TUV TESTING REPORT CHINA TRADE

Transcription

1 TUV TESTING REPORT CHINA TRADE

2 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 1 of 10 Client: Address : Dodavatel ověřený firmou Olsson Europe, s.r.o. The following merchandise was (were) submitted and identified by the client as: Issued by: TÜV NORD (Hangzhou) Green Product Service Centre Technical Manager Name of Product: Water Bottle Test Model: Model May Cover: / P.O./ Ref.No. /

3 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 2 of 10 Material: TRITAN/ PP/ Silicon Rubber Buyer: / Supplier: / Sample Received: Oct.21, 2014 Test Period: Oct.21, Oct.27, 2014 Test Request: 1, In accordance with German Food, Articles of Daily Use and Feed Code of September 1, 2005 (LFGB), Section 30, 31 and DIN 51032:1986, AP (2004) 5, Commission Regulation (EU) No 10/2011 of 14 January 2011 and BfR. 2, As the client required, to determine the Polycyclic Aromatic Hydrocarbons (PAHs) contents of the submitted sample(s). Conclusion: Please refer to next pages When tested as specified, the tested parameters comply with the requirements as stated in the above. COMPONENT LIST/ LIST OF MATERIALS FOR BELOW TEST: No. Description Materials No. Components Materials Material Color 1 Silicon Rubber Washer 1# Silicon Rubber Washer PS Semi-transparent 2 Bottle Cover 2# Bottle Cover PP Blue 3 Rocking Ball 3# Rocking Ball PP Blue 4 Turret Body 4# Turret Body PP Blue 5 Glass Bottle 5# Glass Bottle Glass Transparent TEST RESULTS 1. Sensory and Odor Test 1.1 Sensory and Odor Test 10/2011 and its recently amendments No.202/2014, BfR With reference to DIN Test Condition: reflux temperature/ 1hour Test Media: Distilled Water No. of panelist: 6

4 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 3 of 10 Sample Testing Parameter Grading result Recommended Level Conclusion Complete Sample Transfer of Smell 0 <2.5 Pass Transfer of Taste 0 <2.5 Note: 1. < denotes less than 2. available grading are listed as below: Grading 0: no perceptible taste/ smell deviation 1: just perceptible taste/ smell deviation 2: weak taste/ smell deviation 3: clear taste/ smell deviation 4: strong taste/ smell deviation 2. Overall Migration 2.1 Overall migration With reference to 82/711/EEC with its amendments and No.10/2011 with its amendments for selection of condition and EN for selection of conditions and test method, EN aqueous food simulants bytotal immersion method, EN substitute test. Simulant used Time Temperature Permis sible 2# 3# 4# DI water 0.5hour mg/dm 2 <1mg/dm 2 <1mg/dm 2 <1mg/dm 2 3% Acetic Acid 0.5hour mg/dm 2 <1mg/dm 2 <1mg/dm 2 <1mg/dm 2 3. Catalyst Residue 3.1 Chromium, Vanadium and Zirconium content Acid digestion, followed byanalysis using InductivelyCoupled Argon Plasma Spectrometer Test Items 2# 3# 4# 1 Total Chromium mg/kg 10 <2 2.5 <2

5 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 4 of 10 2 Total Vanadium mg/kg 20 <5 < Total Zirconium mg/kg 100 <10 <10 <10 4. Specific migration of Heavy Metals 4.1 Specific Migration of Heavy Metals 10/2011 and its amendments, BfR Sample preparation in 3% Acetic acid at 100 for 0.5 hour, followed by analysis using Inductively Coupled Argon Plasma Spectrometer. Test Items Simulants Used Temperature& Time MDL 2# 3# 4# Barium, Ba 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Cobalt, Co 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Copper, Cu 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Iron, Fe 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Lithium, Li 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Manganese, Mn 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. Zinc, Zn 3% Acetic Acid 100 /0.5hour mg/kg n.d. n.d. n.d. 5. Lead and Cadmium Content 5.1 Lead and Cadmium content Acid digestion, followed byanalysis using InductivelyCoupled Argon Plasma Spectrometer Test Items 1# 2# 3# 4# 1 Total Lead mg/kg 40 <5 <5 <5 <5 2 Total Cadmium mg/kg 20 <2 <2 <2 <2

6 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 5 of Volatile organic matter (VOM) 6.1 Volatile organic matter With reference to LFGB BfR Part B Part II Section XV, May 2003 and LFGB section 35B (EG) Test Condition: 100, 0.5 hour Test Items 1 Volatile organic matter % # / 7. Extractable lead and cadmium 7.1 Extractable lead and cadmium 10/2011 and its amendments, BfR With reference to EN : Determination of the release of lead and cadmium from silicate surfaces other than ceramic ware, analysis was performed byatomic Absorption Spectrometer. Test Items Released Lead, mg/l s 5# / <0.1 <0.1 <0.1 <0.1 Limits Refer to below form 0.4 Test Items Released Cadmium, mg/l s 5# / <0.01 <0.01 <0.01 <0.01 Limits Refer to below form 0.05 Depth, mm 210

