SOLIK Li-hochleitende Keramiken für all-solid-state Batterien
|
|
- Barbra Stephens
- 6 years ago
- Views:
Transcription
1 SOLIK Li-hochleitende Keramiken für all-solid-state Batterien Dr. Ningxin ZHANG Electric Drive Technologies Center for Low-Emission Transport Austrian Institute of Technology GmbH
2 Outline Basic Data Project vision Good reasons for project Progress Perspectives Conclusion
3 Basic data Name of Institute: Austrian Institute of Technology GmbH Name and of project leader: Ningxin ZHANG, Partners: Paris-Lordon University Salzburg, Inst. Mater. Chem. & Phys. Technical University of Vienna, Inst. Tech. Chem. Förderprogramm: e!mission.at, 4 th Call Project Number: Duration: 01 May October 2017 (extended) Project budget: 701,
4 Visions Developing garnet structured electrolytes with the highest Li + conductivity through optimized strategy on doping and synthesis (PLUS). Uncovering the relationship between Li + conductivity and materials paramters of garnet electrolytes (TUW & AIT) Assembly and characterization of prototype all-solid-state LIBs (AIT) 4
5 Good reasons / Excellence Why All-Solid-State LIB: Green emobility Safety Why garnet structured LLZO (Li 7 La 3 Zr 3 O 12 ) electrolyte Phase structure Doping strategy Know-how on preparation of prototype Size effect Integration process Yuki Kato, et al, Nature Energy, DOI: /NENERGY John Christopher Bachman, et al, Chemical Review, DOI: /acs.chemrev.5b Dong Ok Shin, et al, Scientific Reports, DOI: /srep
6 OUTLET Basic Data Project vision Excellence of project Progress: synthesis of LLZO Perspectives Conclusion
7 LLZO powders synthesis Solid state process Synthesis strategies: Solid-state process Sol-gel process Sol-gel method sol gelation gel calcination 7
8 LLZO powders synthesis: XRD Solid state process Sol-gel process 8
9 Sintering parameters Li 7 La 3 Zr 2-x Nb x O 12 Solid state process Sol-gel process For powders synthesized via sol-gel process, small grains are obtained. For powders prepared with solid-state process, an optimized sintering strategy of lower temperature with prolonged time helps to grow large crystals. 9
10 Finished compositions D 3+ xli 7-x La 3 Zr 2 O 12 Li 7-y La 3 Zr 2-y D 5+ yo 12 Al Ga Ta Nb method solid state yes yes no Yes sol-gel no no yes Yes Doping level x(y) (per formula unit) Temperature ( C) 0.15/0.20/0.3/ /0.20/0.30/ /0.50/0.7 5/1.00/1.25/1. 50/1.75/ /0.50/0.75/ 1.00/1.25/1.50/ 1.75/2.00 synthesis 850 C/1050 C/1200 C 900 C/1100 C/1200 C 10
11 OUTLET Basic Data Project vision Excellence of project Progress: measuring Li + conductivity Perspectives Conclusion
12 Electrode configuration Type Metal paste Sputtered film Metal foil Materials Ag/Pt/Au Au/Pt/Li Li Treated Temperature 200~300 o C RT RT/170 o C Electrodeeletrolyte interface 12
13 Analysis of EIS R b R b +R gb Overall R R b R gb Solid State Ioncs,177(2006) J. Power Sources, 206(2012) J.Am.Ceram.Soc.,98(2015) Sputtered Au as electrodes Li foil as electrodes Sputtered Pt as electrodes 13
14 Microelectrodes Impedance Analyzer LLZO Microelectrodes Tip (W) Counter electrode Heat or cooling Counter electrode: Electrode: Ti/Pt 10 nm Ti 200 nm Pt Ø: µm Material: Al 0.20 pfu The application of microelectrodes makes it possible to identify the influence of grain boundary. 14
15 EIS results with microelectrode Repetitivity of EIS ~8mm Influence of electrode size Selection of electrodes Coutour plot of Li + conductivity The distribution of Li + conductivity in Al doped LLZO samples 15
16 Influence of electrode type Targets: Clearify the influence of electrode/electrolyte interface on the ionic conductivity in solid electrolyte Determnation of suitable electrode Samples: 6 LLZO pellets doped with Ga 0.3 with the similar geometry Same sintering and post treatment processes Electrode configuration: Symmetric: Ag-LLZO-Ag // Au-LLZO-Au // Li-LLZO-Li Asymmetric: Ag-LLZO-Au // Ag-LLZO-Li // Au-LLZO-Li Assembled into coin cells in a glove box filled with Ar 16
17 -Im(Z) (MΩ cm) EIS results 1 0,8 Au-LLZO-Au Li-LLZO-Li Li-LLZO-Au Li-LLZO-Ag Ag-LLZO-Au 0,6 0,4 0, ,2 0,4 0,6 0,8 1 Re(Z) (MΩ cm) 23 o C J Phys Chem Lett, 2015, 6,
18 LnR -Im(Z) (Ω) C 29 C 37 C 45 C C 66 C 78 C 92 C LLZO-Nb-0.25 EC-Lab Re(Z) (Ω) 9 8 Grain Grain boundary y = 6,0029x - 12,008 R² = 0,9992 RT: Grain σ = 3,52e-4 S/cm Grain boundary σ = 6,26e-5 S/cm Linear (Grain) Linear (Grain boundary) y = 3,1019x - 3,8978 R² = 0, ,5 2,7 2,9 3,1 3,3 3,5 1/T*1000 (K-1) 18
