Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 LOCTITE SF 7900 CERAMIC SHIELD WELDING AEROSOL known as Page 1 of 16 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Protective coating for welding 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Aerosols Category 1 H222 Extremely flammable aerosol. Aerosols Category 1 H229 Pressurised container: May burst if heated. Serious eye irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure Category 3 H336 May cause drowsiness or dizziness. Target organ: Central Nervous System 2.2. Label elements Label elements (CLP):

2 Page 2 of 16 Hazard pictogram: Signal word: Hazard statement: Danger H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Supplemental information Precautionary statement: Prevention Precautionary statement: Storage EUH066 Repeated exposure may cause skin dryness or cracking. P210 Keep away from heat/open flames/hot surfaces. - No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe mist/vapours. P280 Wear eye protection/face protection. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures Base substances of preparation: Pigment solvent

3 Page 3 of 16 Declaration of the ingredients according to CLP (EC) No 1272/2008: Butane, n- (< 0.1 % butadiene) Propane EC Number REACH-Reg No content Classification % Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H % Flam. Gas 1 H220 Press. Gas % Flam. Gas 1 H220 Press. Gas H % Flam. Liq. 2 H225 Eye Irrit. 2 H319 STOT SE 3 H336 ethyl formate ,3-Dioxolane % Flam. Liq. 2 H225 Acute Tox. 4; Inhalation H332 Acute Tox. 4; Oral H302 Eye Irrit. 2 H319 STOT SE 3 H % Flam. Liq. 2 H225 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: Rinse with running water and soap. In case of adverse health effects seek medical advice. SECTION 4: First aid measures Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. In case of adverse health effects seek medical advice.

4 Page 4 of Most important symptoms and effects, both acute and delayed Vapors may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking. EYE: Irritation, conjunctivitis Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder Fine water spray SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: Water jet (solvent-containing product) Special hazards arising from the substance or mixture Cool pressurized can containers with jet of water. Containers may explode Advice for firefighters Wear protective equipment. Wear self-contained breathing apparatus. Additional information: Cool endangered containers with water spray jet. General information: Danger of slipping on spilled product. Keep away from sources of ignition and naked flames. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Take up with liquid-absorbing material (sand). Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid skin and eye contact. Ventilate working rooms throughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. See advice in section 8 Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working.

5 Page 5 of Conditions for safe storage, including any incompatibilities Do not store or use near heat, spark, open flame or other sources of ignition. Take precautionary measures against static discharges during storage and transport. Keep container in a well ventilated place. Ensure that storage and workrooms are adequately ventilated Specific end use(s) Protective coating for welding

6 Page 6 of 16 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks Time Weighted Average [ACETONE] [ACETONE] [ACETONE] Butane [BUTANE] Butane [BUTANE] [BUTAN-2-ONE (METHYL ETHYL KETONE)] [BUTAN-2-ONE (METHYL ETHYL KETONE)] [BUTAN-2-ONE (METHYL ETHYL KETONE)] [BUTANONE] [BUTANONE] Ethyl formate [ETHYL FORMATE] Ethyl formate [ETHYL FORMATE] Short Term Exposure Limit (STEL): Time Weighted Average Short Term Exposure Limit (STEL): Time Weighted Average Short Term Exposure Limit (STEL): Skin designation: Time Weighted Average Time Weighted Average Short Term Exposure Limit (STEL): Short Term Exposure Limit (STEL): Time Weighted Average Indicative Can be absorbed through the skin. Indicative Indicative Regulatory list ECTLV ECTLV ECTLV Occupational Exposure Limits Valid for Ireland Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks Time Weighted Average Indicative OELV [ACETONE] [ACETONE] Butane [BUTANE] Propane [PROPANE] Time Weighted Average Time Weighted Average Time Weighted Average Indicative Regulatory list IR_OEL ECTLV IR_OEL IR_OEL Time Weighted Average Indicative OELV IR_OEL

7 Page 7 of 16 [METHYL ETHYL KETONE (MEK)] [METHYL ETHYL KETONE (MEK)] [METHYL ETHYL KETONE (MEK)] [BUTANONE] [BUTANONE] Ethyl formate [ETHYL FORMATE] Ethyl formate [ETHYL FORMATE] 1,3-Dioxolane [1,3-DIOXOLANE] Short Term Exposure Limit (STEL): Skin designation: Time Weighted Average Short Term Exposure Limit (STEL): Short Term Exposure Limit (STEL): Time Weighted Average 20 Time Weighted Average Indicative OELV Can be absorbed through the skin. Indicative Indicative IR_OEL IR_OEL ECTLV ECTLV IR_OEL IR_OEL IR_OEL Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) soil aqua (freshwater) aqua (marine water) aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) soil Exposure period Value mg/l ppm mg/kg others 21 mg/l 30,4 mg/kg 3,04 mg/kg 29,5 mg/kg 284,74 mg/kg 284,7 mg/kg 22,5 mg/kg oral 1000 mg/kg 100 mg/l 10,6 mg/l 1,06 mg/l 55,8 mg/l 55,8 mg/l 55,8 mg/l 709 mg/l Remarks

8 Page 8 of 16 Derived No-Effect Level (DNEL): Name on list Application Area Route of Exposure Health Effect Workers Inhalation Acute/short term local effects Workers Dermal Long term Workers Inhalation Long term general Dermal Long term population general population general population Inhalation oral Long term Long term Workers Dermal Long term Workers Inhalation Long term general population general population general population Dermal Inhalation oral Long term Long term Long term Exposure Time Value 2420 mg/m3 186 mg/kg bw/day 1210 mg/m3 62 mg/kg bw/day 200 mg/m3 62 mg/kg bw/day 1161 mg/kg bw/day 600 mg/m3 412 mg/kg bw/day 106 mg/m3 31 mg/kg bw/day Remarks Biological Exposure Indices: Ingredient [Regulated substance] [BUTAN-2-ONE] Parameters Biological specimen Sampling time Conc. Basis of biol. exposure index Butan-2-one Urine Sampling time: End of UKEH40BMG shift. V Remark Additional Information 8.2. Exposure controls: Engineering controls: Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Respiratory protection: In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter. This recommendation should be matched to local conditions. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