7 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 6 of 10 Diameter, mm 50 Capacity, L 0.5 limits for articles made from ceramics, glass ceramics with decorated inner surfaces, and for articles with enameled surfaces. Flatware Hollow-ware Tableware Kitchen Equipment Cooking & baking utensils, receptacles also used as packaging storage container Lead mg/dm 2 Cadmium mg/dm 2 Lead mg/kg Cadmium mg/kg Made from ceramic, glass and glass ceramics Enameled Made from ceramic, glass and glass ceramics Enameled Samples for enameled container, part of equipment and water heater Extractable component 8.1 Extractable component With reference to 61st Communication on testing of plastics in Bundesgesundheitsbl 46(2003) 362. Condition: 100 /0.5hour Simulants 1# / 1 DI water % 0.5 < % Acetic Acid % 0.5 <0.1 Simulants 3 10% Ethanol % 0.5 <0.1 1# / Re sult

8 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 7 of Peroxide Component 9.1 Peroxide component With reference to European pharmacopoeia, 2005 AppendixX F. Peroxide Value method A Simulants 1# / 1 Peroxide value - Absent Absent 10. Organotin Content 10.1 Organotin Content Solvent extraction followed by analysis using Gas ChromatographySpectrometer. Simulants MDL 1# / 1 Monobutyl tin, MBT mg/kg 1 Absent Absent 2 Dibutyl tin, DBT mg/kg 1 Absent Absent 3 Tributyl tin, TBT mg/kg 1 Absent Absent 4 Tetrabutyl tin, TeBT mg/kg 1 Absent Absent 5 Triphenyl tin, TPT mg/kg 1 Absent Absent 6 Monooctyl tin, MOT mg/kg 1 Absent Absent 7 Dioctyl tin, DOT mg/kg 1 Absent Absent 11. PAHs Content 11.1 PAHs Content

9 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 8 of 10 With reference to ZEK Document , Analysis was performed bygc-ms. Test Items MDL 4# / 1 Naphthalene mg/kg 0.2 n.d. 2 Acenaphthylene mg/kg 0.2 n.d. 3 Acenaphthene mg/kg 0.2 n.d. 4 Fluorene mg/kg 0.2 n.d. 5 Phenanthrene mg/kg 0.2 n.d. 6 Anthracene mg/kg 0.2 n.d. 7 Fluoranthene mg/kg 0.2 n.d. 8 Pyrene mg/kg 0.2 n.d. 9 Benzo[a]anthracene mg/kg 0.2 n.d. 10 Chrysene mg/kg 0.2 n.d. 11 Benzo[b]fluoranthene mg/kg 0.2 Refer to limits form category 1 n.d. 12 Benzo[k]fluoranthene mg/kg 0.2 n.d. 13 Benzo[a]pyrene mg/kg 0.2 n.d. 14 Indeno[1,2,3-cd]pyrene mg/kg 0.2 n.d. 15 Dibenzo[a,h]anthracene mg/kg 0.2 n.d. 16 Benzo[g,h,i]perylene mg/kg 0.2 n.d. 17 Benzo[j]fluoranthene mg/kg 0.2 n.d. 18 Benzo[e]pyrene mg/kg 0.2 n.d. Limits for PAHs in Products:

10 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 9 of 10 Parameter Category 1 Category 2 Category 3 Material in contact with foodstuff, or materials indented to be put in the mouth and toys for children aged < 36 months Materials with foreseeable contact to skin for longer than 30 seconds (long-term skin contact) and toys not covered by category 1 Materials with foreseeable contact to skin up to 30 seconds (short term skin contact) or without skin contact. Benzo[a]pyrene (mg/kg) Not detectable (<0.2) 1 20 Sum of 18 PAH (mg/kg) Not Detectable (<0.2) Remark : * If the limits of category 1 are surpassed but the limits of category 2 still met, the confirmation of suitability of contact with foodstuff or the oral mucosa can be verified by an additional specific migration test of the PAH components according to EN 1186 ff. and 64 LFBG The results of the migration test shall be evaluated according to law criteria for foodstuff. ******** TO BE CONTINUED *********

11 Reference No. : TRHZ Date : Oct.27, 2014 Page No.: 10 of 10 SAMPLE PHOTOS 1# 2# 3# 4# 5# Whole Product View ******** END OF REPORT *********

12 management importních projektů z ČLR Olsson Europe, s.r.o. VAT No.: CZ Klimentská 1216/46 Prague 1, ZIP: Czech Republic info@china-trade.cz Společnost Olsson Europe, spol. s r.o. je registrována u Městského soudu v Praze, spisová značka C