Test Report. Sample Information. Overall Rating. Article / complies / with the FiTS. / Submitted Samples

Transcription

1 Page 1 of 10 Test Report Customer: Tchibo GmbH BV Order No.: Contact Person: Überseering Report No.: Deutschland Report Version: 1 Andrée Ahrens Date of Reception: (25415) Customer Reference: PJN 85872; Brand Name: TCM - ARTICLE NO. - Report Date: Importer/Supplier: VR King UG, Wiclefstrasse 18, Date of Order: Berlin, Germany Importer Contact: Hendrik Schicke Sampled By: client Testing Requirements: Q & P Information: Sample Description: Sample Information Tested according to "FiTS" requirements Complete specifications of quality and testing are attached to the sample, VR cardboard glasses for smartphones Performance Date: No. of orkdays: 1 Overall Rating Article / complies / ith the FiTS. / Nr. 1 Submitted Samples.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

2 Page 2 of 10 Tests required Alkylphenols Azo dyes Allergenic disperse dyes & carcinogenic dyestuffs Formaldehyde Lead and Cadmium, total content Odour estimation PAH (Polycyclic aromatic hydrocarbons) Pentachlorophenol (PCP) Phthalates acc. to REACH Tinorganic compounds Summary of Test Results Tested according to "FiTS" requirements Conclusion No Conclusion Remark.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

3 Page 3 of 10 PLEASE NOTE: For samples that are marked ith ** on the folloing pages the result as generated from a composite sample (mixed satch/mixed sample/non separable components). As the sample cannot be separated/is very difficult to separate, no single testing components might not pass the test. REACH PHTHALATES: At concentrations of more than 0.1 % (1000 mg/kg) for any of the REACH-relevant phthalates (related to every article of the complex article) the supplier is obligated to inform the recipient (in every case) and the customers (only at request) in accordance to article 33 of 1907/2006/EC (REACH regulation). List of not tested parameters: Dimethylfumarate: Adhesive, glue: not relevant Screening on Volatile Substances (VOC):not relevant Paint, lacquer and coatings: Screening on Volatile Substances (VOC):not relevant Polymers ithout Food contact: Hexabromocyclododecane:not relevant Sensitizing disperse dyes not relevant Textile, synthetic materials: Formaldehyde: not relevant Dimethylfumarate: not relevant Alkylphenols: not relevant Alkylphenolethoxylates: not relevant PFOA/PFOS: not relevant Chlorinated organic carriers: not relevant.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

4 Page 4 of 10 Article No Sample ID Sample description Tested Samples ) Coated cardboard multicoloured** ) Coated cardboard multicoloured**, 2) Plastic lenses transparent (2 mixed components) ) Adhesive foil transparent, 4) Foam dark grey, 5) Rubber band black (3 mixed components) ) Hook and Loop Fastener black Complete article Test Results Tested according to "FiTS" requirements Sample Description: 1) Coated cardboard multicoloured** Lab Reference No: Formaldehyde, free in paper and cardboard: EN 645 cold ater extraction, EN 1541 photometric determination, reporting limit: 5 mg/kg Formaldehyde 150 mg/kg <5 mg/kg Pentachlorophenol (PCP) in paper: EN ISO Pentachlorophenol (PCP) 0.15 mg/kg <0.05 mg/kg Sample Description: 1) Coated cardboard multicoloured**, 2) Plastic lenses transparent (2 Lab Reference No: mixed components) Alkylphenols: BVCPS inhouse method, ultrasound extraction ith Methanol ( plastics THF/Methanol), determination using GC-MS, reporting limit: 3 mg/kg / % Nonylphenols (NP) <3 mg/kg No Specification Octylphenols (OP) <3 mg/kg No Specification Sum of Alkylphenols 100 mg/kg not detected Lead & Cadmium, total content: DIN EN 14602, reporting limit: 1 mg/kg Cadmium (Cd) 100 mg/kg <1 mg/kg Lead (Pb) 90 mg/kg 2.0 mg/kg Determination of PAH: ZEK , ultrasound extraction ith Toluene, determination ith GC-MS (SIM), reporting limit: 0.2 mg/kg Benzo (a) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (e) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (a) anthracene 0.2 mg/kg <0.2 mg/kg Chrysene 0.2 mg/kg <0.2 mg/kg Benzo (b) fluoranthene 0.2 mg/kg <0.2 mg/kg Benzo (j) fluoranthene 0.2 mg/kg <0.2 mg/kg Benzo (k) fluoranthene 0.2 mg/kg <0.2 mg/kg Dibenzo (a,h) anthracene 0.2 mg/kg <0.2 mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

