Safety data-sheet (2001/58/EC) Printed Revision (GB) Version 4.0 Kali Gazon

Transcription

1 ! 1. Identification of the substance/preparation Name of product Manufacturer/distributor Advice Emergency advice! Recommended intended purpose(s) Fertilizer! Effect of the substance / the formulation Plant nutrient COMPO GmbH & Co. KG Gildenstraße 38, Münster Postbox 2107, D Münster Phone , Fax Abt. ZU Phone Fax Abt. ZU Phone Composition/information on ingredients Chemical characterization Granules from Potassium Sulphate (K2SO4) and Magnesium Sulphate (MgSO4 x H2O) Equivalent 30% K2O and 10% MgO Potassium Sulphate (K2SO4) CAS-No , EC-No. (EINECS/ELINCS) Magnesium Sulphate Mohydrate (MgSO4 H2O) CAS-No , EC-No. (EINECS/ELINCS) Additional advice May contain anti-dusting additives in very small quantities. Designation according to EC European Community Fertilizer-Directive 76/116/EEC and supplementary directives: Sulphate of Potash Containing Magnesium Salt with S 30/10 3. Special hazards information for man and environment R-phrases t applicable Special hazards information for humans and environment 4. First aid measures General information In the event of persistent symptoms receive medical treatment. In case of inhalation Ensure of fresh air. In the event of symptoms refer for medical treatment. In case of skin contact In case of contact with skin wash off with water. In case of eye contact In case of contact with eyes rinse thoroughly with water. Page 1/7

2 In case of ingestion Rinse out mouth thoroughly with water. 5. Fire-fighting measures Suitable extinguishing material Product does t burn, fire-extinguishing activitys according to surrounding. Extinguishing material that may t be used for safety reasons Special exposure hazards arising from the substance, combustible products or resulting gases Sulfur oxide Special protective equipment for firefighters Do t inhale explosion and/or combustion gases. Additional information Collect contaminated firefighting water separately, must t be discharged into the drains. 6. Accidental release measures Personal precautions Avoid dust formation. Environmental precautions Do t discharge into the drains or bodies of water.. Methods for cleaning up/taking up Avoid dust formation. Disposal according to regulations. Flush away residues with water. Take up mechanically and send for disposal. Additional Information Informations for safe handling look up chapter 7. Informations for personal protective equipment look up chapter 8. Informations for disposal look up chapter Handling and storage Advice on safe handling No special measures necessary if used correctly. Take the usual precautions when handling with chemicals. Advice on protection against fire and explosion The product is t combustible. No special measures necessary. Requirements for storage rooms and vessels No special measures required. Advice on storage compatibility Keep away from water. Further information on storage conditions Store in a dry place. Storage group 13 Page 2/7

3 Information on storage stability Unlimited stability. 8. Exposure controls / personal protection Additional advice on system design Respiratory protection In case of dust formation wear micro dust mask. Hand protection Rubber gloves Eye protection tightly fitting goggles Skin protection General protective measures Hygiene measures Do t eat or drink when working. Brush soiled clothing. After work wash thoroughly. 9. Physical and chemical properties Form granules Colour whitish Odour odourless Data relevant for safety ph value in delivery state Value Temperature at Method Remark 7 20 C 180 g/l DIN neutral melting point > 1060 C Flash point Flammable solid Combustion temperature Autoignition t applicable Vapour pressure 0 mbar 20 C Density t determined 20 C 1013 hpa Bulk density abt kg/m3 Solubility in water abt. 180 g/l 20 C 1013 hpa Page 3/7

4 Value Temperature at Method Remark Solubility/other t determined Partition coefficient (log pow) t determined Combustion value 1 Oxidizing properties Explosive properties Additional information Physical dates refer to pure product. 10. Stability and reactivity Conditions to avoid No hazardous reactions kwn. Materials to avoid No hazardous reactions kwn. Hazardous decomposition products Sulphur dioxide Sulphurous oxides (SOx) Thermal decomposition Remark >700 C 11. Toxicological information Acute toxicity/irritability/sensitization Value/Validation Species Method Remark LD 50 acute oral 6600 mg/kg rat K 2 SO 4 Ref. (1) LD 50 acute dermal LC 50 acute inhalation t determined t determined Irritability skin experiences Irritability eye experiences Sensitization skin experiences Sensitization respiratory system experiences Page 4/7

5 Toxicity test (Additional information) No experimental indication of getoxic effects. Substance has mutagen activity ( Ames test ). Additional information The declarations of toxicology refer to main component. Our dates do t cover total texture toxic judgement. Follow the usual hygenic directives for handling with chemicals. 12. Ecological information Data on elimination (persistence and degradability) Elimination rate Method of analysis Method Validation Physicochemical degradability Biological degradability Degradability Biological eliminability t applicable Irganic product, cant be eliminated from the water by biological purification processes. t applicable Irganic product, cant be eliminated from the water by biological purification processes. t applicable Irganic product, cant be eliminated from the water by biological purification processes. t applicable Irganic product, cant be eliminated from the water by biological purification processes. Ecotoxicological effects Value Species Method Validation Fish LC mg/l (96 h) bleak DIN part 31 K2SO4 Ref. (2) Daphnia EC mg/l (48 h) Daphnia magna DIN part 11 K2SO4 Ref. (2) Algae EC mg/l (72 h) Scenedesmus subspicatus DIN part 33 K2SO4 Ref. (2) Bacteria EC20 > 20 g/l (16 h) Pseudomonas putida DIN part 8 K2SO4 Ref. (2) Behaviour in sewage plant When low concentrations are discharged correctly into adapted biological sewage treatment plants, interference with the degradation activity of activated sludge is t likely. Additional ecological information Value Method Remark AOX t applicable General regulation The informations to ecology refer to main component. Page 5/7

6 13. Disposal considerations Waste code No. Name of waste agrochemical waste other than those mentioned in Recommendations for the product In accordance with regulations for special waste, must be taken, after pretreatment, to an authorised special waste disposal site. Recommendations for packaging Uncontaminated packaging may be taken for recycling. Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken fot reuse. 14. Transport information Land and inland navigation transport (ADR/RID/GGVS/GGVE/ADNR) Remarks No hazardous material as defined by the prescriptions. Transport/further informations 15. Regulatory information Remarks for classification R-phrases t applicable S-phrases t applicable Special labelling for certain preparations National regulations Restriction of occupation Decree for case of interference/remarks Classification according to VbF/remarks t applicable VbF: is t subject to decree for compostible liquids. German TA LUFT remarks Water hazard class 1 KBwS-classification Other regulations, restrictions and prohibition regulations Page 6/7

7 16. Other information Recommendend uses and restrictions Further information The information contained herein is based on our present kwledge and is t meant to guarantee product properties. Recipients of our product must take responsibility for observing existing laws and regulations. Refer to product information paper. CAS-No. refers to pure substance. Sources of key data used Ref. (1): GISAAA 50 (7), 24, 1985 Ref. (2): Data sheet No. 255, Kommision Bewertung wassergefährlicher Stoffe, Bundesgesundheitsamt, P. O. Box , D Berlin, 1992 Page 7/7