: CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted GHS07

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1 Date of issue: 03/12/2014 Revision date: 09/02/2015 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : D/E Resin 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc W Irving Park Road, Schaumburg, IL USA , during normal business hours EC Representative: Bisico France, 120, allée de la Coudoulette, Lançon de Provence, France Telephone: Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 Eye Irrit. 2 H315 H319 Skin Sens. 1 H317 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: Outside the U.S.: , collect calls accepted Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Irritant GHS07 : bisphenol A glycidylmethacrylate, 2-hydroxyethyl methacrylate, stabilized : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation : P264 - Wash hands thoroughly after handling P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose in a safe manner in accordance with local/national regulations P270 - Do not eat, drink or smoke when using this product 2.3. Other hazards 09/02/2015 EN (English) 1/6

2 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC bisphenol A glycidylmethacrylate (CAS No) (EC no) Xi; R41 Xi; R37/38 R43 2-hydroxyethyl methacrylate, stabilized (CAS No) (EC no) (EC index no) X Xi; R36/38 R43 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] bisphenol A glycidylmethacrylate (CAS No) (EC no) hydroxyethyl methacrylate, stabilized (CAS No) (EC no) (EC index no) X Full text of R- and H-phrases: see section Eye Dam. 1, H318 Skin Sens. 1, H Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). If skin irritation or rash occurs: : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 09/02/2015 EN (English) 2/6

3 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing mist, vapours. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. : Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Viscous Liquid. Colour : Straw. Odour : acrylic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : 150 C Flash point : 75 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) n flammable Vapour pressure Relative vapour density at 20 C Relative density : > 1 Solubility : Insoluble in water Log Pow Viscosity, kinematic 09/02/2015 EN (English) 3/6

4 Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat > 5000 mg/kg (Rat) LD50 dermal rabbit > 3000 mg/kg (Rabbit) Skin corrosion/irritation : Causes skin irritation. Causes skin irritation Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms :. SECTION 12: Ecological information Toxicity LC50 fishes mg/l (96 h; Pimephales promelas; Measured concentration) LC50 fish mg/l (48 h; Leuciscus idus) Persistence and degradability D/E Resin Persistence and degradability 09/02/2015 EN (English) 4/6

5 bisphenol A glycidylmethacrylate ( ) Persistence and degradability Biodegradability in water: no data available. Persistence and degradability Readily biodegradable in water. Biodegradability in soil: no data available. Adsorbs into the soil Bioaccumulative potential D/E Resin Bioaccumulative potential bisphenol A glycidylmethacrylate ( ) Log Pow 4.94 (Estimated value) Bioaccumulative potential No bioaccumulation data available. BCF fish (Pisces; Calculated value) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Results of PBT and vpvb assessment Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) 09/02/2015 EN (English) 5/6

6 Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Not subject to ADN Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no substances with Annex XVII restrictions D/E Resin is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Water hazard class (WGK) : 1 - slightly hazardous to water Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of R-, H- and EUH-phrases: Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation R36/38 Irritating to eyes and skin R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact Xi Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/02/2015 EN (English) 6/6