Hazardous Waste Initial Training
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1 Hazardous Waste Initial Training
2 Hazardous Waste Disposal Types of Waste Chemical Waste Radioactive Waste Biohazardous Waste/Medical Waste Pathological Waste Refer to the Waste Disposal Guide
3 Typical Wastes in Chemistry Spent solvents Metal bearing aqueous materials Acidic materials Unused or expired chemicals Silica gels w/solvent contaminates Used oil vacuum pumps Sharps needles/syringes
4 THE Absolute Three Things you need to stay out of trouble: Words Hazardous Waste Completed Waste Tag (No Abbreviations) Keep Container Closed (Except When Actively Adding) Training (Initial and Annual Refresher)
5 Hazardous Waste Containers Liquids EHS provides 5-gallon carboys that DOT-approved No lab glassware, beakers, flasks Small Containers (< 1 gallon) Make your own - Deface previous labeling EHS will bring packing material (boxes, absorbent) and package the wastes for transportation.
6 Examples of HW Containers
7 Attach to container!! Fill out immed. Fill out when added Fill out when full/90 days
8 Options for waste accumulation may include...
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10 Examples Of What Not To Do!
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15 Not this
16 This is closed
17 So What is Hazardous Chemical Waste? Liquid, Solid or Gas that is a: Listed Discarded Chemical Commercial Product (DCCP) Listed Hazardous Waste (spent a from process/source) Characteristic Hazardous Waste
18 Discarded Chemical Commercial Product (DCCP)
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20 Process waste from specific source - Solvent rinses - Manufacturing / R & D processes
21 Listed Solvents The following substances used as a solvent/degreaser or mixtures or blends containing 10% of any of these before use: Acetone Methanol Benzene Methyl Ethyl Ketone (MEK) n-butanol Methyl Isobutyl Ketone (MIBK) Carbon Disulfide 2-Nitropropane Carbon Tetrachloride Pyridine Chlorinated fluorocarbons Tetrachloroethylene (perchlor) Chlorobenzene Toluene Cresols 1,1,1-Trichloroethane Cresylic acid 1,1,2-Trichloro-1,2,2-trifluoroethane Cyclohexanone 1,1,2-Trichloroethane 2-Ethoxyethanol Trichloroethylene (trichlor) Ethyl acetate Xylene Isobutanol Methylene chloride
22 Characteristic Hazardous Waste - Corrosive (ph < 2 or ph > 12.5) - Acids/bases - Ignitable (Flash Point < 140 F) - Solvents, Flammable liquids - Reactive with air or water (sodium/potassium/lithium metal; organometal compounds), cyanide or sulfide bearing - Toxic (See Table)
23 Toxic -Heavy Metals (ppm or mg/kg) Arsenic 5.0 Mercury 0.2 Barium Silver 5.0 Cadmium 1.0 Selenium 1.0 Chromium 5.0 Lead 5.0
24 Non-Metal Toxic Wastes: (See Waste Disposal Guide page 61) Benzene 0.5 ppm Carbon Tetrachloride 0.5 ppm Chloroform 6.0 ppm 1,2-Dichloroethane 0.5 ppm Methyl Ethyl Ketone ppm Nitrobenzene 2.0 ppm Pyridine 5.0 ppm Tetrachloroethylene 0.7 ppm Trichloroethylene 0.5 ppm
25 More Non-Metal Toxic Wastes: (See Waste Disposal Guide page 61) Chlordane 0.03 ppm Chlorobenzene ppm Cresols ppm 1,4-dichlorobenzene 7.5 ppm 2,4-dinitrotoluene 0.13 ppm Heptachlor ppm Vinyl chloride 0.20 ppm
26 Non-Hazardous Waste... but still regulated... Unlisted, yet still contain toxic metals (thallium, osmium, nickel, vanadium beryllium, antimony, cobalt) Waste Oils Anything liquid being collected for disposal Fluorescent tubes
27 Segregating Liquid Waste Flammables/Organic Liquids Corrosives (must be sub-segregated) Heavy metal solutions (EXCEPT Mercury) Mercury Containing Wastes
28 Metal Cans/Buckets DO NOT place in dumpser 1. Leave lid on when empty do not air dry! 2. Leave labeling as is 3. Place in hallway for pickup by EHS
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31 Used Oil These words must be on any container used to store waste oil. And there s one of these all ready for your oil at the loading dock!!
32 Sharps Management Sharps include all: Needles Syringes w/o needles Scalpels Sharps also include any item that is sharp enough to puncture the skin and is contaminated with potentially infectious material.
33 Sharps Containers Don t overfill the sharps container A sharps container must be permanently closed and disposed of through ORCBS when: It is ¾ full, or Within 90 days of first use Don t forget the SHARPS label!
34 Non-Sharps Biohazardous Waste Waste items generated through lab process that are contaminated with potentially infectious material, human or animal body fluids (other than urine or feces) or r-dna Storage: Biohazard bag in secondary container Lid required if possibility of liquid release
35 More on Solid, Non-Sharps Biohazardous Waste Do not commingle chemical with biological waste (i.e. phenol chloroform, ethidium bromide) Decontaminate in an autoclave approved by the EHS for that purpose following posted parameters. (Don t forget the black bag!)
36 Waste Minimization (required by EPA) Waste minimization can be achieved by: Substituting non-hazardous or less toxic material whenever possible. Purchasing only the amount of chemical that is needed.
37 Final Comments The EHS Waste is here to help you with the proper disposal of waste. Issues arise when: Problems and waste are hidden from EHS (Unlike cheese & wine, chemicals do not get better with age) Chemical contents are intentionally left off the waste tag
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40 Please Remember Hazardous Waste Refresher Class On-line Every year
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