5 Continuted\Unseiter Page 5 of 10 Sample Description: 1) Coated cardboard multicoloured**, 2) Plastic lenses transparent (2 Lab Reference No: mixed components) Determination of PAH: ZEK , ultrasound extraction ith Toluene, determination ith GC-MS (SIM), reporting limit: 0.2 mg/kg Naphthalene 0.2 mg/kg <0.2 mg/kg Acenaphtylene 0.2 mg/kg <0.2 mg/kg Acenaphtene 0.2 mg/kg <0.2 mg/kg Fluorene 0.2 mg/kg <0.2 mg/kg Phenanthrene 0.2 mg/kg <0.2 mg/kg Anthracene 0.2 mg/kg <0.2 mg/kg Fluoranthene 0.2 mg/kg <0.2 mg/kg Pyrene 0.2 mg/kg <0.2 mg/kg Indeno (1,2,3-cd) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (g,h,i) perylene 0.2 mg/kg <0.2 mg/kg Sum of all PAH's 1 mg/kg not detected Phthalates: Phthalates acc. to REACH, reporting limit: % Diisobutylphthalate (DiBP) measurement Dibutylphthalate (DBP) measurement Benzylbutylphthalate (BBP) Di(2-ethylhexyl)phthalate (DEHP) measurement 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate Bis(2-methoxyethyl)phthalate (DMEP) Di-iso-pentylphthalate (DiPP) n-pentyl-iso-pentylphthalate (PiPP) 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear Dipenthylphthalate (DPP) Di-n-hexylphthalate (DnHP) 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear (DiHP) Di-hexylphthalate, branched and linear (DHxP) Tinorganic compounds: DIN EN ISO modified / DIN modified, reporting limit: mg/kg Dioctyltin (DOT) 1 mg/kg <0.025 mg/kg Monobutyltin (MBT) 1 mg/kg <0.025 mg/kg Dibutyltin (DBT) 1 mg/kg <0.025 mg/kg Tributyltin (TBT) 1 mg/kg <0.025 mg/kg Triphenyltin (TPhT) 1 mg/kg <0.025 mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

6 Page 6 of 10 Sample Description: 3) Adhesive foil transparent, 4) Foam dark grey, 5) Rubber band black Lab Reference No: (3 mixed components) Alkylphenols: BVCPS inhouse method, ultrasound extraction ith Methanol ( plastics THF/Methanol), determination using GC-MS, reporting limit: 3 mg/kg / % Nonylphenols (NP) 3.9 mg/kg No Specification Octylphenols (OP) <3 mg/kg No Specification Sum of Alkylphenols 100 mg/kg 3.9 mg/kg Lead & Cadmium, total content: DIN EN 14602, reporting limit: 1 mg/kg Cadmium (Cd) 100 mg/kg <1 mg/kg Lead (Pb) 90 mg/kg <1 mg/kg Determination of PAH: ZEK , ultrasound extraction ith Toluene, determination ith GC-MS (SIM), reporting limit: 0.2 mg/kg Benzo (a) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (e) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (a) anthracene 0.2 mg/kg <0.2 mg/kg Chrysene 0.2 mg/kg <0.2 mg/kg Benzo (b) fluoranthene 0.2 mg/kg <0.2 mg/kg Benzo (j) fluoranthene 0.2 mg/kg <0.2 mg/kg Benzo (k) fluoranthene 0.2 mg/kg <0.2 mg/kg Dibenzo (a,h) anthracene 0.2 mg/kg <0.2 mg/kg Naphthalene 0.2 mg/kg <0.2 mg/kg Acenaphtylene 0.2 mg/kg <0.2 mg/kg Acenaphtene 0.2 mg/kg <0.2 mg/kg Fluorene 0.2 mg/kg <0.2 mg/kg Phenanthrene 0.2 mg/kg <0.2 mg/kg Anthracene 0.2 mg/kg <0.2 mg/kg Fluoranthene 0.2 mg/kg <0.2 mg/kg Pyrene 0.2 mg/kg <0.2 mg/kg Indeno (1,2,3-cd) pyrene 0.2 mg/kg <0.2 mg/kg Benzo (g,h,i) perylene 0.2 mg/kg <0.2 mg/kg Sum of all PAH's 1 mg/kg not detected Phthalates: Phthalates acc. to REACH, reporting limit: % Diisobutylphthalate (DiBP) measurement Dibutylphthalate (DBP) measurement Benzylbutylphthalate (BBP) Di(2-ethylhexyl)phthalate (DEHP) measurement 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate Bis(2-methoxyethyl)phthalate (DMEP) Di-iso-pentylphthalate (DiPP) n-pentyl-iso-pentylphthalate (PiPP) 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear Dipenthylphthalate (DPP) Di-n-hexylphthalate (DnHP).bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

