Case Study: MMNA and PPG. Applying BC4200NP Paint Detackification Chemistry at the Normal, Illinois, MMNA Automobile Assembly Facility

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1 Case Study: MMNA and PPG Applying BC42NP Paint Detackification Chemistry at the Normal, Illinois, MMNA Automobile Assembly Facility CMS Forum 1/25/6

2 Mitsubishi Motors North America The company s only North American manufacturing facility began construction in 185 and is located about 15 miles south of Chicago, IL The automobile assembly plant is one the most technologically advanced in the world, utilizing nearly 1 robots housed under 2.4 million ft 2 Body parts are stamped and bumpers molded in house to produce the Mitsubishi Galant, Eclipse, Endeavor, and Spyder Part of an elite group of manufactures to be both IS 1 and IS 141 Certified

3 Mitsubishi Environmental Stewardship IS 141:16 certification in 2 IS 141:24 certification in acres of IL natural prairie grass established, increasing tri-county content by 4% ne of first EM s to introduce lead free rust prevention coatings Fully recyclable TP bumper systems VC emissions 68% beneath EPA limit and 15% less than 15 levels In a five year period, landfill waste reduced by 35% n pace recycle 2 tons of material in 26, generating $4.1 million in revenue. Protecting the Environment for ur Families ur Friends ur Future!

4 PPG Industries, Inc. Founded in 1883 in Pittsburgh, PA About 31, employees worldwide Employees are largest stockholder group 25 sales approximately $1.2 Billion Markets served: Coatings: EM Auto, Industrial, Refinish, Architectural (Pittsburgh Paint), Wood Protection (lympic Stains) Glass: EM Auto, Replacement Glass, Architectural, Aerospace Transparences, ptical (Transition Lenses) Chemicals: WWT, ChlorAlkali, Metal Treatment, Specialty Chemicals

5 Typical Paint Spray Booth -Down draft/water wash booth -Numerous robotic/manual zones -1 3 Long

6 Paint Detackification Chemicals Introduced to detackify or render the paint nonsticky / non-tacky Further introduced to coagulate paint and solvent particles Flocculants added to agglomerate smaller particles Specialized form of wastewater treatment

7 Mechanism of Paint Detackification Chemical Interaction Charge neutralization (coagulation) Favorable at low p Physical Interaction Chemical flocs encapsulate or coat atomized paint particles Favorable at high p Joint Physical/Chemical Interaction

8 Mechanism of Treating Solvent Borne Paints Atomized Paint Detackifier Chemical Interaction Physical Interaction Chemical Flocs Enhanced Physical Interaction Detackified Paint Sludge Flocculant (Latex Polymer)

9 Mechanism of Treating Mechanism of Treating Water Borne Paints Detackifier Chemical Interaction WB Solution Enhanced Physical Interaction Coagulated Paint Flocculant (Latex Polymer) Flocculated Sludge

10 Feed Points for Treating Solvent Borne Paints Spray Booth p Adjuster Flocculant Flocculant Sludge Sludge Removal System Foam Depressor Sludge Pit Clean Well Detackifier

11 Feed Points for Treating Water Borne Paints Spray Booth p Adjuster Flocculant Flocculant Sludge Sludge Removal System Detackifier Sludge Pit Clean Well Foam Depressor

12 Evolution of Paint Detackification Technology 1 st Generation Clay/Amine 2 nd Generation Melamine/Formaldehyde 3 rd Generation Solution Polymer/Al Salt 4 th Generation Emulsion/Dispersion Technology 5 th Generation Naturally ccurring Polymers (chitosan, tannin, starch, etc.)

13 Environmental Advantages of Chitosan Technology BC42NP A linear polysaccharide derived from exoskeleton of crustaceans Main component, chitosan, is similar in composition to keratin and cellulose Does not include melamine-formaldehyde resins (residual free formaldehyde) Is not derived from acrylic acid or other petroleum derived raw materials (ethylene, propylene) Is made from a waste product of food production (shrimp, crab, and lobster shells) Technology protected by US Patents #6,673,263 B2 and #6,858,3 B2

14 BC42NP Chemistry The Deacetylation of Chitin to Form Chitosan C 2 C 2 C 2 C 2 NCC 3 NCC 3 NCC 3 NCC 3 chitin conc. Na 135 o C C 2 C 2 C 2 C 2 N 2 N 2 N 2 N 2 chitosan

15 Advantages to MMNA of BC42NP Technology ands off, low maintenance working system Runs day in, day out with very little MMNA involvement Consistent, low suspended solids and low turbidity detackification pit water System Performance is ptimized

16 Typical Data from MMNA Typical Data from MMNA /13/ /14/ /15/ /16/ /1/ /2/ /21/ /22/ /23/ /5/ /6/26 Degree of Foa m Degree of Paint Kill Conductivity (μmhos) Suspended Solids (ppm) Turbidity (NTU) p Pit #1 Date

17 Financial Advantages of BC42NP Program Cost per pound of product is revenue neutral vs. other detackifiers Paint to Chemical ratio is increased with program, i.e., less overall chemical is required Reduced use of caustic (p adjuster) since product is less acidic than other detackifiers

18 Cultural and Technological Changes at MMNA First Auto EM to use this product ther Auto EM s are conducting trials Preliminarily installed as revenue neutral product however additional advantages have surfaced Decreased water content of sludge less time drying before disposal Decreased operator input less time needed to maintain operation Decreased out of range lab analysis less time in investigation and remediation Increased dig-out intervals lower suspended solids in pits yield less settling Increased usable equipment life lower suspended solids in return streams yield less coating, plugging, and maintenance of equipment

19 BC42NP Environmental Awards 25 recipient of Environmental Achievement Award from Environmental Management Association Nominated for 26 Facility of the Year Award by Environmental Protection Magazine

20 TANK YU CMS FRUM!

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