: COMMANDER POWDER. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification.

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1 Date of issue: 01/16/2008 Revision date: 08/20/2014 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : COMMANDER POWDER : COM 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Sky Blue Industries, Inc. 760 W. Exchange Road Ogden, Utah USA T (800) Emergency telephone number : Industrial and Institutional Alkaline Detergent Emergency number : Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Corr. 1A H314 Aquatic Acute 2 H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) Prevention Response Storage Disposal GHS05 : Danger : Causes severe skin burns and eye damage Toxic to aquatic life : Do not breathe dust. Wash hands and exposed skin thoroughly after handling. Avoid release to the environment. Wear eye protection, protective clothing, protective gloves. : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER, a doctor. Wash contaminated clothing before reuse. : Store locked up. : Dispose of contents/container in accordance with local/state/federal regulations. comply with local/state/federal regulations Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available 08/20/2014 EN (English) Page 1

2 SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification Sodium carbonate (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Aquatic Acute 3, H402 Disodium metasilicate (CAS No) Acute Tox. 4 (Oral), H302 Skin Corr. 1A, H314 Sodium dodecylbenzenesulfonate (CAS No) Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 STOT SE 3, H335 Aquatic Acute 1, H400 2-butoxyethanol (CAS No) Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Tetrasodium ethylenediaminetetraacetate, tetrahydrate (CAS No) Eye Dam. 1, H318 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates: Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. Keep upwind. : Equip cleanup crew with proper protection. : Ventilate area. 08/20/2014 EN (English) 2/8

3 6.2. Environmental precautions Avoid release to the environment. See Section 12 for additional Ecological information Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe dust. Avoid contact during pregnancy/while nursing. : Wash hands and exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from: Direct sunlight, Heat sources. Keep container closed when not in use. : Strong acids. Strong oxidizing agents. : Sources of ignition. Direct sunlight. USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 20 ppm USA ACGIH Remark (ACGIH) Eye & URT irr 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Orange powder Colour : Orange Odour : Citrus Odour threshold ph : ph solution : 1 % Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature 08/20/2014 EN (English) 3/8

4 Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Soluble in water 9.2. Other information VOC content : 3.0 % SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates: Corrosive vapours Chemical stability Stable under normal conditions Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong oxidizing agents Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates: Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat 438 mg/kg (Rat) ATE US (oral) 438 mg/kg bodyweight Disodium metasilicate ( ) LD50 oral rat LD50 dermal rat ATE US (oral) 1153 mg/kg > 5000 mg/kg bodyweight (Rat; Read-across; OECD 402: Acute Dermal Toxicity) 1153 mg/kg bodyweight LD50 oral rat LD50 dermal rat 530 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 1746 mg/kg bodyweight; Rat; Experimental value) > 2000 mg/kg bodyweight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LD50 dermal rabbit 435 mg/kg bodyweight (Rabbit; Experimental value; OECD 402: Acute Dermal Toxicity; 435 mg/kg bodyweight; Rabbit; Weight of evidence; Equivalent or similar to OECD 402) LC50 inhalation rat (mg/l) 2.17 mg/l/4h (Rat; Experimental value; 2.35 mg/l/4h; Rat; Experimental value) LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (vapours) ATE US (dust,mist) ,Rat; Weight of evidence 530 mg/kg bodyweight 435 mg/kg bodyweight 2.17 mg/l/4h 2.17 mg/l/4h 08/20/2014 EN (English) 4/8

