Safety Summary. Monocalcium Phosphate
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1 AB Lifosa, 50, Juodkiskio g. 50, LT-57502, Kedainiai, Lithuania Safety Summary Global Product Strategy (GPS) according to the recommendations of International Council of Chemical Associations (ICCA) as the fulfillment of the obligations under the Strategic Approach to International Chemicals Management (SAICM) of United Nations (UN). Monocalcium Phosphate This safety summary is provided within the scope of ICCA Global Product Strategy (GPS) to provide to the general public. GPS safety summary includes explanations on the possible chemical hazards and/or exposure scenarios, as well as information on safe handling and risk management. This summary is not intended to provide technical information on emergency actions, medical information or information on treatment in case of exposure. 1. General information Producer: AB Lifosa Address: 50, Juodkiskio g. 50, LT-57502, Kedainiai, Lithuania Tel.: + ( ) Fax: + ( ) info@lifosa.com 2. Substance identification Trade name Synonyms Chemical Name CAS-No EC-No Molecular formula Са(Н2Р04)2 Structural formula Monocalcium Phosphate Calcium bis(dihydrogenorthophosphate) MCP Calcium dihydrogenphosphate 3. Product Uses Produced from specially prepared (fluorine-free) wet-process phosphoric acid and calcite material. MCP is used as a food additive for domestic animals and birds. Food containing MCP provides animals with calcium and phosphorus, which promotes forming hard bone stock and skeleton, improves functions of animal organism, metabolism, and function of nervous, immune and reproductive systems, increasing its
2 productivity. Mineral additives of such compounds are especially recommended for feeding herbivorous animals. Basic technical characteristics according to IST :2016 Main specifications Норма для производителя Lifosa MCP 22,7 (0,2-1,4) Lifosa MCP 22,7 (0,5-2) 1. Total phosphorus (P), %, not less than 22,7 22,7 2. Calcium (Ca), %, not less than ph (1% solution), not less than 3,3 3,3 4. Moisture, %, not more than Ashes insoluble in 3N HCl, %, not more than Fluorine (F), mg/kg, not more than Arsenic (As), mg/kg, not more than Lead (Pb), mg/kg, not more than Mercury (Hg), mg/kg, not more than 0,1 0,1 10. Granulometry: mm, %, not less 95 - than mm, %, not less than Physical/Chemical Properties Physical state powder Colour white Odor odorless Explosive properties No data available Flammability No data available Oxidizing properties No data available Molecular Weight g/mol Melting point / melting range 200 ph >3.3 Density 2.22 g/cm 3 at 20 C Bulk density kg/m 3 Water solubility 18 g/l at 30 C 5. Health information 5.1 DNEL (Derived No-Effect Level)/DMEL (Derived Minimal Effect Level) for workers Inhalation - Acute - systemic effects, mg/m 3 : No data available Inhalation - acute - local effects, mg/m 3 : No data available Inhalation - long-term - systemic effects, mg/m 3 : 4.07 Inhalation - long-term - local effects, mg/m 3 : No data available Dermal - acute - systemic effects, mg/kg bw day: No data available Dermal - acute - local effects, mg/kg bw day: No data available Dermal - long-term - systemic effects, mg/kg bw day: No data available Dermal - long-term - local effects, mg/kg bw day: No data available Oral - acute - systemic effects, mg/kg bw day: No data available Oral - acute - local effects, mg/kg bw day: No data available Oral - long-term - systemic effects, mg/kg bw day: No data available Oral - long-term - local effects, mg/kg bw day: No data available DNEL (Derived No-Effect Level)/DMEL (Derived Minimal Effect Level) for consumers Page 2 of 6
3 Inhalation - Acute - systemic effects, mg/m 3 : No data available Inhalation - acute - local effects, mg/m 3 : No data available Inhalation - long-term - systemic effects, mg/m 3 : 3.04 Inhalation - long-term - local effects, mg/m 3 : No data available Dermal - acute - systemic effects, mg/kg bw day: No data available Dermal - acute - local effects, mg/kg bw day: No data available Dermal - long-term - systemic effects, mg/kg bw day: No data available Dermal - long-term - local effects, mg/kg bw day: No data available Oral - acute - systemic effects, mg/kg bw day: No data available Oral - acute - local effects, mg/kg bw day: No data available Oral - long-term - systemic effects, mg/kg bw day: No data available Oral - long-term - local effects, mg/kg bw day: No data available 5.2 Toxicity value Acute oral toxicity LD50 (rats) mg/kg: Acute dermal toxicity LD50 (rats) mg/kg: 2000 Acute inhalation toxicity - gas: No data available Acute inhalation toxicity - vapor: No data available Acute inhalation toxicity - dust/mist: No data available Chronic oral toxicity: No data available Chronic dermal toxicity: No data available Chronic inhalation toxicity: No data available 5.3 Irritation/Corrosivity/Sensitization No data available 5.4 CMR-effects No data available 5.5 Specific target-organ toxicity No data available 6. Environmental information 6.1 Predicted No Effect Concentration (PNEC) PNEC aqua - freshwater: No data available PNEC aqua - marine water: No data available PNEC aqua - intermittent releases: No data available PNEC sediment - freshwater: No data available PNEC sediment - marine water: No data available PNEC soil: No data available PNEC STP: Toxicity value Short-term toxicity to fish LC50 (96 h, mg/l): No data available Long-term toxicity to fish NOEC (mg/l): No data available Short-term toxicity to aquatic invertebrates EC50 (48h, mg/l): No data available Long-term toxicity to aquatic invertebrates NOEC (mg/l): No data available Toxicity to aquatic algae IC50 (72 h, mg/l): No data available NOEC (mg/l): No data available Toxicity to microorganisms EC50 (mg/l): No data available NOEC (mg/l): No data available Page 3 of 6
