TACKIFIERS FOR ADHESIVES

Transcription

1 TACKIFIERS FOR ADHESIVES

2 KRATON - A RELIABLE PARTNER Kraton, the world s leading producer of value-added pine chemicals, provides adhesive formulators with high quality, sustainable solutions that meet a variety of formulation and application needs. Adhesive manufacturers can rely on Kraton Corporation for a steady, consistent and timely supply of quality products. With more than 80 years of expertise and the world s largest pine chemical biorefining capacity, we have developed a broad portfolio of high performance bio-based tackifiers. We support worldwide customers through our global production facilities and sales network. This allows customers to benefit from flexibility in sourcing and managing their local, regional and global supply chains. Consistent and Timely Supply of Quality Products Sustainable Solution Provider Our vision as a leading biorefiner is to transform biobased raw materials into value-added, sustainable chemical solutions. By leveraging our diversified chemistry offering, rheology expertise and approach to product development, we are able to deliver optimal tackifier solutions for each customer s situation. High Amounts of Biorenewable Content Contribute to Customer Sustainability Goals Kraton s commitment to sustainability complements our dedication to meeting adhesive manufacturers specifications and performance requirements. With high amounts of biorenewable content in our products, we support our customers in achieving their corporate sustainability goals.

3 Biorenewable Content of Kraton Pine Chemical Products Aqueous Dispersions 50% Styrenated Terpenes 60% Terpene Phenols 60% Rosin Esters 85% Terpene Resins 99% Biorenewable Content (BRC) is the percent of renewable carbon respired within the last decade vs. fossil carbon respired more than 50,000 years ago. BRC is measured by 14 C content. The amount of BRC in Kraton Pine Chemical products, as shown above, has been third party verified according to ASTM D6866 testing standards. Kraton is the frontrunner in biorefining Crude Tall Oil (CTO) and Crude Sulfate Turpentine (CST), co-products of the Kraft wood pulping process. This process originates with pine forests harvested by pulp and paper manufacturers. Many of our primary suppliers have been certified to recognized accreditation standards that address responsible forest management. We emphasize maximization of the value of our raw materials while minimizing waste and environmental impact. Renewable raw material Using the co-product of pulp production Refining and producing chemicals Providing value-added pine chemicals to the adhesives industry PULP MILL 3

4 TACKIFIERS FOR ADHESIVES By working with a large and varied molecular asset base, Kraton Science & Technology teams can select or create products that achieve desired performance results. Polymer Compatibility Compatibility between a tackifier and an adhesive polymer is a crucial factor in enhancing viscoelastic properties. In contrast, a certain amount of incompatibility can also provide desired properties. The Hildebrand solubility parameter gives an estimate of the degree of interaction between tackifier and polymer. Materials with similar values are likely to be miscible and have favorable viscoelastic properties. Hildebrand Solubility Parameter Tackifiers AMS Phenolics AMS Polyterpenes Styrenated Terpene Rosin Esters Terpene Phenolics (low OH) Terpene Phenolics (high OH) Polymers Ethylene Isoprene Butadiene Styrene high polar (VA, PUR) Low polarity High polarity 4

5 SYLVATAC and SYLVALITE Rosin Esters Rosin esters are compatible with a broad range of polymers, including high and low vinyl acetate EVA, acrylics, SBR, SIS and SBS. This characteristic enables formulation flexibility in various hot melt, water-based and solvent-based adhesive applications. Solid rosin esters can be formulated into SBC- or EVA-based adhesives for packaging, PSA and woodworking applications. In addition to these end-uses, liquid rosin esters can also be used in water-based acrylic for construction adhesives. Kraton continuously upgrades its product line and introduced a highly stabilized rosin ester: SYLVALITE ENDURA99. This innovative tackifier enables you to differentiate by providing excellent color stability and oxidative stability when formulating hotmelt adhesives. Test SP AN Color T g Method AQCM 003 AQCM 001 AQCM 002 AQCM 218 Unit mgkoh/g Gardner (neat) Gardner (1:1 toluene) SYLVATAC RE 5S liquid EU SYLVALITE RE 10L liquid US SYLVATAC RE 12 liquid EU SYLVATAC RE US SYLVATAC RE US SYLVALITE RE 80HP US SYLVATAC RE 85 (US) US SYLVATAC RE 85 (EU) EU SYLVALITE RE 85GB US SYLVALITE RE 88F EU SYLVATAC RE EU SYLVATAC RE US The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request. 5