5 LD50 oral rat LD50 dermal rabbit ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 2800 mg/kg (Rat; Experimental value) > 2000 mg/kg (Rabbit; Experimental value) 2800 mg/kg bodyweight : Causes severe skin burns and eye damage. ph: ph: Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity Ecology - water : Toxic to aquatic life mg/l (96 h; Pisces) 2.19 mg/l (96 h; Daphnia magna) 6.9 mg/l (96 h; Rita rita) 0.9 mg/l (96 h; Algae) Disodium metasilicate ( ) EC50 Daphnia 2 EC50 Daphnia 2 ErC50 (algae) TLM fish 1 TLM other aquatic organisms 1 Threshold limit algae mg/l (96 h; Brachydanio rerio) 216 mg/l (96 h; Daphnia magna; Static system) 2320 mg/l (96 h; Gambusia affinis) 632 mg/l (96 h; Lymnaea sp.; Static system) 207 mg/l (72 h; Scenedesmus subspicatus; GLP) 116 ppm (96 h; Cyprinodon variegatus; Nominal concentration) 1700 mg/l (48 h; Daphnia sp.; Nominal concentration) 1341 ppm (96 h; Lepomis macrochirus) 1720 mg/l (24 h; Daphnia magna) 911 mg/l (72 Hr.) ,96 h; Pisces ,96 h 900 mg/l (168 h; Scenedesmus quadricauda) 35 mg/l (192 h; Microcystis aeruginosa) Tetrasodium ethylenediaminetetraacetate, tetrahydrate ( ) 121 mg/l (96 h; Lepomis macrochirus; Anhydrous form) 625 mg/l (24 h; Daphnia magna) mg/l (96 h; Lepomis macrochirus; Anhydrous form) > 100 mg/l (72 h; Scenedesmus subspicatus; Anhydrous form) EC50 other aquatic organisms 1 EC50 Daphnia mg/l (96 h; Lepomis macrochirus) < 424 mg/l (48 h; Daphnia magna) 14 mg/l (168 h; Plankton) 740 mg/l (96 h; Gambusia affinis) 265 mg/l (48 h; Daphnia magna) 08/20/2014 EN (English) 5/8

6 TLM fish 1 TLM other aquatic organisms ppm (96 h; Lepomis macrochirus) 500 ppm (96 h; Daphnia magna) 242 mg/l (5 days; Algae) COMMANDER POWDER Not established. Readily biodegradable in water. Disodium metasilicate ( ) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. No (test)data on mobility of the substance available. Readily biodegradable in water. Biodegradable in the soil. Photodegradation in the air g O₂ /g substance 2.20 g O₂ /g substance g O₂ /g substance 0.31 % ThOD Tetrasodium ethylenediaminetetraacetate, tetrahydrate ( ) Not readily biodegradable in water. ThOD Biodegradability: not applicable. Low potential for adsorption in soil. (inorganic) Bioaccumulative potential COMMANDER POWDER Bioaccumulative potential Not established. BCF fish 1 BCF fish (Lepomis macrochirus) 130 (Leuciscus idus) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Disodium metasilicate ( ) Bioaccumulative potential Bioaccumulation: not applicable. Log Pow 0.81 (Experimental value; BASF test; 25 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Tetrasodium ethylenediaminetetraacetate, tetrahydrate ( ) Bioaccumulative potential No bioaccumulation data available. Log Pow (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Surface tension N/m (25 C) 08/20/2014 EN (English) 6/8

7 12.5. Other adverse effects Effect on ozone layer Effect on the global warming Other information : : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information Other information : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container in accordance with local/state/federal regulations. : Avoid release to the environment. : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Not listed on SARA Section 313 (Specific toxic chemical listings) RQ (Reportable quantity, section 304 of EPA's List of Lists) : SARA Section 311/312 Hazard Classes 1000 lb SARA Section Emission Reporting 100 % Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations 08/20/2014 EN (English) 7/8

8 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Tetrasodium pyrophosphate ( ) U.S. - New Jersey - Right to Know Hazardous Substance List Sodium tripolyphosphate ( ) U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List Sodium trimetaphosphate ( ) U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Indication of changes : HCS 2012 Compliance Update. Formulation Adjustment. Revision date : 08/20/2014 Other information : None. Full text of H-phrases: see section 16: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category Acute Tox. 4 (Oral) Acute toxicity (oral), Category Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category Aquatic Acute 2 Hazardous to the aquatic environment Acute Hazard, Category Aquatic Acute 3 Hazardous to the aquatic environment Acute Hazard, Category Eye Dam. 1 Serious eye damage/eye irritation, Category Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Flam. Liq. 4 Flammable liquids, Category Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H227 Combustible liquid H302 Harmful if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation H320 Causes eye irritation H335 May cause respiratory irritation H400 Very toxic to aquatic life H401 Toxic to aquatic life H402 Harmful to aquatic life SDS US (GHS HazCom 2012) - Custom The information provided on this document is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. 08/20/2014 EN (English) 8/8