MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 01 Issue date Revision date - Supersedes date - CAS # Product use Manufacturer information Manufacturer/Supplier: Mixture Industrial use. Unisorb Installation Technologies 4117 Felters Road, Michigan Center, MI PO Box 1000 Jackson, MI General Information: Emergency: CHEM TEL International: Hazards Identification Physical state Appearance Emergency overview Solid. Black paste. Low hazard for usual industrial or commercial handling by trained personnel. OSHA regulatory status This product is not hazardous according to OSHA 29CFR Potential health effects Eyes Skin Inhalation Ingestion Potential environmental effects 3. Composition / Information on Ingredients Direct contact with eyes may cause temporary irritation. adverse effects due to skin contact are expected. Under normal conditions of intended use, this material is not expected to be an inhalation hazard. harmful effects expected in amounts likely to be ingested by accident. t expected to be harmful to aquatic organisms. CAS # Percent Distillates (petroleum), hydrotreated heavy naphthenic Distillates (petroleum), hydrotreated light naphthenic vacuum Calcium oxide Quartz Titanium dioxide Composition comments 4. First Aid Measures First aid procedures Eye contact Any pigments or fillers in this product which may be considered "Hazardous" are potentially hazardous only if inhaled as an air-borne dust. Exposure by these ingredients as used in sealants, putties, bedding compounds and other non-sprayable products is highly unlikely. All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. Get medical attention promptly if symptoms occur after washing. 1 / 7

2 Skin contact Inhalation Ingestion 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions Specific methods Hazardous combustion products 6. Accidental Release Measures Wash off with soap and plenty of water. Get medical attention promptly if symptoms occur after washing. If symptomatic, move to fresh air. Get medical attention if symptoms persist. Seek medical advice. unusual fire or explosion hazards noted. Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Self-contained breathing apparatus operated in positive pressure mode and full protective clothing must be worn in case of fire. Move container from fire area if it can be done without risk. Carbon oxides. Silicon oxides. Nitrogen oxides. Personal precautions Wear appropriate personal protective equipment (See Section 8). Methods for cleaning up 7. Handling and Storage Handling Storage Sweep or scoop up and remove. Observe good industrial hygiene practices. Keep container closed. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit s 5 mg/m3 Inhalable fraction. Respirable fraction. 0.5 mg/m3 Inhalable fraction. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Distillate s (petroleum ), PEL 5 mg/m3 PEL 5 mg/m3 Mist mg/m3 500 ppm PEL 5 mg/m3 Mist mg/m3 500 ppm PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. 2 / 7

3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) PEL 15 mg/m3 Total dust. Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) 5 mg/m3 Mist. Respirable. 5 mg/m3 Fume. Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Respirable. 0.5 mg/m3 Aerosol, inhalable. Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) 3 mg/m3 Respirable fraction. Total dust. Respirable fraction. 0.5 mg/m3 Inhalable fraction. Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Distillate s (petroleum ), 5 mg/m3 Mist. 5 mg/m3 Mist. 3 / 7

4 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Mexico. Occupational Exposure Limit s Distillate s (petroleum ), Residues (petroleum ), Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Physical state Color Odor Odor threshold ph Vapor pressure Vapor density Boiling point Melting point/freezing point 5 mg/m3 Respirable dust. 5 mg/m3 Fume. Total dust. 5 mg/m3 Mist. 5 mg/m3 Mist. STEL 20 mg/m3 STEL Fume. 5 mg/m3 Fume. STEL 20 mg/m3 Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Wear a full-face respirator, if needed. Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Black paste. Solid. Paste. Black. Slight oil-like. t available. t available. t available. t available. t available. t available. 4 / 7

5 Solubility (water) Specific gravity 1.3 Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Insoluble Percent volatile > 0.1 Partition coefficient (n-octanol/water) 375 F (190.6 C) t available. t available. t available. data available. 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Sensitization Carcinogenicity ACGIH Carcinogens Material is stable under normal conditions. Avoid temperatures above 130 F (54.44 C). Strong oxidizing agents. hazardous decomposition products are known. Will not occur. sensitizing effects known. Distillates (petroleum), hydrotreated heavy naphthenic (CAS Distillates (petroleum), hydrotreated light naphthenic IARC Monographs. Overall Evaluation of Carcinogenicity US NTP Report on Carcinogens: Known carcinogen 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulation / Accumulation Partition coefficient Mobility in environmental media 13. Disposal Considerations Disposal instructions Contaminated packaging Due to the form of the product, exposure to the potentially carcinogenic components is not expected. A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. A2 Suspected human carcinogen. A4 t classifiable as a human carcinogen. A4 t classifiable as a human carcinogen. 1 Carcinogenic to humans. 2B Possibly carcinogenic to humans. 2B Possibly carcinogenic to humans. Known To Be Human Carcinogen. t expected to be harmful to aquatic organisms. data available. data available. data available. data available. Dispose of contents/container in accordance with local/regional/national/internat ional regulations. When this product as supplied is to be discarded as waste, it does not meet the definition of a RCRA waste under 40 CFR 261. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 5 / 7

6 14. Transport Information DOT t regulated as a hazardous material by DOT. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. TDG t regulated as dangerous goods. 15. Regulatory Information US federal regulations This product is not hazardous according to OSHA 29CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance (40 CFR 355, Appendix A) Section 311/312 (40 CFR 370) Drug Enforcement Administration (DEA) (21 CFR ) WHMIS status Inventory status Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - t controlled n-controlled Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) *A "" indicates this product complies with the inventory requirements administered by the governing country(s) State regulations Toxic Substances Control Act (TSCA) Inventory WARNING: This product contains chemicals known to the State of California to cause cancer. US - California Hazardous Substances (Director's): Listed substance Distillates (petroleum), hydrotreated heavy naphthenic (CAS 6 / 7

7 Distillates (petroleum), hydrotreated light naphthenic US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance US - California Proposition 65 - CRT: Listed date/carcinogenic substance US - New Jersey RTK - Substances: Listed substance Distillates (petroleum), hydrotreated light naphthenic US. Massachusetts RTK - Substance List Listed: October 1, 1988 Carcinogenic. Listed: September 2, 2011 Carcinogenic. Distillates (petroleum), hydrotreated heavy naphthenic (CAS Distillates (petroleum), hydrotreated light naphthenic US. New Jersey Worker and Community Right-to-Know Act t regulated. US. Pennsylvania RTK - Hazardous Substances 16. Other Information Further information HMIS ratings Health: 1 Flammability: 1 Physical hazard: 1 NFPA ratings Health: 1 Flammability: 1 Instability: 1 Disclaimer HMIS is a registered trade and service mark of the NPCA. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 7 / 7