6 Test SP AN Color T g Method AQCM 003 AQCM 001 AQCM 002 AQCM 218 Unit mgkoh/g Gardner (neat) Gardner (1:1 toluene) SYLVALITE ENDURA US SYLVALITE RE 100S EU SYLVALITE RE 100L US SYLVALITE RE 100F EU SYLVATAC RE 103S EU SYLVALITE RE 105XL EU SYLVALITE RE 105L US SYLVALITE RE 110L US SYLVALITE RE EU UNI-TAC Modified Rosin UNI-TAC 70 tackifier imparts outstanding adhesion to difficult-to-bond substrates due to the high acid number, non-crystallinity and low molecular weight of this highly polar solid rosin. Test SP AN Color T g Method AQCM 003 AQCM 001 AQCM 002 AQCM 218 Unit mgkoh/g Gardner (neat) UNI-TAC US 6 The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request.

7 AQUATAC Dispersions AQUATAC waterborne tackifiers have high solid content which contributes to improving overall operational efficiency for adhesive manufacturers. These dispersed tackifiers are compatible with a broad range of water-based polymers including natural rubber, C-SBR, SBR, polychloroprene and acrylic latices. They can be formulated to achieve optimum performance properties for both pressure sensitive and non-pressure sensitive adhesives. Test SP (base resin) Solid Content Viscosity ph Method AQCM 003 AQCM 029 AQCM 004 (Brookfield 25 ) AQCM 136 (EU) AQCM 035 (US) Unit % mpa.s / cps AQUATAC XR EU AQUATAC FC EU AQUATAC US AQUATAC US AQUATAC , US AQUATAC E US The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request. 7

8 SYLVARES AMS Resins These aromatic tackifiers have a very light color, along with excellent oxidative stability. AMS resins can be used to modify styrene end blocks of SBC in order to improve the range of temperature performance. AMS resins may be used in EVA- and SBC-based adhesives for packaging, bookbinding, nonwovens and assembly applications. Test SP Mw Color T g Method AQCM 003 AQCM 217 AQCM 002 AQCM 218 Unit g/mol Hazen (1:1 toluene) SYLVARES SA EU SYLVARES SA EU SYLVARES SA EU SYLVARES SA EU SYLVARES SA EU SYLVARES AMS Phenolics Resin The phenolic component of these tackifiers improves compatibility with high polarity polymers such as EVA, PUR and acrylics. AMS phenolic resins are recommended for use in applications that require water-white color, excellent adhesion and oxidative stability. The low T g improves elasticity at low temperature, which makes these tackifiers suitable for bookbinding and packaging adhesives. Test SP Mw Color T g Method AQCM 003 AQCM 217 AQCM 002 AQCM 218 Unit g/mol Hazen (1:1 toluene) SYLVARES EU SYLVARES EU SYLVARES EU 8 The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request.

9 SYLVARES and ZONATAC Styrenated Terpenes Adhesive formulators can benefit from the aliphatic-aromatic nature of styrenated terpenes, which result in high compatibility with EVA, SIS and SBS polymers. Displaying light color and low odor properties, styrenated terpenes can be the right choice for premium hot melt applications. Test SP Mw Color T g Method AQCM 003 AQCM 217 AQCM 002 AQCM 218 Unit g/mol Gardner (neat) SYLVARES ZT 106LT US ZONATAC NG US SYLVARES Polyterpenes Polyterpene grades with high-softening point have shown to combine high heat resistance and excellent tack and peel for pressure sensitive adhesives. These resins offer the highest amount of biorenewable content of Kraton s product lines and are compatible with polyolefins and the mid-block of SIS co-polymers. Test SP Mw Color T g Method AQCM 003 AQCM 217 AQCM 002 AQCM 218 Unit g/mol Gardner (neat) SYLVARES TR A25L US SYLVARES TR B US SYLVARES TR M US SYLVARES TR US SYLVARES TR US The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request. 9

10 SYLVARES Terpene Phenolics Our terpene phenolic resins are available in a wide range of polarities, which increases the versatility of adhesive formulation. High functionality terpene phenols provide outstanding adhesion when formulated with EVAs and other polar polymers. The low polarity terpene phenolic resins improve adhesion of pressure sensitive adhesives (in SIS, SBS and acrylic systems) to difficult-to-bond substrates like coated and recycled paper, glass and metal foils. Test SP Mw Color T g Method AQCM 003 AQCM 217 AQCM 002 AQCM 218 Unit g/mol Gardner (neat) SYLVARES TP US SYLVARES TP US SYLVARES TP 115P US SYLVARES TP US SYLVARES TP US SYLVARES TP 2040HM US SYLVARES TP US The values presented in this brochure are average values for typical resin samples and should not be construed as product specifications. Kraton test methods are available upon request. 10