7 Continuted\Unseiter Page 7 of 10 Sample Description: 3) Adhesive foil transparent, 4) Foam dark grey, 5) Rubber band black Lab Reference No: (3 mixed components) Phthalates: Phthalates acc. to REACH, reporting limit: % 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear (DiHP) Di-hexylphthalate, branched and linear (DHxP) Tinorganic compounds: DIN EN ISO modified / DIN modified, reporting limit: mg/kg Dioctyltin (DOT) 1 mg/kg <0.025 mg/kg Monobutyltin (MBT) 1 mg/kg <0.025 mg/kg Dibutyltin (DBT) 1 mg/kg <0.025 mg/kg Tributyltin (TBT) 1 mg/kg <0.025 mg/kg Triphenyltin (TPhT) 1 mg/kg <0.025 mg/kg Sample Description: 6) Hook and Loop Fastener black Lab Reference No: Azo dyes/arylamines (other materials): EN :2012, LFGB 64 B & -4 ( BVL B & -4); reporting limit: 10 mg/kg Azo dyes/arylamines 20 mg/kg not detected Allergenic disperse dyes & carcinogenic dyestuffs: DIN 54231, 64 LFGB B , reporting limit: 15 mg/kg Disperse dyes & carcinogenic dyestuffs 50 mg/kg not detected Sample Description: Complete article Lab Reference No: Odour estimation: BVCPS inhouse method, pre odour test based on SNV Grade 1.5 No Specification All services provided by are subject to our current Terms and Conditions. The test result relates only to the tested item. Without the ritten consent of excerpts of this report shall not be reproduced. Tests not covered by the laboratory's testing spectrum may be subcontracted to an accredited laboratory. The accreditation relates to competences stated on the accreditation certificate. If nothing else has been agreed on samples are stored for 3 months. All tested parameters are listed in the appendix. The testing of mixed samples is carried out at the customer's explicit request and may imply a deviation from the testing standard. Please note the folloing: results for mixed samples that are belo the limit may exceed the limit if the samples contained in the mixed sample are tested individually. In these cases separate testing of the samples is recommended. Performance Date: Total Run Time: 1 Anett Rack Analytical Testing Specialist No results printed beyond this point in the report.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

8 Page 8 of 10 Analysis / Test: Azo dyes/arylamines (other materials) Detailed Method Descriptions EN :2012, LFGB 64 B & -4 (BVL B & -4), detection of the use of certain azo colorants in textiles accessible ith or ithout extraction, reduction by dithionit, detection of certain amines by GC-MS and/or LC-DAD-MS, reporting limit: 10 mg/kg Analysis / Test: Allergenic disperse dyes & carcinogenic dyestuffs DIN 54231, 64 LFGB B , ultrasound extraction ith Methanol, determination by LC-DAD-MS, reporting limit: 15 mg/kg Analysis / Test: Lead & Cadmium, total content DIN EN 14602, total metal content, microave digestion ith salpetric acid/hydrochloric acid, determination using ICP, reporting limit: 1 mg/kg Analysis / Test: List of grades: Odour estimation 1= odourless 2= faint smell 3= tolerable smell 4= irritating smell 5= intolerable smell Analysis / Test: Tinorganic compounds DIN EN ISO modified / DIN modified, ultrasound extraction ith Ethanol / Diethyldithiocarbamate, derivatisation ith Tetraethylborate, determination using GC-MS, reporting limit: mg/kg.bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