19 Ionic conductivity S/cm Summary of doping effects 1,E-02 1,E-03 Ta doped LLZO Nb-doped LLZO 1,E-04 1,E-05 1,E ,25 0,5 0,75 1 1,25 1,5 1,75 2 Doping level (pfu) Comment: Doping effect of Al & Ga to Li is more effective than that of Nb & Ta to Zr. Daniel Rettenwander, et al, Chem Mater, 2016, 28,
20 LLZO-Ga0.3pfu A possible mechanism is the evoluton of space charge layer as a function of temperature?? Arrhenius plot of conductivity of LLZO nanofiber membrane, PNAS, doi/pnas
21 OUTLET Basic Data Project vision Excellence of project Progress: Preparation of all-solid-state LiBs I. LLZO ceramic pellet II. LLZO thick film on separator III. LLZO thick film on anode Perspectives Conclusion
22 Thin Film battery Preparation of targets Structure & sintering Thin film deposition Magnetron sputtering by Energy Department of AIT in Tech Gate broken target due to thermal mismatchingbetween Cu plate and LLZO ceramic 22
23 Current (A) LLZO ceramic pellet: half cell 3,0E-06 2,0E-06 1,0E-06 Graphite-LLZO(Al0.2)-Li Graphite LLZO pellet Li foil 0,0E+00-1,0E-06 1st CV 2nd CV -2,0E-06-3,0E Voltage (V) 23
24 Specific capacity (mah/g) Current (µa) II. Thick LLZO film: full cell Assembly C/2 C/5 EIS LNMO-LLZO thick film-graphite LNMO-LLZO thick film-graphite ,5 3 3,5 4 4,5 5 5,5 Voltage (V) 1C LNMO LLZO thick film /separator Graphite C 4C 6C 6C 1C 1C Cycle number CV curve showed lithiation & de-lithiation peaks ~30% of the specific capacity of LNMO reached 24
25 III. LLZO-anode composite film Direct coating of LLZO film on anode Co-calendaring of electrolyte-electrode composite film LLZO - anode composite film Li foil Li metal piece as counter electrode After coating Assembly into EL-CELL Electrochemical measurements ungoing 25
26 Dissemination of results Publications on peer reviewed journals: Daniel Rettenwander, et al, Structural and electrochemical consequences of Al and Ga consubstituion in Li 7 La 3 Zr 2 O 12 solid electrolytes, Chemistry of Materials, 2016,28, (2016 IF: 9.407) Reinhard Wagner, et al, Crystal structure of garnet-related Li-ion conductor Li 7-3x Ga x La 3 Zr 2 O 12 : fast Li-ion conduction caused by a different cubic modification? Chemistry of Materials, 2016,28, (2016 IF: 9.407) Andreas Wachter-Welzl, et al, Microelectrodes for local conductivity and degradation measurements on Al stabilized Li 7 La 3 Zr 2 O 12 garnets, Journal of Electroceramics, 2016, doi: /s (2016 IF:1.263) Conference paper: Ningxin, Zhang, et al, Electrode interface effect on Li ionic conductivity of garnet solid electrolyte LLZO, ABAA9, the 9 th International Conference on Advanced Lithium Ion Batteries for Automotive Applications, 17-20th October, 2016, Huzhou, China. 26
27 Summary and perspectives Summary Combination among: Crystal structure and chemistry Electrical measurement and mechanism analysis Battery building and evaluation Perspective Gap to target Possibility to reach the target 27
28 Acknowledgment Thanks for the finacial support of this project from: Thanks for the great cooperation within the project: Prof. Georg Amthauer, Prof. C.A. Geigther, Dr. Daniel Rettenwander, Dr. Reinhard Wagner, and M. M. Maier et al from PLUS. Prof. Jürgen Fleig and Dr. Andreas Wachter-Welzl, Stenfanie Taibl et al from TU Wien. Prof. Atanaska Trifonova and other colleagues from AIT. 28
29 THANK YOU! Ningxin ZHANG, 27 th March 2017
Synthesis of Fine Cubic Li 7 La 3 Zr 2 O 12 Powders in Molten LiCl-KCl Eutectic and Facile Densification by Reversal of Li + /H + Exchange
Supporting Information Synthesis of Fine Cubic Li 7 La 3 Zr 2 O 12 Powders in Molten LiCl-KCl Eutectic and Facile Densification by Reversal of Li + /H + Exchange J. Mark Weller, Justin A. Whetten, Candace
More informationSupplementary Information for A Shortcut to Garnet-type Fast Li-Ion Conductors for All Solid State Batteries
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supplementary Information for A Shortcut to Garnet-type Fast Li-Ion Conductors
More informationAll-solid-state Li battery using a light-weight solid electrolyte
All-solid-state Li battery using a light-weight solid electrolyte Hitoshi Takamura Department of Materials Science, Graduate School of Engineering, Tohoku University Europe-Japan Symposium, Electrical
More informationNegating interfacial impedance in garnetbased solid-state Li metal batteries
