MATERIAL SAFETY DATA SHEET

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1 MATERIAL SAFETY DATA SHEET Product name CAS # Product use Manufacturer 1. Product and Company Identification Cleansweep One Mixture Cleaner Graffiti Solutions Canada 552 St Thomas Rang Embrun, ON KA 1W CA Phone: Phone: Fax: CANUTEC Emergency overview Potential short term health effects Routes of exposure Eyes Skin Ingestion Target organs Chronic effects Signs and symptoms OSHA regulatory status 2. Hazards Identification DANGER MAY CAUSE CHEMICAL BURNS TO EYES AND SKIN. Eye, Skin contact,, Ingestion. Causes chemical burns. May cause blindness. May cause chemical burns. May cause respiratory tract irritation or chemical burns. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Eyes. Respiratory system. Skin. Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis. The product causes burns of eyes, skin and mucous membranes. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Composition/Information on Ingredients Components CAS # Percent Phosphoric acid Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt Sodium dodecylbenzenesulfonate Ethanol First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Immediately flush with water. Wash with soap and water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. #17771 Page: 1 of 8

2 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Not flammable by WHMIS/OSHA criteria. Dry chemical. Carbon dioxide. Fog. Firefighters should wear a self-contained breathing apparatus. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of phosphorus. Oxides of carbon. 6. Accidental Release Measures Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. 7. Handling and Storage DANGER May cause chemical burns to eyes and skin. Use good industrial hygiene practices in handling this material. Do not get this material in your eyes, on your skin, or on your clothing. Keep out of the reach of children. Store in a closed container away from incompatible materials. 8. Exposure Controls/Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Phosphoric acid (CAS ) Type STEL STEL TWA Value 1 ppm 3 mg/m3 1 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 191.1) Components Type Phosphoric acid (CAS ) Exposure limits PEL PEL Value 19 mg/m3 1 ppm 1 mg/m3 Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH or OSHA PEL. #17771 Page: 2 of 8

3 Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations General ventilation normally adequate. Wear chemical goggles. Rubber gloves. Confirm with a reputable supplier first. As required by employer code. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. Appearance Color Form Odor Odor threshold Physical state Clear light green Liquid Mint ph 1.2 Freezing point Boiling point Melting point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Liquid. 9. Physical and Chemical Properties 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Do not mix with other chemicals. Hazardous polymerization does not occur. Stable under recommended storage conditions. Reacts violently with alkaline material. This product may react with reducing agents. Reducing agents. Caustics. Oxidizers. May include and are not limited to: Oxides of carbon. Oxides of phosphorus. #17771 Page: 3 of 8

4 Toxicological data Components Acute Oral Species Mouse Dog Guinea pig Mouse 11. Toxicological Information Ethanol, 2-[2-[2-(tetradecyloxy)ethoxy]ethoxy]-, hydrogen sulfate, sodium salt (CAS ) Acute Dermal Oral Rabbit Acute Dermal Oral Effects of acute exposure Eye contact Skin contact Ingestion Sensitization Chronic effects Carcinogenicity ACGIH Carcinogens Causes chemical burns. May cause blindness. May cause chemical burns. May cause respiratory tract irritation or chemical burns. Test Results 39 mg/l, 4 Hours ppm, 4 Hours 55 mg/kg 56 mg/kg 345 mg/kg 76 mg/kg 274 mg/kg 153 mg/kg 27 mg/kg 438 mg/kg Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. See below. IARC Monographs. Overall Evaluation of Carcinogenicity A3 Confirmed animal carcinogen with unknown relevance to humans. Volume 44, Volume 96, Volume 1E 1 Carcinogenic to humans. Volume 96, Volume 1E 1 Carcinogenic to humans. US - California Proposition 65 - CRT: Listed date/carcinogenic substance Carcinogenic. #17771 Page: 4 of 8

5 US NTP Report on Carcinogens: Known carcinogen Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Ecotoxicity Ecotoxicological data Components Crustacea Aquatic Crustacea Fish 12. Ecological Information Known To Be Human Carcinogen. Components of this product have been identified as having potential environmental concerns. EC5 EC5 Aquatic Crustacea Fish Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity EC5 Species Daphnia Water flea (Daphnia magna) Fathead minnow (Pimephales promelas) Water flea (Ceriodaphnia dubia) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Partition coefficient Ethanol -.31 Sodium dodecylbenzenesulfonate.45 Chemical fate information 13. Disposal Considerations Test Results mg/l, 48 Hours mg/l, 48 hours > 1 mg/l, 96 hours mg/l, 48 hours mg/l, 96 hours Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. 14. Transport Information U.S. Department of Transportation (DOT) Basic shipping requirements: UN number UN185 Proper shipping name Phosphoric acid solution Hazard class 8 Packing group III Special provisions A7, IB3, N34, T4, TP1 Packaging exceptions 154 Packaging non bulk 23 Packaging bulk 241 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: UN number UN185 #17771 Page: 5 of 8

6 Proper shipping name Hazard class Packing group DOT PHOSPHORIC ACID, LIQUID 8 III TDG 15. Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number Canada WHMIS Ingredient Disclosure: Threshold limits WHMIS status 1 tonnes.1 % 1 % 1 % WHMIS classification WHMIS labeling Controlled Class E - Corrosive Material Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US federal regulations Yes This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) Not regulated. US CWA Section 311 Hazardous Substances: Listed substance CERCLA Hazardous Substance List (4 CFR 32.4) #17771 Page: 6 of 8

7 US CAA Section 111 Volatile Organic Compounds: Listed substance Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Not regulated. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. CERCLA (Superfund) reportable quantity Phosphoric acid: 5 Sodium dodecylbenzenesulfonate: 1 Ethanol: 1 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance US - Illinois Chemical Safety Act: Listed substance US - Louisiana Spill Reporting: Listed substance US - Minnesota Haz Subs: Listed substance US - New Jersey RTK - Substances: Listed substance US - New York Release Reporting: Hazardous Substances: Listed substance US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) #17771 Page: 7 of 8 No Yes

8 16. Other Information Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 3 X 3 Disclaimer Issue date Effective date Expiry date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 6-February February February-217 Prepared by Dell Tech Laboratories, Ltd. Phone: (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z4.1/Z Standard. #17771 Page: 8 of 8

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