11 GLOBAL INTEGRATED TEAM APPROACH We engage experts from a variety of disciplines to consult on challenges in order to solve them more effectively and efficiently for our customers. OUR WORLDWIDE MULTI-FUNCTIONAL TEAM PROVIDES: Accessible and Personalized Technical Support Our Technical Service teams provide support from Science & Technology (S&T) Centers located in China, the US and EU. We have in-house capabilities to assist adhesive formulators with the selection of raw materials and to provide expert support from development to commercial Personalized support application. The teams assist from China, EU and US Science & Technology in scale-up trials and our S&T Centers Centers are equipped to fulfill adhesive application testing. Alongside our Account Managers, the Technical Service teams regularly call on customers at all levels of the organization to provide training on our products. Hands-On Operational Assistance To ensure that our communications with adhesive manufacturers are clear and complete, our Operations Engineering site personnel work closely visits and with customers to enable interactive exchanges smoother logistics across the supply chain. In order to improve process efficiency, we make site visits and interactive engineering exchanges that facilitate the review and understanding of particular technologies. We focus on continuous improvement in manufacturing and use Root Cause Analysis to fully understand any issue that might arise. 11

12 Expert Regulatory Guidance The highly-regulated chemical industry requires in-depth and current knowledge of the latest developments. Thanks to a dedicated Global Product Regulatory Team with comprehensive regional expertise, Kraton provides global support to customers on complex and changing regulations including, but not limited to, EU Food Contact, US FDA Ingredient Status, international chemical control laws such as EU REACH, US TSCA, Japan CSCL and Decree 591 in China. INNOVATIVE SOLUTIONS Targeted Innovation Our innovation is driven by creativity, passion and active assessment of market trends. We work in state-of-the-art laboratories on technology platforms focused on pine rosin and terpene-based product opportunities. To ensure that our innovation takes emerging customer needs, polymer advances and regulatory changes into account, we collaborate Innovation Driven by with adhesive manufacturers as well as internal and external Creativity, Passion experts. Kraton s own analytical, rheology and regulatory and Customer Needs teams support our global product development initiatives and our continuous drive to understand structure property relationships. We encourage close cooperation, knowledgesharing and transparency in our relationships with customers to take advantage of our combined strengths. Analytical Expertise 12 Kraton has three highly specialized analytical laboratories with advanced equipment and techniques that include (pyrolysis) GC-MS, (oxidative) DSC, TGA, GPC, HPLC, FTIR, NIR, UV-Vis, ICP - AES, sulfur analysis and preparative flash chromatography. Our chemists in the US, EU and China are able to perform in-depth analyses to characterize raw materials and adhesives, as well as to investigate process and application issues.

13 Application Expertise Pa 10 8 Our core competency in rheology, combined with sophisticated modeling techniques, form a solid base for enabling customers to achieve optimum product performance. Dynamic Mechanical Analysis (DMA), a rheology technique, is a powerful tool in generating a detailed understanding of how products and other individual ingredients interact without requiring the details of the total formulation. Viscoelastic profiles created using the DMA Core Competency In technique, in combination with the recently-developed Rheology and Use of modeling approach, provide a strong base for problemsolving and formulation assistance that goes beyond Modeling Techniques Sophisticated tackifier selection. Connection to Reality Dynamic Mechanical Analysis Typical Viscoelastic Response of a Hot Melt Pressure Sensitive Adhesive System Typical viscoelastic response Rl130119, of a V4111/ real Escorez Hot 5400/ Melt Primol Pressure 352; 100/154/046 Sensitive Adhesive system G Ingredients: --Styrenic block copolymer --Resin Tackifier --Oil 10 7 G Network G' G'' 10 5 tan(d ) Tack tanδ Flow/Melt Glass Region Transition Region Rubbery Plateau Melt Flow Region Temperature T 13