In the format provided by the authors and unedited. DOI: 10.1038/NMAT4821 Negating interfacial impedance in garnetbased solid-state Li metal batteries Xiaogang Han, 1,a Yunhui Gong, 1,a Kun (Kelvin) Fu,
More informationDesign and fabrication of all-solid-state rechargeable lithium batteries using ceramic electrolytes
International Symposium on Electrical Fatigue in Functional Materials September 15, 2014 Sellin, Rügen, Germany Design and fabrication of all-solid-state rechargeable lithium batteries using ceramic electrolytes
More informationKuang-Che Hsiao. Supervisor: Prof. Tony West
New Potential Cathode Materials for Lithium-ion ion Battery - Synthesis and characterization of Li 1+x FePO 4-x N x cathode - Kuang-Che Hsiao Supervisor: Prof. Tony West 08/06/2010 E-mail: dtp09kh@sheffield.ac.uk
More informationTransition from Super-lithiophobicity to Super-lithiophilicity of Garnet Solid-State Electrolyte
Supporting Information Transition from Super-lithiophobicity to Super-lithiophilicity of Garnet Solid-State Electrolyte Wei Luo, 1,2, Yunhui Gong, 1,3, Yizhou Zhu, 1,3 Kun (Kelvin) Fu, 1,3 Jiaqi Dai, 1,3
More informationIon Transport across Grain Boundaries in Fast Lithium Ion Conducting Glass Ceramics
Engineering Conferences International ECI Digital Archives Functional Glasses: Properties And Applications for Energy and Information Proceedings Winter 1-8-2013 Ion Transport across Grain Boundaries in
More informationRechargeable Sodium-ion Batteries with a Cl-doped
Supplementary Information: Room-Temperature All-solidstate Rechargeable Sodium-ion Batteries with a Cl-doped Na 3 PS 4 Superionic Conductor Iek-Heng Chu a, Christopher Kompella a, Han Nguyen a, Zhuoying
More informationSupporting Information
Supporting Information Garnet electrolyte with an ultra-low interfacial resistance for Li-metal batteries Yutao Li, Xi Chen, Andrei Dolocan, Zhiming Cui, Sen Xin, Leigang Xue, Henghui Xu, Kyusung Park,
More informationSynthesis, crystal structure and conductive properties of garnet-type lithium ion conductor Al-free Li 7 x La 3 Zr 2 x Ta x O 12 (0 x 0.
Full paper Synthesis, crystal structure and conductive properties of garnet-type lithium ion conductor Al-free Li 7 x La 3 Zr 2 x Ta x O 12 (0 x 0.6) Naoki HAMAO, Kunimitsu KATAOKA, Norihito KIJIMA and
More informationA design of Solid-State Li-S cell with evaporated Lithium anode to eliminate shuttle effects
Supporting Information A design of Solid-State Li-S cell with evaporated Lithium anode to eliminate shuttle effects Yujie Hao, a Sheng Wang, a Feng Xu, a Yijie Liu, a Ningning Feng, a Ping He, *a Haoshen
More informationHigh-Performance All-Solid-State Lithium-Sulfur. Battery Enabled by a Mixed-Conductive Li 2 S
Supporting information High-Performance All-Solid-State Lithium-Sulfur Battery Enabled by a Mixed-Conductive Li 2 S Nanocomposite Fudong Han, Jie Yue, Xiulin Fan, Tao Gao, Chao Luo, Zhaohui Ma, Liumin
More informationThe Preparation of C/Ni Composite Nanofibers with Pores by Coaxial Electrospinning
2016 International Conference on Intelligent Manufacturing and Materials (ICIMM 2016) ISBN: 978-1-60595-363-2 The Preparation of C/Ni Composite Nanofibers with Pores by Coaxial Electrospinning Yiqiang
More informationToward the Design of High Voltage Magnesium-Lithium Hybrid Batteries using Dual-Salt Electrolytes
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supplemental Information Toward the Design of High Voltage Magnesium-Lithium Hybrid Batteries using
More informationDrawing a Soft Interface: An Effective Interfacial Modification Strategy for Garnet-type Solid-state Li Batteries
Drawing a Soft Interface: An Effective Interfacial Modification Strategy for Garnet-type Solid-state Li Batteries Yuanjun Shao 1,2,#,Hongchun Wang 2,#,Zhengliang Gong 2,*,Dawei Wang 3, Bizhu Zheng 3, Jianping
More informationSoft silicon anodes for lithium ion batteries
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supplementary Information Soft silicon anodes for lithium ion batteries Qizhen
More informationSupplementary Figure 1. Crystal structures of conventional layered and Li-rich layered manganese oxides. a, The crystal structure of rhombohedral
Supplementary Figure 1. Crystal structures of conventional layered and Li-rich layered manganese oxides. a, The crystal structure of rhombohedral LiMO 2 (M = Ni, Co, Mn) with the space group R3m. b, The
More informationSOFC Powders and Unit Cell Research at NIMTE. Jian Xin Wang, Jing Shao, You Kun Tao, Wei Guo Wang
