 MMSCFD ~ Nm³/h H 2 -capacity 9
10 Capital is King in small-scale mid-continent NH 3 production Modular construction can nearly mirror $/tonne costs as larger stick built plants $700,000 Modular vs Stick Built $600,000 $/mtpd Installed Cost - USGC $500,000 $400,000 $300,000 $200,000 $100,000 $ NH3 Capacity - mtpd 27/10/2017 In-house developed budgetary estimations for EPC and EPF-C USGC, no NH 3 storage included, clear and level site, etc. 10
11 Linde s long history in hydrogen & synthesis gas Total LSTK E/EP Max. installed capacity Hydrogen plants ,000 Nm 3 /hr H 2 HyCO/ syngas plants ,000 Nm 3 /hr H 2 +CO Ammonia plants ,350 mtpd CO 2 plants 30 2,065 mtpd Sulfur plants ,000 mtpd Rectisol units ,300,000 Nm 3 /hr Syngas Chemical CO 2 wash units ,000 Nm 3 /hr Syngas/NG Low temperature H 2 /CO separation ,000 Nm 3 /hr CO Nitrogen wash units ,000 Nm 3 /hr Syngas Cryogenic C 3 /C 4 recovery ,000 mtpa PSA units ,000 Nm 3 /hr H 2 Linde operated H 2 /CO plants ,000 Nm 3 /hr H 2 +CO 11
12 Collaborate. Innovate. Deliver. Thanks for your attention.
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