9 Page 9 of 10 Alkylphenols Octylphenols (OP) ( ) Nonylphenols (NP) ( ) Azo dyes/arylamines (other materials) 4,4'-Methylene-bis-(2-chloro-aniline) ( ) 4,4'-Diaminodiphenylmethane ( ) 4,4'-Oxydianiline ( ) 4-Chloroaniline ( ) 3,3'-Dimethoxybenzidine ( ) 3,3'-Dimethylbenzidine ( ) p-cresidine ( ) 2,4,5-Trimethylaniline ( ) 4,4'-Thiodianiline ( ) 2,4-Diaminoanisole ( ) Aniline ( ) 3,3'-Dimethyl-4,4'-diaminodiphenylmethane ( ) o-anisidine ( ) 2-Naphtylamine ( ) 3,3'-Dichlorobenzidine ( ) 4-Aminobiphenyl ( ) Benzidine ( ) o-toluidine ( ) 4-Chloro-o-toluidine ( ) 2,4-Toluenediamine ( ) o-aminoazotoluene ( ) 5-Nitro-o-toluidine ( ) 1,4-Phenylenediamine ( ) Allergenic disperse dyes & carcinogenic dyestuffs Disperse dyes - Disperse Yello 1 ( ) Disperse dyes - Disperse Blue 35 ( ) Disperse dyes - Disperse Blue 102 ( / ) Disperse dyes - Disperse Blue 106 ( ) Disperse dyes - Disperse Yello 39 ( ) Disperse dyes - Orange 37 / 76 / 59 ( ) Carcinogenic dyestuffs - Direct Black 38 ( ) Disperse dyes - Disperse Bron 1 ( ) Disperse dyes - Disperse Blue 1 ( ) Disperse dyes - Disperse Blue 3 ( ) Disperse dyes - Disperse Orange 1 ( ) Carcinogenic dyestuffs - Direct Blue 6 ( ) Disperse dyes - Disperse Yello 3 ( ) Disperse dyes - Disperse Red 11 ( ) Disperse dyes - Disperse Red 1 ( ) Disperse dyes - Disperse Red 17 ( ) Disperse dyes - Disperse Blue 7 ( ) Parameters & CAS No. Carcinogenic dyestuffs - Acid Red 26 ( ) Disperse dyes - Disperse Blue 26 ( ) Disperse dyes - Disperse Yello 49 ( ) Carcinogenic dyestuffs - Basic Red 9 ( ) Carcinogenic dyestuffs - Direct Red 28 ( ) Disperse dyes - Disperse Blue 124 ( ) Other banned dyestuff - Disperse Yello 23 ( ) Carcinogenic dyestuffs - Basic Violet 14 ( ) Disperse dyes - Disperse Yello 9 ( ) Disperse dyes - Disperse Orange 3 ( ) Carcinogenic dyestuffs - Disperse Orange 11 ( ) Other banned dyestuff - Disperse Orange 149 ( ) Formaldehyde, free in paper and cardboard Formaldehyde ( ) Lead & Cadmium, total content Lead (Pb) ( ) Cadmium (Cd) ( ) Determination of PAH Anthracene ( ) Pyrene ( ) Benzo (g,h,i) perylene ( ) Benzo (e) pyrene ( ) Indeno (1,2,3-cd) pyrene ( ) Benzo (j) fluoranthene ( ) Benzo (b) fluoranthene ( ) Fluoranthene ( ) Benzo (k) fluoranthene ( ) Acenaphtylene ( ) Chrysene ( ) Benzo (a) pyrene ( ) Dibenzo (a,h) anthracene ( ) Benzo (a) anthracene ( ) Acenaphtene ( ) Phenanthrene ( ) Fluorene ( ) Naphthalene ( ) Phthalates Di(2-ethylhexyl)phthalate (DEHP) measurement ( ) Bis(2-methoxyethyl)phthalate (DMEP) ( ) Dipenthylphthalate (DPP) ( ) Di-iso-pentylphthalate (DiPP) ( ) 1,2-Benzenedicarboxylic acid, di-c7-11-branched and linear alkyl esters (DHNUP) -> determinated as Diundecylphthalate ( , ) 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear (DiHP) ( ).bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin cps-scherin@de.bureauveritas.com Businesspark A96, 86842

10 Page 10 of 10 1,2-Benzenedicarboxylic acid, di-c6-8-branched alkyl esters, C7-rich (DIHP) ( ) n-pentyl-iso-pentylphthalate (PiPP) ( ) Diisobutylphthalate (DiBP) measurement ( ) Dibutylphthalate (DBP) measurement ( ) Di-n-hexylphthalate (DnHP) ( ) 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear ( ) Benzylbutylphthalate (BBP) ( ) Tinorganic compounds Dioctyltin (DOT) (-nonexistent-) Dibutyltin (DBT) ( ) Tributyltin (TBT) ( ) Triphenyltin (TPhT) ( ) Monobutyltin (MBT) ( ).bureauveritas.de/cps Reg.No. Scherin HRB 3564 Scherin Wilhelm-Hennemann-Str. 8, Scherin Businesspark A96, 86842