595 10.1149/1.3205571 The Electrochemical Society SOFC Powders and Unit Cell Research at NIMTE Jian Xin Wang, Jing Shao, You Kun Tao, Wei Guo Wang Division of Fuel Cell and Energy Technology Ningbo Institute
More informationMATERIAL DEVELOPMENT AND PROCESSING ASPECTS OF CO-SINTERED CERAMIC ELECTRODES FOR ALL SOLID- STATE BATTERIES
MATERIAL DEVELOPMENT AND PROCESSING ASPECTS OF CO-SINTERED CERAMIC ELECTRODES FOR ALL SOLID- STATE BATTERIES Katja Waetzig, Jochen Schilm, B. Matthey, St. Barth, K. Nikolowski, M. Wolter Dresden, 20 th
More informationa) The self-diffusion coefficient of a metal with cubic structure can be expressed as
EXERCISES KJM5120 Chapter 5; Diffusion 1. Random (self) diffusion a) The self-diffusion coefficient of a metal with cubic structure can be expressed as 1 n D = s 6 t 2 where n/t represents the jump frequency
More informationNanocrystalline LiFePO4 as cathode material for lithium battery applications S.C SIAH
Nanocrystalline LiFePO as cathode material for lithium battery applications Abstract S.C SIAH Engineering Science Programme, National University of Singapore Kent Ridge, Singapore 119260 LiFePO was prepared
More informationImproving cyclic performance of Si anode for lithium-ion batteries by forming an intermetallic skin
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information Improving cyclic performance of Si anode for lithium-ion batteries by
More information6th International Conference on Advanced Design and Manufacturing Engineering (ICADME 2016)
6th International Conference on Advanced Design and Manufacturing Engineering (ICADME 2016) Porous Co3O4 irregular Micro-cubes with lithium storage performances Ting Wanga, Hao Zhengb, Jinsong Chengc,
More informationSUPPLEMENTARY INFORMATION
High Electrochemical Activity of the Oxide Phase in Model Ceria- and Ceria-Ni Composite Anodes William C. Chueh 1,, Yong Hao, WooChul Jung, Sossina M. Haile Materials Science, California Institute of Technology,
More informationSupporting Information for. A Water-in-Salt Electrolyte for Potassium-Ion Batteries
Supporting Information for A Water-in-Salt Electrolyte for Potassium-Ion Batteries Daniel P. Leonard #, Zhixuan Wei #, Gang Chen, Fei Du *, Xiulei Ji * Department of Chemistry, Oregon State University,
More informationSchool of Materials Science and Engineering, South China University of Technology,
Supporting information Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Co-Insertion Wei Sun, Fei Wang, Singyuk Hou, Chongyin Yang, Xiulin Fan, Zhaohui Ma, Tao Gao, Fudong Han, Renzong Hu, Min Zhu *, Chunsheng
More informationEffect of Starting Materials on the Characteristics of (La 1-x Sr x ) Mn 1+y O 3-δ Powder Synthesized by GNP
Korea-America nano forum Effect of Starting Materials on the Characteristics of (La 1-x Sr x ) Mn 1+y O 3-δ Powder Synthesized by GNP 2007. 04. 26 orea nstitute of eramic ngineering & echnology MI-Jai
More informationRe-building Daniell Cell with a Li-Ion exchange Film
Supplementary Information Re-building Daniell Cell with a Li-Ion exchange Film Xiaoli Dong, Yonggang Wang*, Yongyao Xia Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative
More informationDesign Principles for Solid Electrolyte Electrode Interfaces in All-Solid-State Li-Ion Batteries : Insight from First-Principles Computation.
Design Principles for Solid Electrolyte Electrode Interfaces in All-Solid-State Li-Ion Batteries : Insight from First-Principles Computation Yifei Mo Department of Materials Science and Engineering Maryland
More informationIn situ generation of Li 2 FeSiO 4 coating on MWNT as a high rate cathode material for lithium ion batteries
Supporting Information: In situ generation of Li 2 FeSiO 4 coating on MWNT as a high rate cathode material for lithium ion batteries Yi Zhao, Jiaxin Li, Ning Wang, Chuxin Wu, Yunhai Ding, Lunhui Guan*
More informationElectrical Property of Thick Film Electrolyte for Solid Oxide Fuel Cell
Journal of Metals, Materials and Minerals, Vol.18 No.2 pp.7-11, 28 Electrical Property of Thick Film Electrolyte for Solid Oxide Fuel Cell Thitimaporn DUANGMANEE 1, Suda WANNAKITTI 2, Rapeepong SUWANWARANGKUL
More informationHigh Performance Lithium Battery Anodes Using Silicon Nanowires
Supporting Online Materials For High Performance Lithium Battery Anodes Using Silicon Nanowires Candace K. Chan, Hailin Peng, Gao Liu, Kevin McIlwrath, Xiao Feng Zhang, Robert A. Huggins and Yi Cui * *To
More informationSolid Electrolytes: Are we there yet?
