Combined evaluation of EPRTR and UWWTD reporting

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2 2008 PRTR water emissions of priority substances installations total 404 installations with releases to water 235 installations with releases of priority substances

3 2008 PRTR water emissions of priority substances mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) number of reported releasse

4 2008 PRTR water emissions of priority substances mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) reported releases (kg/y)

5 2008 PRTR water emissions of priority substances mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) percentage of total release

6 2008 PRTR water emissions of priority substances a more detailed look into chemical industry waste and waste water management

7 Chemical Industry explosives and pyrotechnic products gases non metals, metal oxides oxygen containing hydrocarbons salts simple hydrocarbons trichlororbenzenes (all isomers) trichloromethane PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds hexachlorocyclohexane (HCH) dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) acids basic inorganic chemicals basic organic chemicals basic pharmaceutical products basic plastic materials dyes and pigments trichlororbenzenes (all isomers) trichloromethane PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds hexachlorocyclohexane (HCH) dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) percentage of total release

8 waste and waste water management recovery or disposal of hazardous waste Urban waste water treatment plants > 100,000 p.e. trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) incineration of non hazardous waste Independently operated industrial waste water treatment plants Landfills receiving > 10 t/d or > t tot. Capacity trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) number of reported releasse

9 waste and waste water management recovery or disposal of hazardous waste Urban waste water treatment plants > 100,000 p.e. trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) incineration of non hazardous waste Independently operated industrial waste water treatment plants Landfills receiving > 10 t/d or > t tot. Capacity trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) percentage of total release

10 merging PRTR and UWWTD UWWTP (PRTR (5f)) 202 sewage treatment plants size > 100,000 p.e. (100, Mio. p.e.) loads of priority substances (17 substances reported) substances specific thresholds UWWTP (91/271/EWG) agglomerations > 2,000 p.e. ~ 4000 in Germany (234 plants > 100,000 p.e) organic design capacity (p.e.) nominal load (p.e.)

11 ODC distribution > > Ausbaugröße in EW > > > > Anzahl der KA

12 smallest plants with reported releases priority substance ODC p.e nominal load p.e. load kg/a Nickel ,9 Mercury ,30 Lead ,3 Cadmium ,10 Di-2-Ethylhexylphthalat ,40 Nonylphenol ,84 PCP ,98 Dichloromethan ,97 Octylphenole und Octylphenolethoxylate , Dichlorethan ,95

13 smallest plants with reported releases priority substancef ODC p.e nominal load p.e. load kg/a Tributyltin ,61 Diuron ,49 Trichlormethane ,0 Trichlorbenzenes ,21 Hexachlorcyclohexane ,95 Isoproturon ,16 Fluoranthene ,00

14 per capita emissions -mercury and compounds- 0, ,00006 EW-spezifische Hg-Fracht (kg/ew/a) 0, , , , , Nominalbelastung (EW)

15 per capita emissions -mercury and compounds- 56 reports 27 measured 25 calculated 4 estimated

16 per capita emissions -lead and compounds- 0,0025 0,002 EW-spezifische Blei-Fracht (kg/ew/a) 0,0015 0,001 0, Nominalbelastung (EW)

17 per capita emissions -lead and compounds- 48 reports 23 measured 20 calculated 5 estimated

18 per capita emissions -cadmium and compounds- 0,00025 EW-spezifische Cadmium-Fracht (kg/ew/a) 0,0002 0, ,0001 0, Nominalbelastung (EW)

19 per capita emissions -cadmium and compounds- 18 reports 13 measured 4 calculated 1 estimated

20 per capita emissions -nickel and compounds- 0,005 0,0045 EW-spezifische Nickel-Fracht (kg/ew/a) 0,004 0,0035 0,003 0,0025 0,002 0,0015 0,001 0, Nominalbelastung (EW)

21 per capita emissions -nickel and compounds- 132 reports 66 measured 61 calculated 5 estimated

22 per capita emissions -Nonylphenole- 0, ,00025 EW spezifische N-Fracht (kg/ew/a) 0, , , , , Nominalbelastung EW

23 per capita emissions Di-2-Ethylhexylphthalate 0, ,0003 EW-spezifische Arsen-Fracht (kg/ew/a) 0, ,0002 0, ,0001 0, Nominalbelastung (EW)

24 conclusions the urban waste water system is an important source detailed and regionalised knowledge of infrastructure necessary reliable extrapolations via per-capita emission factors high quality analytical data required (LOD artifacts)

25 our next steps evaluate data from special investigations design»sample«for model calculations design and perform monitioring program

26 Thank you

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