DEMYSTIFYING COPPER FOR DISEASE MANAGEMENT

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1 DEMYSTIFYING COPPER FOR DISEASE MANAGEMENT Chemicool.com periodictable.com Kari Peter, Ph.D. Department of Plant Pathology and Environmental Microbiology Penn State University Fruit Research and Extension Center Biglerville, PA Ext

2 Understanding the ins and outs of copper and the best practices for using it in disease management How copper works Factors that impact the efficacy of copper sprays Copper injury: how phytotoxicity occurs Why ph matters Dos and don ts of using copper Using copper for disease management Apple Scab, Fire Blight Peach Leaf Curl, Bacterial Canker Bacterial Spot

3 How does copper work? Copper is a general biocide: Non-selective (plant, fungi, bacteria) Acts as a protectant for fungicide-bactericide treatments Apply before infection NO post-infection activity Sticks where it hits No re-distribution post application While on the leaf Requires moisture to be present on plant surface to be active Copper particles gradually desintegrate releasing copper ions Copper is most effective on those diseases that need free water present to develop Going in for the kill... The copper ions destroy critical enzymes important for cell to function

4 How does copper work? The challenge: To have copper ions present to kill the target (fungi, bacteria) while keeping concentration low enough to avoid copper injury on plants Using copper products that are relatively insoluble in water Soluble Bluestone: Copper sulfate pentahydrate Copper ions available all at once on leaf surface anytime water is present Residues rapidly removed by rain Low solubility (insoluble) Fixed copper Spray solution of fixed copper: suspension of copper particles Particles persist on leaf surface after dries Gradual release of copper ions when particles react with water on the leaf surface Residual protection; reduces phytotoxicity to plant tissues

Copper formulations are not created equal: Solubility in water differs among copper products Bluestone copper (Soluble) (Copper sulfate pentahydrate) Ex.

5 Copper formulations are not created equal: Solubility in water differs among copper products Bluestone copper (Soluble) (Copper sulfate pentahydrate) Ex. MasterCop + Lime = fixed Basic copper sulfate Nordox Addition of Hydrated lime D. Rosenberger, Cornell more Solubility in water less 100% soluble in water Copper Hydroxide Ex. Kocide 3000 Copper Oxychloride Ex. COC DF Basic copper sulfate Cuprous oxide Ex. Nordox Fixed coppers only partially soluble in water Note: Basic copper sulfate and copper sulfate (aka copper sulfate pentahydrate) are not the same

6 Efficacy of copper spray depends on the amount of elemental copper: % Metallic Copper Product Name Active Ingredient % Active Ingredient % Metallic Copper Cueva Copper octanoate Nordox Cuprous oxide Mastercop (soluble) Copper sulfate pentahydrate Kocide 3000 Copper hydroxide 30 DF 30 Champ Formula 2 Flowable Copper-Count-N (soluble) Copper hydroxide 37.5 F 24.4 Copper diammonia diacetate complex Badge X2 Copper oxychloride + copper hydroxide Nu-Cop Copper hydroxide COC DF Copper oxychloride

Efficacy of copper spray depends on the size of the copper particles: Particle size Copper particle size Determined by how finely copper has been ground Cannot be determined by looking at the product

7 Efficacy of copper spray depends on the size of the copper particles: Particle size Copper particle size Determined by how finely copper has been ground Cannot be determined by looking at the product Large particles Easily removed by wind or rain after leaf surfaces dry Small particles More small particles/lb = better spray coverage Adheres to plant surface better Longer residual activity (longevity of the product and release of copper ions) Small particle Large particle Hardy, S. et al. NSW DPI Primefacts #757, available at data/assets/pdf_file/0003/138171/

Efficacy of copper spray depends on the size of the copper particles: Particle Size Product Name Active Ingredient % Active Ingredient % Metallic Copper Cueva Copper octanoate 10.0 1.

8 Efficacy of copper spray depends on the size of the copper particles: Particle Size Product Name Active Ingredient % Active Ingredient % Metallic Copper Cueva Copper octanoate Mean Particle size (microns) Nordox Cuprous oxide Mastercop (soluble) Copper sulfate pentahydrate * Kocide 3000 Copper hydroxide 30 DF Champ Formula 2 Flowable Copper-Count-N (soluble) Copper hydroxide 37.5 F Copper diammonia diacetate complex Badge X2 Copper oxychloride + copper hydroxide * Nu-Cop Copper hydroxide COC DF Copper oxychloride

When using copper products on tree fruits, keep in mind the dos and don ts to minimize copper injury Solubility of fixed coppers increases under acidic conditions Copper will become more phytotoxic

9 When using copper products on tree fruits, keep in mind the dos and don ts to minimize copper injury Solubility of fixed coppers increases under acidic conditions Copper will become more phytotoxic if applied in an acidic solution Check the ph of your spray water acidic solutions worsens phytotoxicity Beware of adjuvants (LI-700) DO NOT mix copper with a foliar fertilizer or phosphorous acid product (Rampart, Phostrol, ProPhyt) DO NOT mix with mancozeb

10 The ph of copper formulations vary: Appreciating ph when it comes to copper sprays solution Rate/acre ph water 7.07 Cueva 2 qt Cueva + Double Nickel 2 qt + 1 qt 6.42 Cueva + Double Nickel + lime 2 qt + 1 qt +2 lbs Mastercop 1.5 pt 5.99 Mastercop + lime 1.5 pt + 2 lbs 9.26 Kocide 12.0 oz 7.52 Kocide + lime 12.0 oz + 2 lbs 12 Cuprofix Ultra 20.0 oz 7.34 Bordeaux mixture (copper sulfate pentahydrate + lime = fixed copper)