Solid Electrolytes: Are we there yet? 400 Apgar Drive, Unit E Somerset, NJ 08873 (732) 868-3141; sales@neicorporation.com www.neicorporation.com Solid Electrolytes for Lithium-ion and Lithium-Sulfur Batteries:
More informationFactors Governing Life of High-Energy Lithium-Ion Cells
Factors Governing Life of High-Energy Lithium-Ion Cells D.P. Abraham IBA 2013 March 11, 2013 Barcelona, Spain Research sponsors are both Government and Private Sector 2 Diagnostics Overview Use of characterization
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2015. Supporting Information for Adv. Energy Mater., DOI: 10.1002/aenm.201500096 A Tale of Two Sites: On Defining the Carrier Concentration
More informationSupporting Information for
Supporting Information for Self-stabilized solid electrolyte interface on host-free Li metal anode towards high areal capacity and rate utilization Zhenglin Hu 1,3, Shu Zhang 1, Shanmu Dong*,1, Quan Li
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 2018 Supplementary Information for Chemical Science, DOI: 10.1039/ ((please add manuscript
More informationInvestigation of anode materials for lithium-ion batteries
University of Wollongong Thesis Collections University of Wollongong Thesis Collection University of Wollongong Year 2006 Investigation of anode materials for lithium-ion batteries Ling Yuan University
More informationPHYSICAL PROPERTIES OF La 0.9 Sr 0.1 Cr 1-X Ni X O 3-δ (X = 0-0.6) SYNTHESIZED VIA CITRATE GEL COMBUSTION
PHYSICAL PROPERTIES OF La 0.9 Sr 0.1 Cr 1-X Ni X O 3-δ (X = 0-0.6) SYNTHESIZED VIA CITRATE GEL COMBUSTION Anuchit Ruangvittayanon * and Sutin Kuharuangrong Received: Sept 29, 2009; Revised: Nov 17, 2009;
More informationElectrolytes: Stabilized Zirconia
Laurea Magistrale in Scienza dei Materiali Materiali Inorganici Funzionali Electrolytes: Stabilized Zirconia Prof. Antonella Glisenti - Dip. Scienze Chimiche - Università degli Studi di Padova Bibliography
More informationChapter 7. Evaluation of Electrode Performance by. Electrochemical Impedance
Chapter 7 Evaluation of Electrode Performance by Electrochemical Impedance Spectroscopy (EIS) 7.1 Introduction A significant fraction of internal resistance of a cell comes from the interfacial polarization
More informationSYNTHESIS AND ELECTRICAL PROPERTIES OF Sr 3 NiNb 2 O 9 MATERIALS FOR SOFCs
Journal of Ovonic Research Vol. 12, No. 2, March April 2016, p. 81-86 SYNTHESIS AND ELECTRICAL PROPERTIES OF MATERIALS FOR SOFCs Q. LI *, Z. P. LIU, R. YAN, L. M. DONG College of Materials Science and
More informationDevelopment of Novel Anode Material for Intermediate Temperature SOFC (IT-SOFC)
Development of Novel Anode Material for Intermediate Temperature SOFC (IT-SOFC) Amit Sinha *, D. N. Miller and J.T.S. Irvine School of Chemistry, University of St Andrews North Haugh, St Andrews KY16 9ST
More informationNitrogen-Doped Graphdiyne Applied for Lithium-
Supporting Information for Nitrogen-Doped Graphdiyne Applied for Lithium- Ion Storage Shengliang Zhang,, Huiping Du,, Jianjiang He,, Changshui Huang,*, Huibiao Liu, Guanglei Cui and Yuliang Li Qingdao
More informationIn Situ IonicÕElectric Conductivity Measurement of La 0.55 Li 0.35 TiO 3 Ceramic at Different Li Insertion Levels
A1196 Journal of The Electrochemical Society, 151 8 A1196-A1201 2004 0013-4651/2004/151 8 /A1196/6/$7.00 The Electrochemical Society, Inc. In Situ IonicÕElectric Conductivity Measurement of La 0.55 Li
More informationEffect of heat treatment on electrochemical characteristics of spinel lithium titanium oxide
Korean J. Chem. Eng., 27(1), 91-95 (2010) DOI: 10.1007/s11814-009-0298-0 RAPID COMMUNICATION Effect of heat treatment on electrochemical characteristics of spinel lithium titanium oxide Sung-Chul Hong*,
More informationNew ceramic superionic materials for IT-SOFC applications
Materials Science-Poland, Vol. 23, No. 1, 2005 New ceramic superionic materials for IT-SOFC applications GRZEGORZ PAŚCIAK *, JACEK CHMIELOWIEC, PIOTR BUJŁO Electrotechnical Institute Division of Electrotechnology
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Surface graphited carbon scaffold enables simple
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supplementary Information Flame made nanoparticles permit processing of
More informationSelf-Healing Wide and Thin Li Metal Anodes Prepared. Using Calendared Li Metal Powder for Improving Cycle
Supporting Information Self-Healing Wide and Thin Li Metal Anodes Prepared Using Calendared Li Metal Powder for Improving Cycle Life and Rate Capability Dahee Jin, Jeonghun Oh, Alex Friesen, Kyuman Kim,
More informationNovel Materials for Lithium-Ion Batteries
Novel Materials for Lithium-Ion Batteries John Bradley May 18th 2012 Project Supervisors: Prof. West & Chaou Tan Abstract The effect of carbon coating on two novel battery cathode materials LiMnP 2 O 7
More informationIn-situ Study of Solid Electrolyte Interphase on Silicon Electrodes using PeakForce Tapping Mode AFM in Glove-box
General Motors R&D BROWN UNIVERSITY In-situ Study of Solid Electrolyte Interphase on Silicon Electrodes using PeakForce Tapping Mode AFM in Glove-box A. Tokranov 1, X. Xiao 2, C. Li 3, S. Minne 3 and B.