9 Page 9 of 16 Eye protection: Protective goggles Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Aerosol liquid Off white Odor Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure (50 C (122 F)) Vapour pressure (55 C (131 F)) Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits lower upper Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Not applicable 56 C (132.8 F) -20 C (-4 F)Solvent Mixtures 764 mbar 961 mbar 0,8 g/cm3 Soluble 1,8 %(V) 13,0 %(V) 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Heat, flames, sparks and other sources of ignition.

10 Page 10 of Incompatible materials See section reactivity Hazardous decomposition products None if used for intended purpose. In case of fire toxic gases can be released Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. STOT-single exposure: May cause drowsiness or dizziness. Skin irritation: Repeated exposure may cause skin dryness or cracking. Eye irritation: Causes serious eye irritation. Acute oral toxicity: ethyl formate Value Value Route of Exposure Species type application time LD mg/kg oral rat Method Acute toxicity estimate (ATE) mg/kg oral Expert judgement LD rat mg/kg LD mg/kg oral rat Acute inhalative toxicity: Butane, n- (< 0.1 % butadiene) Value Value Route of Exposure Species type application time LC50 76 mg/l 4 h rat LC mg/l 4 h rat Method Acute toxicity estimate (ATE) 5,1 mg/l Aerosol Expert judgement LC50 > 5000 ppm 6 h rat Acute dermal toxicity: Value Value Route of Exposure Species type application time LD50 > mg/kg dermal rabbit Method Acute toxicity estimate (ATE) mg/kg dermal Expert judgement LD rabbit mg/kg

11 Page 11 of 16 Skin corrosion/irritation: moderately irritating Result Exposure time Species rabbit Method Serious eye damage/irritation: Result Exposure time Species Method irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: not sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig Not specified Germ cell mutagenicity: Propane Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative with metabolic activation negative Ames test) in vitro mammalian chromosome aberration test bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time Species Method with and without OECD Guideline 471 (Bacterial Reverse Mutation with and without Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) Repeated dose toxicity Result LOAEL=20000 ppm NOAEL=900 mg/kg Route of application oral: drinking water oral: drinking water NOAEL=2500 ppm inhalation 90 days6 hours/day, 5 LOAEL=5000 ppm inhalation 90 days6 hours/day, 5 days/week Exposure time / Frequency of treatment Species Method 13 wdaily rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) 13 wdaily rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) rat days/week rat SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains / surface water / ground water.

12 Page 12 of 16 Other adverse effects: The product contains organic solvents which are insoluble in water. According to the requirements of the ATV regulations for the dis charge of wastewater from commercial and industrial plant, organic solvents which are immiscible with water can only be dis charged to an extent which corresponds to their solubility in water. The local discharge regulations take precedence Toxicity Butane, n- (< 0.1 % butadiene) Butane, n- (< 0.1 % butadiene) Butane, n- (< 0.1 % butadiene) ethyl formate ,3-Dioxolane ,3-Dioxolane ,3-Dioxolane Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia pulex OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC mg/l chronic Daphnia LC50 27,98 mg/l Fish 96 h EC50 14,22 mg/l Daphnia 48 h EC50 7,71 mg/l Algae 96 h 28 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) EC mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC50 > 95,4 mg/l Fish 96 h Lepomis macrochirus OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 772 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation ErC50 > 877 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) NOEC 877 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) Test) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method

13 Page 13 of 16 1,3-Dioxolane readily biodegradable aerobic % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) readily biodegradable aerobic > 60 % OECD 301 A - F aerobic 20 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil ethyl formate ,3-Dioxolane LogKow Bioconcentration factor (BCF) Exposure time Species Temperature Method -0,24 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 0,29 0,23-0, Results of PBT and vpvb assessment Butane, n- (< 0.1 % butadiene) Propane PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: In consultation with the responsible local authority, must be subjected to special treatment. Waste code The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you.

14 Page 14 of 16 SECTION 14: Transport information UN number ADR 1950 RID 1950 ADN 1950 IMDG 1950 IATA UN proper shipping name ADR RID ADN IMDG IATA AEROSOLS AEROSOLS AEROSOLS AEROSOLS Aerosols, flammable Transport hazard class(es) ADR 2.1 RID 2.1 ADN 2.1 IMDG 2.1 IATA Packaging group ADR RID ADN IMDG IATA Environmental hazards ADR RID ADN IMDG IATA Special precautions for user ADR RID ADN IMDG IATA Tunnelcode: (D) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 91,1 % (2010/75/EU)

15 Page 15 of Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Great Britain): Remarks Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, e.g COSHH Essentials. EH40 Occupational Exposure Limits Chemicals (Hazard Information & Packaging for Supply) Regulations. The Personnel Protective Equipment at Work Regulations. The Carriage of Dangerous Goods by Road Regulations. The Health & Safety at Work Act (Note: Use latest editions/amendments of above referenced documents.)

16 Page 16 of 16 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H220 Extremely flammable gas. H225 Highly flammable liquid and vapor. H280 Contains gas under pressure; may explode if heated. H302 Harmful if swallowed. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): F+ - Extremely flammable Xi - Irritant Risk phrases: R12 Extremely flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe spray. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S38 In case of insufficient ventilation, wear suitable respiratory equipment. Additional labeling: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.