4 6.3 Environmental fate Phototransformation in air: No data available Phototransformation in water: No data available Phototransformation in soil: No data available Hydrolysis: No data available Biodegradation in water: screening tests: No data available Biodegradation in water and sediment: simulation tests: No data available Biodegradation in soil: No data available Bioaccumulation: aquatic / sediment: No data available Bioaccumulation: terrestrial: No data available Adsorption / desorption: No data available Henry's Law constant: No data available PBT and vpvb assessment: No data available 7. Exposure Assessment See section Recommendations on Risk Management Closed manufacturing processes (if necessary), performance forced-air or local exhaust ventilation at the work zone, use of personal protection equipment. Minimization of quantity of exposed workers. Use of special dispensers and pumps designed to prevent splashes / spills. Effective removal of contaminants. Minimization of manual phases. Avoidance of contact with contaminated tools and objects. Regular cleaning of equipment and work area. Verification of the appropriate use of risk management measures. Ensure high levels of personal hygiene. Inform consumers through labeling. 9. Classification and labelling 9.1 Classification Classification according to Regulation (EC) No 1272/2008: Not classified. 9.2 Labelling Labelling according to Regulation (EC) No 1272/2008: Not labelled. 10. Registartion information Monocalcium Phosphate Monocalcium Phosphate is exempted from obligations of Regulation (EC) No. 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) 11. Conclusion In the Product Safety Summary for risk calculations the following Exposure scenarios are used: ES1 - M1 Identifiers Market Sector Titles of exposure scenarios and the related contributing scenarios Manufacture - Industrial manufacture / import - batch synthesis - Manufacture (ERC 1) - Worker contributing scenario (PROC 3) Page 4 of 6
5 ES2 - M2 ES3 - F1 ES4 - F2 ES5 - IW1 ES6 - PW1 ES7 - C1 - Worker contributing scenario (PROC 4) Manufacture - Manufacture of MCP - Manufacture (ERC 1) - Worker contributing scenario (PROC 1) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 3) - Worker contributing scenario (PROC 4) Formulation - Industrial end use as fertiliser - Formulation (ERC 2) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 7) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) Formulation - Formulation of fertilizers - Formulation (ERC 2) - Worker contributing scenario (PROC 2) - Worker contributing scenario (PROC 14) Use at industrial site - Use at industrial site - Use at industrial site (ERC 4) - Worker contributing scenario (PROC 5) - Worker contributing scenario (PROC 7) - Worker contributing scenario (PROC 13) - Worker contributing scenario (PROC 14) Use by professional worker - Use by professional worker - Use by professional worker (ERC 8a) - Worker contributing scenario (PROC 19) Consumer Use - Use as fertilizer - Consumer Use (ERC 8e) - Consumer contributing scenario (PC 12) Page 5 of 6
6 GPS safety summary used most unfavorable exposure scenarios. When the impact of the scenarios considered the risks from the substance effect on the employee monitored. In certain cases, controlled risk levels are achieved by the use of standard technical, organizational and individual conditions, measures and means to reduce the likelihood of exposure to the workers, which are designed and function in the company. When considering the impact of the scenarios on the impact of the risks of substances controlled by the consumer. In certain cases, requires adequate control of risk, which primarily depends on the application of preventive measures by the user. The impact of the substance on the environment on the stages of the life cycle (production, manufacture, processing) is not carried out due to the absence of handles in place to assess. The analysis shows that risks could be adequately controlled through the use of standardized technical, organizational measures, which are designed and operated by AB Lifosa. 12. Contact information For more information on the matter, please contact at: or visit: Date of issue 04-Aug-2016 Note For more information on first aid measures, fire fighting, prevention and elimination ofaccidents and emergency situations and their consequences, recycling, safe use andtransportation and storage rules, refer to the Safety Data Sheet (SDS) for this chemical orchemical products. While the data and information contained herein are presented in good faith and believedto be accurate at the date of printing, it is provided for your guidance only and may be revised inthe future. No warranties of any kind, either express or implied, of merchantability, fitness for aparticular purpose or of any other nature are made regarding the data or information provided.further, the Company assumes no obligation or liability whatsoever resulting from use of or reliance on the data and information given. The Company makes no commitment to update or correct any information that appears onthe Internet. Page 6 of 6
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