More informationStudy of lithium glassy solid electrolyte/electrode interface by impedance analysis
Bull. Mater. Sci., Vol. 23, No. 3, June 2, pp. 179 183. Indian Academy of Sciences. Study of lithium glassy solid electrolyte/electrode interface by impedance analysis A KARTHIKEYAN, P VINATIER and A LEVASSEUR*
More informationOperando Electron Magnetic Measurements in Li-ion Batteries. Supporting Information
Electronic Supplementary Material (ESI) for Energy. This journal is The Royal Society of Chemistry 2014 Operando Electron Magnetic Measurements in Li-ion Batteries Gregory Gershinsky, Elad Bar, Laure Monconduit,
More informationA gel-ceramic multi-layer electrolyte for long-life lithium sulfur batteries
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting information A gel-ceramic multi-layer electrolyte for long-life lithium sulfur batteries
More informationSupporting Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2018 Supporting Information High performance All-Solid-State Li-Se Batteries induced
More informationPolymer-Rich Composite Electrolytes for All Solid-State Li-S Cells
Supporting Information Polymer-Rich Composite Electrolytes for All Solid-State Li-S Cells Xabier Judez,, Heng Zhang,*, Chunmei Li,*, Gebrekidan Gebresilassie Eshetu, Yan Zhang, José A. González-Marcos,
More informationInductively Coupled Plasma Etching of Pb(Zr x Ti 1 x )O 3 Thin Films in Cl 2 /C 2 F 6 /Ar and HBr/Ar Plasmas
Korean J. Chem. Eng., 19(3), 524-528 (2002) Inductively Coupled Plasma Etching of Pb(Zr x Ti 1 x )O 3 Thin Films in Cl 2 /C 2 F 6 /Ar and HBr/Ar Plasmas Chee Won Chung, Yo Han Byun and Hye In Kim Department
More informationElectronic Supplementary Material (ESI) for Chemical Communications This journal is The Royal Society of Chemistry 2013
Sodium-ion battery based on ion exchange membranes as electrolyte and separator Chengying Cao, Weiwei Liu, Lei Tan, Xiaozhen Liao and Lei Li* School of Chemical and Chemistry Engineering, Shanghai Jiaotong
More informationLiNi 0.5 Mn 1.5 O 4 porous nanorods as high-rate and long-life cathode for Li-ion batteries
Supporting Information LiNi 0.5 Mn 1.5 O 4 porous nanorods as high-rate and long-life cathode for Li-ion batteries Xiaolong Zhang, Fangyi Cheng, Jingang Yang, Jun Chen* Key Laboratory of Advanced Energy
More informationElectrochemical performance of lithium-rich layered oxides for
IBA 2013 Electrochemical performance of lithium-rich layered oxides for electric vehicle applications Jay Hyok Song, Andrei Kapylou, Chang Wook Kim, Yong Chan You, and Sun Ho Kang* SAMSUNG SDI Contents
More informationNovel Mn 1.5 Co 1.5 O 4 spinel cathodes for intermediate temperature solid oxide fuel cells
Novel Mn 1.5 Co 1.5 O 4 spinel cathodes for intermediate temperature solid oxide fuel cells Huanying Liu, a, b Xuefeng Zhu, a * Mojie Cheng, c You Cong, a Weishen Yang a * a State Key Laboratory of Catalysis,
More informationSupporting Information
Supporting Information Hydrogenation Driven Conductive Na 2 Nanoarrays as Robust Binder-Free Anodes for Sodium-Ion Batteries Shidong Fu, Jiangfeng Ni, Yong Xu, Qiao Zhang*, and Liang Li*, College of Physics,
More informationDevelopment of Novel NOx Sensors and System Integration with Alumina Heater Elements
Development of Novel NOx Sensors and System Integration with Alumina Heater Elements UC Riverside PEMS 2016 International Conference & Workshop March 17, 2016 F. Bell, M. Boettcher, J. Chee, J. Fitzpatrick,
More informationRuthenium Oxide Films Prepared by Reactive Biased Target Sputtering
Ruthenium Oxide Films Prepared by Reactive Biased Target Sputtering Hengda Zhang Anthony Githinji 1. Background RuO2 in both crystalline and amorphous forms is of crucial importance for theoretical as
More informationZnO-based Transparent Conductive Oxide Thin Films
IEEE EDS Mini-colloquium WIMNACT 32 ZnO-based Transparent Conductive Oxide Thin Films Weijie SONG Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, P. R. China
More informationEffect of nano Si addition on synthesized LTO for lithium battery anode
IOP Conference Series: Earth and Environmental Science PAPER OPEN ACCESS Effect of nano Si addition on synthesized LTO for lithium battery anode To cite this article: A Zulfia et al 2018 IOP Conf. Ser.:
More informationElucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale
Elucidating the Phase Transformation of Li4Ti5O12 Lithiation at the Nanoscale Michael G. Verde 1*, Loïc Baggetto 2, Nina Balke 3, Gabriel M. Veith 2, Joon Kyo Seo 4, Ziying Wang 1, Ying Shirley Meng 1*
More informationSupplementary Information. Reversible superconductor-insulator transition in LiTi 2 O 4 induced by
Supplementary Information Reversible superconductor-insulator transition in LiTi 2 O 4 induced by Li-ion electrochemical reaction K. Yoshimatsu 1,*, M. Niwa 1, H. Mashiko 1, T. Oshima 1 & A. Ohtomo 1,2
More informationCeramic Processing Research
Journal of Ceramic Processing Research. Vol. 16, No. 1, pp. 49~53 (2015) J O U R N A L O F Ceramic Processing Research Effect of particle size on the density and ionic conductivity of Na 3 Zr 2 Si 2 PO
More informationSupporting Information
Supporting Information Structure and Solution Dynamics of Lithium Methyl Carbonate as a Protective Layer For Lithium Metal Haodong Liu, Xuefeng Wang, Hongyao Zhou, Hee-Dae Lim, Xing Xing, Qizhang Yan,
More informationChristodoulos Chatzichristodoulou Technical University of Denmark, Department of Energy Conversion and Storage
Fuel Cell & Hydrogen Technologies JP SP2: Catalyst and Electrodes Borovetz, Bulgaria June 2 nd and 3 rd 2014 The need for localized electrochemical measurements and the promise of Controlled Atmosphere
More informationSUPPORTING INFORMATION. High-Voltage and Noncorrosive Ionic Liquid Electrolyte Used in Rechargeable Aluminum Battery
SUPPORTING INFORMATION High-Voltage and Noncorrosive Ionic Liquid Electrolyte Used in Rechargeable Aluminum Battery Huali Wang, Sichen Gu, Ying Bai,, ** Shi Chen, Feng Wu,, and Chuan Wu,, ** Beijing Key
More informationInfluence of radio frequency power on structure and ionic conductivity of LiPON thin films
Bull. Mater. Sci., Vol. 31, No. 4, August 2008, pp. 681 686. Indian Academy of Sciences. Influence of radio frequency power on structure and ionic conductivity of LiPON thin films ZONGQIAN HU*, DEZHAN
More informationStudy on electrical properties of Ni-doped SrTiO 3 ceramics using impedance spectroscopy
Bull. Mater. Sci., Vol. 28, No. 3, June 2005, pp. 275 279. Indian Academy of Sciences. Study on electrical properties of Ni-doped SrTiO 3 ceramics using impedance spectroscopy S K ROUT*, S PANIGRAHI and
More informationSupplementary Information for
Supplementary Information for An elastic and Li-ion-percolating hybrid membrane stabilizes Li metal plating Quan Pang, Laidong Zhou, Linda F. Nazar* Department of Chemistry and the Waterloo Institute for
More informationAnomalous high ionic conductivity of nanoporous β-li 3 PS 4
Anomalous high ionic conductivity of nanoporous β-li 3 PS 4 Zengcai Liu 1, Wujun Fu 1, E. Andrew Payzant 1,2, Xiang Yu 1, Zili Wu 1,3, Nancy J. Dudney 2, Jim Kiggans 2, Kunlun Hong 1, Adam J. Rondinone
More informationLower Cost Higher Performance Graphite for LIBs. Prepared by: Dr. Edward R. Buiel President and CEO Coulometrics, LLC. Date: March 23, 2017
Lower Cost Higher Performance Graphite for LIBs Prepared by: Dr. Edward R. Buiel President and CEO Coulometrics, LLC. Date: March 23, 2017 Outline Company overview Review of natural graphite resources
More informationALD TiO 2 coated Silicon Nanowires for Lithium Ion Battery Anodes with enhanced Cycling Stability and Coulombic Efficiency
ALD TiO 2 coated Silicon Nanowires for Lithium Ion Battery Anodes with enhanced Cycling Stability and Coulombic Efficiency Elmira Memarzadeh Lotfabad a, Peter Kalisvaart a,*, Kai Cui b, Alireza Kohandehghan
More informationElectrochemical Supercapacitors in F.E.E.Lab
Electrochemical Supercapacitors in F.E.E.Lab Keryn Lian Department of Materials Science and Engineering University of Toronto Keryn.lian@utoronto.ca 416-978-8631 Power Density (W/kg) Supercapacitors and
More informationNovel concept of rechargeable battery using iron oxide nanorods. anode and nickel hydroxide cathode in aqueous electrolyte
Supplementary Information for: Novel concept of rechargeable battery using iron oxide nanorods anode and nickel hydroxide cathode in aqueous electrolyte Zhaolin Liu *, Siok Wei Tay and Xu Li Institute
More informationAll-solid-state Batteries with Thick Electrode Configurations
All-solid-state Batteries with Thick Electrode Configurations Yuki Kato, * Shinya Shiotani, Keisuke Morita, Kota Suzuki, Masaaki Hirayama, Ryoji Kanno Toyota Motor Europe NV/SA, Hoge Wei 33, 1930 Zaventem,
More informationCluster-Assembled Nanophase (5 to 25 nm grains) Materials, Siegel, Annu. Rev. Mater. Sci. 21 (2991) 559.