14 Glossary AES AMS AN AQCM ASTM C-SBR CSCL DMA DoE DSC EVA FDA FTIR GC-MS GPC HPLC Atomic Emission Spectroscopy Alpha Methyl Styrene Acid Number Arizona Quality Control Method American Society for Testing and Materials Carboxylated Styrene Butadiene Rubber Chemical Substance Control Law Dynamic Mechanical Analysis Design of Experiment Differential Scanning Calorimetry Ethyl Vinyl Acetate Food and Drug Administration Fourier transform infrared spectroscopy Gas Chromatography Mass Spectrometry Gel Permeation Chromatography High Performance Liquid Chromatography ICP Mw NIR OH PSA PUR REACH SBC SBR SBS SIS SP Tg TGA UV-Vis VA Inductively Coupled Plasma Molecular Weight Near-Infrared Hydroxyl Value Pressure Sensitive Adhesives Polyurethane Registration, Evaluation, Authorisation and Restriction of Chemicals Styrenic Block Co-polymers Styrene Butadiene Rubber Styrene Butadiene Styrene Styrene Isoprene Styrene Softening Point Glass Transition Temperature Thermogravimetric Analysis Ultraviolet-Visible Vinyl Acetate 14

15 ABOUT KRATON CORPORATION Kraton Corporation (NYSE KRA ) is a leading global producer of styrenic block copolymers, specialty polymers and high-value performance products derived from pine wood pulping co-products. Kraton s polymers are used in a wide range of applications, including adhesives, coatings, consumer and personal care products, sealants and lubricants, and medical, packaging, automotive, paving, roofing and footwear products. As the largest global provider in the pine chemicals industry, the company s pine-based specialty products are sold into adhesive, road and construction and tire markets, and it produces and sells a broad range of chemical intermediates into markets that include fuel additives, oilfield chemicals, coatings, metalworking fluids and lubricants, inks, flavors and fragrances and mining. Kraton offers its products to a diverse customer base in over 70 countries worldwide. GLOBAL FOOTPRINT Global Headquarters Innovation/Technology Centers Offices - Chemical Segment - Polymer Segment Global Headquarters Houston, TX, USA Regional Offices Jacksonviille, FL, USA Shanghai, China Almere, The Netherlands Tokyo, Japan Paulinia, Brazil Mumbai, India LEGAL DISCLAIMER in the Americas Belpre, OH, USA Dover, OH, USA Panama City, FL, USA Pensacola, FL, USA Savannah, GA, USA Paulínia, Brazil in Asia Kashima, Japan (JV) Mailiao, Taiwan (JV) in Europe Berre, France Niort, France Oulu, Finland Gersthofen, Germany Wesseling, Germany Sandarne, Sweden Kraton Corporation and all of its affiliates, including Arizona Chemical, believe the information set forth herein to be true and accurate, but any recommendations, presentations, statements or suggestions that may be made are without any warranty or guarantee whatsoever, and shall establish no legal duty on the part of any Kraton affiliated entity. The legal responsibilities of any Kraton affiliate with respect to the products described herein are limited to those set forth in Kraton s Conditions of Sale or any effective sales contract. NOTE TO USER: by ordering/receiving Kraton product you accept the Kraton Conditions of Sale applicable in the region. All other terms are rejected. Kraton does not warrant that the products described herein are suitable for any particular uses, including, without limitation, cosmetics and/or medical uses. Persons using the products must rely on their own independent technical and legal judgment, and must conduct their own studies, registrations, and other related activities, to establish the safety and efficacy of their end products incorporating any Kraton products for any application. Nothing set forth herein shall be construed as a recommendation to use any Kraton product in any specific application or in conflict with any existing patent rights. Kraton reserves the right to withdraw any product from commercial availability and to make any changes to any existing commercial or developmental product. Kraton expressly disclaims, on behalf of all Kraton affiliates, any and all liability for any damages or injuries arising out of any activities relating to the use of any information set forth in this publication, or the use of any Kraton products. Kraton maintains a Cosmetics, Drugs and Medical Device Policy that restricts the use of Kraton s Products in certain end use applications without Kraton s prior written consent. Accordingly, Kraton does not guarantee that Kraton s products will be available for use in all potential end use applications. Kraton s Cosmetics, Drugs and Medical Device Policy is available on Kraton s website at *KRATON, the Kraton logo, and AQUATAC, SYLVALITE, SYLVARES, SYLVATAC, UNI-TAC, and ZONATAC are either trademarks or registered trademarks of Kraton Corporation, or its subsidiaries or affiliates, in one or more, but not all countries Kraton Corporation