11 When using copper products on tree fruits, keep in mind the dos and don ts to minimize copper injury Solubility of fixed coppers increases under acidic conditions Copper will become more phytotoxic if applied in an acidic solution Check the ph of your spray water acidic solutions worsens phytotoxicity Beware of adjuvants DO NOT mix copper with a foliar fertilizer or phosphorous acid product (Rampart, Phostrol, ProPhyt DO NOT mix with mancozeb Be mindful of slow drying conditions (rain events) When green tissue is showing, do not apply copper just prior to predicted frosts Adding oil for mite control during the dormant copper spray helps residual activity (of copper) [temperature appropriate]

Using copper for disease management on apples: Dormant Green tip OBJECTIVE: Generate a copper residue that will persist and provide disease control that extends through leaf development stages

12 Using copper for disease management on apples: Dormant Green tip OBJECTIVE: Generate a copper residue that will persist and provide disease control that extends through leaf development stages (pending rainfall) Apple scab Kills overwintering spores Fire blight Kills bacteria on tree (oozing) Rate: Aim for metallic copper to be 2 lb/a Example: Kocide 3000 metallic Cu Equivalent 30% metallic Cu 2 lbs/a = ~ 6 lb Kocide metallic equiv *Liquid coppers follow a different calculation Be careful during dry years (no rain between ½ GT to Pink) = Russetting on sensitive cultivars

13 Using copper for disease management on apples: Cover sprays Risk: Copper injury on apple: Leaves and Fruit

14 Using dormant copper sprays for disease management on stone fruit: Early spring Peach leaf curl Bacterial canker: Bordeaux mixture

Bacterial Canker Management Goal: reduce number of bacteria before trees enter susceptible period Using Copper* Copper alone: evidence shows limited ability to control Bordeaux mixture PLUS vegetable

15 Bacterial Canker Management Goal: reduce number of bacteria before trees enter susceptible period Using Copper* Copper alone: evidence shows limited ability to control Bordeaux mixture PLUS vegetable oil Win Cowgill Rutgers Described: Sept, Oct, Nov, and in spring EXAMPLE: Timing Copper sulfate Lime Water Veg. Oil Sept 4 lb 6 lb 100 gal 2.8 qt Oct - early 5 lb 7 lb 100 gal 2.8 qt Oct late 8 lb 10 lb 100 gal 2.8 qt Nov 10 lb 10 lb 100 gal 2.8 qt Spring 5 lb 7 lb 100 gal 2.8 qt Notes: Use Powdered copper sulfate (bluestone or blue vitriol); Use FRESH hydrated lime (good quality calcium hydroxide) Tank ½ full of water + agitation: Add copper, then lime, then the oil

16 Using copper sprays for disease management: Bacterial spot Petal fall/shuck Split

17 Using copper for disease management: Bacterial spot cover sprays

18 Bacterial spot management during cover sprays: Copper recommendations (N. Lalancette, Rutgers) Okay to use 1 oz/a rate Product Name Active Ingredient % Active Ingredient % Metallic Copper REI PHI Postbloom Label Rate 0.5 oz/a metallic copper Cueva Copper Octanoate hrs 0 days gal 25 oz Nordox Cuprous oxide hrs 0 days 10.7 oz 0.7 oz Kocide 3000 Copper hydroxide 30 DF hrs 0 days oz 1.7 oz Mastercop (soluble) Champ Formula 2 Flowable Copper-Count-N (soluble) Badge X2 Copper sulfate pentahydrate hrs 21 days fl oz 7.4 fl oz Copper hydroxide 37.5 F hrs 21 days not listed 0.9 oz Copper diammonia diacetate complex Copper oxychloride + copper hydroxide hrs 21 days 1 qt 5.2 fl oz hrs 21 days oz 1.8 oz Nu-Cop Copper hydroxide hrs 21 days lbs 1.0 oz COC DF Copper oxychloride hrs 21 days lbs 1.0 oz If you use a copper not listed and need assistance figuring out the 0.5 oz/a rate: kap22@psu.edu

19 Copper injury on peach/nectarine: Leaves

Defoliation it does not take many lesions for this to occur Bacterial Spot K.

20 Bacterial Spot vs. Copper Injury Angular Always bordered by the veins Few or many lesions Yellowing associated with lesions Defoliation it does not take many lesions for this to occur Bacterial Spot K. Peter, PSU Copper/Chemical Injury Round (like a water droplet) Follows spray pattern Swiss cheese Yellowing not always associated with lesions Defoliation of older leaves Captan and sulfur injury: similar symptoms K. Peter, PSU

21 Take home messages: Solubility differences: fixed vs. bluestone Addition of hydrated lime to decrease solubility Importance of % metallic copper and particle size: residual nature of the copper Solubility of fixed coppers increases under acidic conditions Be mindful of slow drying conditions (rain events) When green tissue is showing, do not apply copper just prior to predicted frosts Adding oil for mite control during the dormant copper spray helps residual activity (of copper) [temperature appropriate] Dormant copper sprays: control apple scab, fire blight, peach leaf curl, bacterial canker, bacterial spot Cover sprays: Adjusted rates (0.5 oz/a metallic copper) for bacterial spot cover sprays

22 DEMYSTIFYING COPPER FOR DISEASE MANAGEMENT Chemicool.com periodictable.com QUESTIONS? Kari Peter, Ph.D. Department of Plant Pathology and Environmental Microbiology Penn State University Fruit Research and Extension Center Biglerville, PA Ext

What Copper Formulations are Best for Tree Fruit Applications?

What Copper Formulations are Best for Tree Fruit Applications? 2012 Mid-Atlantic Fruit and Vegetable Convention Hershey, PA 1 February 2012 Dave Rosenberger Cornell University s Hudson Valley Lab Highland,