Cluster-Assembled Nanophase (5 to 25 nm grains) Materials, Siegel, Annu. Rev. Mater. Sci. 21 (2991) 559. Thermal evaporation of metals either in an inert gas or a reactive atmosphere. Metals, ceramics,
More informationUudergraduate Honors Thesis. Ge Zhu 4/13/2018
Development of LiNi0.5Mn.1.5-xTixO4 as an Advanced Cathode for Lithium-Ion Batteries Uudergraduate Honors Thesis Ge Zhu 4/13/2018 Department of Mechanical and Aerospace Engineering Advisor: Dr. Jung Hyun
More informationLaboratory of Advanced Ceramics for Energy and Environment Introduction Prof. Younki Lee
Laboratory of Advanced Ceramics for Energy and Environment Introduction Prof. Younki Lee School of Materials Science and Engineering Gyeongsang National University, Jinju, Republic of Korea 2 Research
More informationValue Proposition for MicroGrid Expanded Metal Current Conducting Foil in Li-ion Cells
NAATBATT Conference March 2016 Value Proposition for MicroGrid Expanded Metal Current Conducting Foil in Li-ion Cells Presented By: John Hart Business Development Manager Power Technologies j.hart@dexmet.com
More informationFeasibility of Using Active Batteries for Munitions Applications
Feasibility of Using Active Batteries for Munitions Applications Dr. Jeffrey Read 7-Dec-2016 Outline Background Electrochemistry @ ARL Active battery systems Long term storage data Li/CF x batteries Li/SOCl
More informationComputation-Guided Understanding and Design of Interfaces in All-Solid-State Li-ion Batteries. Yifei Mo
Computation-Guided Understanding and Design of Interfaces in All-Solid-State Li-ion Batteries Yifei Mo Assistant Professor Department of Materials Science and Engineering University of Maryland Energy
More informationInvestigation of anode materials for lithium-ion batteries
University of Wollongong Thesis Collections University of Wollongong Thesis Collection University of Wollongong Year 2006 Investigation of anode materials for lithium-ion batteries Ling Yuan University
More informationGalvanostatic charge discharge tests, 57 Fe and 119 Sn Mössbauer and XRD measurements on novel Sn-Ni-Fe electrodeposits
Hyperfine Interact DOI 10.1007/s10751-012-0693-5 Galvanostatic charge discharge tests, 57 Fe and 119 Sn Mössbauer and XRD measurements on novel Sn-Ni-Fe electrodeposits G. B. Lak E. Kuzmann M. El-Sharif
More informationSynthesis and Evaluation of Electrocatalysts for Fuel Cells
Synthesis and Evaluation of Electrocatalysts for Fuel Cells Jingguang Chen Center for Catalytic Science and Technology (CCST) Department of Chemical Engineering University of Delaware Newark, DE 19711
More informationSTRUCTURAL AND ELECTRICAL PROPERTIES OF Sb 2 O 3 THIN FILMS
STRUCTURAL AND ELECTRICAL PROPERTIES OF Sb 2 O 3 THIN FILMS NICOLAE ÞIGÃU Faculty of Sciences, Dunãrea de Jos University of Galaþi, 47 Domneascã Street, 800201, Romania e-mail: ntigau@ugal.ro Received
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Deterioration mechanism of LiNi 0.8 Co 0.15 Al 0.05
More informationHigh energy all-solid-state lithium batteries with
Supporting Information High energy all-solid-state lithium batteries with ultralong cycle life Xiayin Yao, Deng Liu, Chunsheng Wang, Peng Long, Gang Peng, Yong-Sheng Hu, *, Hong Li, Liquan Chen, and Xiaoxiong
More informationSupporting information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting information An amorphous material with sponge-like structure as anode for Liion and
More informationLithium Batteries with Nearly Maximum Metal. Storage Supporting Information
Lithium Batteries with Nearly Maximum Metal Storage Supporting Information Abdul-Rahman O. Raji,, Rodrigo Villegas Salvatierra,, Nam Dong Kim, Xiujun Fan, Yilun Li, Gladys A. L. Silva, Junwei Sha and James
More informationSUPPORTING INFORMATION. A Rechargeable Aluminum-Ion Battery Based on MoS 2. Microsphere Cathode
SUPPORTING INFORMATION A Rechargeable Aluminum-Ion Battery Based on MoS 2 Microsphere Cathode Zhanyu Li a, Bangbang Niu a, Jian Liu a, Jianling Li a* Feiyu Kang b a School of Metallurgical and Ecological
More informationLow Cost Bipolar Plates for Large Scale PEM Electrolyzers
1 Low Cost Bipolar Plates for Large Scale PEM Electrolyzers A. S. Gago, A. S. Ansar, P. Gazdzicki, N. Wagner, J. Arnold, K. A. Friedrich Electrochemical Energy Technology Institute of Engineering Thermodynamics
More informationSupporting Information. Kirkendall Diffusion, and their Electrochemical Properties for use in Lithium-ion
Supporting Information Preparation of Hollow Fe 2 O 3 Nanorods and Nanospheres by Nanoscale Kirkendall Diffusion, and their Electrochemical Properties for use in Lithium-ion Batteries Jung Sang Cho 1,2,
More information