8387A BULK MSDS-No. : V001.1 Revision: printing date: A BULK.

Transcription

1 Safety Data Sheet Page 1 of A BULK MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: 8387A BULK Identification of manufacturer, importer or distributor Importer: PT. Henkel Indonesien, TALAVERA Office Park, 21st Floor, Jl. T. B. Simatupang Kav.26, Jakarta Indonesia Tel no Fax no address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients General chemical description: Adhesive Declaration of ingredients: 2,2'- [Methylenebis(phenyleneoxymethylene )]bisoxirane Fatty acids, C18-unsatd., dimers, polymers with epichlorohydrin Poly[oxy(methyl-1,2-ethanediyl)], a-(2- aminomethylethyl)-w-(2- aminomethylethoxy) Methyl-2-phenyl-1H-imidazole Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) EINECS content Classification % Xi - Irritant; R36/38, R43 N - Dangerous for the environment; R51/ % Xn - Harmful; R20/21 R43 Xi - Irritant; R36/ % N - Dangerous for the environment; R51/53 Xi - Irritant; R36/37, R % C - Corrosive; R34 Xn - Harmful; R22 R52/ % Xi - Irritant; R37/38, R ,1-1 % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/53 Section 3. Hazards identification Hazard classification: Risk phrases: Xi - Irritant N - Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2 8387A BULK Page 2 of 6 Section 4. First aid measures Inhalation: Skin contact: Eye contact: Ingestion: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Rinse with running water and soap. Obtain medical attention if irritation persists. Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: water, carbon dioxide, foam, powder Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation. Remove sources of ignition. Do not empty into drains / surface water / ground water. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Section 7. Handling and storage Handling: Storage: Avoid skin and eye contact. See advice in chapter 8 Ensure good ventilation/extraction. Keep container tightly sealed. Keep frozen. Section 8. Exposure controls / personal protection Ingredient Type ppm mg/m 3 Remarks

3 Respiratory protection: 8387A BULK Page 3 of 6 Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Wear suitable protective clothing. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Section 9. Physical and chemical properties Appearance: blue paste Odor: mild Specific gravity: 1,37 Auto ignition: Not available. Flash point: > 100 C (> 212 F) Vapor pressure: Not applicable Solubility: Solvent: Water, Insoluble VOC content < 3 % (1999/13/EC) Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Stable under recommended storage conditions. Reacts with alcohols and amines. Reacts with oxidants, acids and lyes Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization. Hazardous decomposition products: Hazardous polymerization: Hydrocarbons carbon oxides. nitrogen oxides Rapid polymerization may generate excessive heat and pressure.

4 8387A BULK Page 4 of 6 Section 11. Toxicological information Inhalative toxicity: Skin irritation: Eye irritation: Sensitizing: May cause irritation to respiratory system. Irritating to the skin. Irritating to eyes., Prolonged or repeated contact may cause eye irritation. May cause sensitization by skin contact. Germ cell mutagenicity: Bisphenol-A epichlorhydrin resin MW <= Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without with and without Species Method Section 12. Ecological information Mobility: Cured adhesives are immobile. Ecotoxicity: Toxic to aquatic organisms : May cause long-term adverse effects in the aquatic environment. Toxicity: Bisphenol F diglycidyl ether Bisphenol F diglycidyl ether Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish 96 h OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC50 24 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 75 mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability: Bisphenol F diglycidyl ether Result under test conditions no biodegradation observed Route of application Degradability < 10 % Method 37 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test)

5 8387A BULK Page 5 of 6 Section 13. Disposal considerations Product Method of disposal: Packaging Disposal for uncleaned package: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Section 14. Transport information Road transport ADR: Classification code: M6 Hazard ident. number: 90 Technical name: Railroad transport RID: Classification code: M6 Hazard ident. number: 90 Technical name: Inland water transport ADN: Classification code: M6 Hazard ident. number: Technical name: Marine transport IMDG: EmS: F-A,S-F Seawater pollutant: Marine pollutant Proper shipping name:

6 8387A BULK Page 6 of 6 Air transport IATA: Packaging instructions (passenger) 964 Packaging instructions (cargo) 964 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol F diglycidyl ether) Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Safety phrases: Xi - Irritant, N - Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Global inventory status: Regulatory list KECI (KR) INV (CN) Notification yes yes Issue date: Disclaimer: Section 16. Other information This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. : This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.