Maximize ROI on Waste Through Cutting Edge Plasma Gasification Technologies

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Maximize ROI on Waste Through Cutting Edge Plasma Gasification Technologies Presented At Waste-Based Energy Toronto Canada November 23, 2009 ff S Jeff Surma President and CEO

S4 Introductory Statements Disclaimers: S4 has made certain assumptions regarding g conditions, events and circumstances that may occur in the future in performing analysis and projecting future operations that are summarized by this presentation and the associated paper. While S4 believes such assumptions are reasonable and the methodologies S4 has used are appropriate for the purposes set forth in this presentation; depending on conditions, events and circumstances that may occur but are unknown at this time, actual results may materially differ from those projected in this presentation and associated paper. The use of this presentation, the associated report or any information presented or otherwise derived from the presentation (collectively, the Presentation Materials ), whether written or verbal, shall constitute the user s waiver and release of S4 and Jeff Surma from and against all claims and liability, including, but not limited to, any liability for special, incidental, indirect, or consequential damages, in connection with such use ( Claims ). In addition, use of the Presentation Materials shall constitute an agreement by the user to defend and indemnify S4 from and against any Claims. To the fullest extent permitted by law, such waiver, release and indemnification shall apply notwithstanding the negligence, strict liability, fault, willful misconduct or breach of warranty of S4. The benefit of such releases, waivers, releases and indemnification shall extend to S4 s related companies, contractors and the directors, officers, members, employees and agents. S4 RETAINS ALL RIGHTS TO THE INFORMATION AND TECHNOLOGY DESCRIBED IN THE PRESENTATION, MATERIALS; NOTHING CONTAINED HEREIN SHALL CONSTITUTE A WAIVER OF S4 S INTELLECTUAL PROPERTY RIGHTS PERTAINING TO THE SUBJECT MATTER OF PRESENTATION MATERIALS. S4 makes no warranty, express or implied relating to the Presentation Materials. User accepts the sole risk of any such use.

Presentation Overview Gasification Technology Options Environmental Impacts Energy Optimization Project Considerations Application to MSW

S4 Energy Solutions Joint Venture Formed to Commercially Deploy Gasification of Waste 50/50 Joint Venture Between WM and InEnTec Venture Officially Launched in February 2009 JV t O t i C ll b ti ith b t JV to Operate in Collaboration with, but Independent of JV Partners

GASIFICATION TECHNOLOGY OPTIONS Driving Innovation of Clean and Flexible Energy Solutions

Gasification 101 Base Definition: Gasification generally involves the conversion of carbonaceous materials into primarily synthesis gas (CO and H2) through partial oxidation and/or steam reforming reactions, for example: C x H y + xh 2 O xco + (x + y/2)h 2 C x H y + (x/2)o 2 xco + (y/2)h 2

What is Plasma Gasification? Power Supply Electrodes Very High Temperature Region

Gasifiers for Waste Conversion Primary Categories of traditional Gasification Technology: Fixed Bed Downdraft Updraft Fluidized bed (bubbling and circulating) Pyrolysis Systems

Up-Draft (Counter Current) Gasifier Waste Synthesis Gas Solids Flow Zone 3 Zone 2 Zone1 Gas Flow Ash/Slag Gasification Agent

Down-Draft (Co-Current) Gasifier Waste Solids Flow Zone 1 Zone 2 Gasification Agent Gas Flow Ash/Slag Synthesis Gas

PEM TM System Downdraft Plasma Gasifier

PEM TM Unit

Environmental Performance For Driving Innovation of Clean and Flexible Energy Solutions Plasma Technology

Potential Waste Volume Reduction 1 Ton = 182 Cu Ft 2 Cu Ft Recycled

Ultra Low Emissions Advanced d Plasma processes typically exceed US EPA emission requirements by an order of magnitude depending di on the ultimate use of the synthesis gas Dioxin emissions 10x to 100x lower than US EPA requirements No detectible mercury emissions

Potential Carbon Credits Reduced d Transportation ti Production of alternative fuels Reduced net CO 2 emissions in comparison to other technology options Increased efficiency and use of landfills Potential to capture and sequester CO 2

Gasification Options And Driving Innovation of Clean and Flexible Energy Solutions Project Considerations

Primary Project Parameters Waste Feedstock Facility Scale Energy Off-Take By-products Facility Integration Considerations Permitting Economic Incentives and Subsidies

Feedstock Considerations Availability and Quality Advanced Plasma Gasification is designed to provide flexibility Pretreatment requirements minimized Blends High Conversion Efficiency

Capacity Considerations Is Bigger Better? Risk Flexibility Modular

Energy Off-Take Products Syngas fuel Electric Power (reciprocating engines) Hydrogen Methanol Ethanol Other GTL options (e.g. Syn-diesel)

Potential Products AMMONIA NH 3 CO 2 UREA FORMAL- DEHYDE RESINS METHANOL DME COAL CARBON MONOXIDE HYDROGEN ACETIC ACID PHOSGENE POLY- URETHANE BIOMASS GASIFICATION OXO ALCOHOLS DETERGENTS, PLASTICIZERS WASTE FISHER-TROPSCH FUELS, WAXES, OTHERS SNG IC RECIP ENGINE ELECTRIC POWER HYDROGEN FUEL CELL ELECTRIC POWER GAS TURBINES ELECTRIC POWER

By-Products Ash vs Slag vs Glass Liability Cost Completely Inert

Facility Integration Utilities Staff-Sharing Host - Customer for Off-take Primary Secondary

Permitting Scale Local feedstock Public Receptivity High Environmental Performance Low Carbon Footprint

Potential Incentives Carbon Credits RECs Tax Credits Producer Credits Various State and Federal Others

Opportunities for MSW In Driving Innovation of Clean and Flexible Energy Solutions North America

Mass Balance Example (Varies with Waste Composition) Estimates: Thermal Energy ~ 40 to 55 MMBTU/hr Waste Feed Plasma Gasifier Syngas Cleaning Hydrogen Production ~ 2 to 3 MMSCF/day 125 Tons/day Alcohol Production ~6000 to 10000 gal/day Glass Metal Electricity Production ~ 3 to 5 MW net

Potential Energy Off-Take Value 250 $( (US) / Ton Waste 200 150 $2/gal 100 50 $6/MMBtu $6/MMBtu $0.10/kWh 0 Syngas Hydrogen Electricity Alcohol

Summary Conversion of waste into clean energy products can be economically viable option in the near term Risk can be mitigated through proper project analysis and deployment Start Small Build in Flexibility