/ : 2015/830 (REACH
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1 Date of issue: Revision date: Supersedes: Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Soleto Product code : BCP222H Type of product : SC (Suspension Concentrate) Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Professional use : Herbicide Uses advised against 1.3. Details of the supplier of the safety data sheet Belchim Crop Protection NV/SA Technologielaan Londerzeel - Belgium T +32 (0) F +32 (0) info@belchim.com Emergency telephone number Emergency number : +32(0) H/7 days SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Carcinogenicity, Category 2 Specific target organ toxicity Repeated exposure, Category 2 Hazardous to the aquatic environment Acute Hazard, Category 1 H351 H373 H400 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) GHS08 : Warning GHS09 Hazard statements (CLP) Precautionary statements (CLP) : H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. H410 - Very toxic to aquatic life with long lasting effects. : P273 - Avoid release to the environment. P280 - Wear Protective gloves, Protective clothing. P301+P312 - IF SWALLOWED: Call a doctor, a POISON CENTER if you feel unwell. P308+P313 - IF exposed or concerned: Get medical advice/attention. P391 - Collect spillage. P501 - Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous EN (English) 1/7
2 EUH-statements waste. : EUH208 - Contains. May produce an allergic reaction. EUH401 - To avoid risks to human health and the environment, comply with the instructions for use Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] (CAS-No.) (EC-No.) <= 50 Acute Tox. 4 (Oral), H302 Skin Sens. 1, H317 Carc. 2, H351 STOT RE 2, H373 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Sulfonated aromatic polymer, sodium salt <= 5 Eye Irrit. 2, H319 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : IF exposed or concerned: Get medical advice/attention. : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects : Methaemoglobin formation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Water spray. Dry powder. Foam. Carbon dioxide. : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Do not breathe dust/fume/gas/mist/vapours/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment EN (English) 2/7
3 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up Other information : Collect spillage. : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapours/spray. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Stable at room temperature. Storage temperature : 30 C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Ensure good ventilation of the work station. : Gloves. Protective clothing. : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : White to off-white. Odour : Faint aromatic. Odour threshold ph : 7,9 (21 C) Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 100 C Auto-ignition temperature : > 800 C EN (English) 3/7
4 Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Not flammable : 1,219 g/cm³ (20 C) : Dispersible. : mpa.s (100/s - 10/s) : None. : None Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Soleto LD50 oral rat LD50 oral LD50 oral rat LD50 oral LD50 dermal rat LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity NOAEL, oral, rat Reproductive toxicity STOT-single exposure STOT-repeated exposure > 2000 mg/kg > 2000 ml/kg mg/kg mg/kg > 3000 mg/kg > 1,6 mg/l/4h ph: 7,9 (21 C) ph: 7,9 (21 C) : Suspected of causing cancer. 2.6 mg/kg bw/day (48 months) : May cause damage to organs through prolonged or repeated exposure EN (English) 4/7
5 NOAEL, short term, rat NOAEL, short term, mouse NOAEL, short term, oral, Dog NOAEL, short term, Dermal, rat Aspiration hazard < 2.7 mg/kg bw/day (28 days) < 13.8 mg/kg bw/day (28 days) 1.59 mg/kg bw/day (1 years) 40 mg/kg bw/day (28 days) SECTION 12: Ecological information Toxicity Soleto LC50 fish mg/l EC50 Daphnia mg/l ErC50 (algae) 1,39 mg/l (72 h) ErC50 (other aquatic plants) 0,73 mg/l (7 d) LC50 fish 1 43 mg/l EC50 Daphnia 1 44,1 mg/l EC50 72h algae (1) 0,63 mg/l NOEC chronic fish 0,5 mg/l (28 days) NOEC chronic crustacea > 10 mg/l (21 days) Persistence and degradability Persistence and degradability Bioaccumulative potential Not readily biodegradable. Log Pow 2,48 (20 C; ph 7.3) Bioaccumulative potential No bioaccumulation Mobility in soil Ecology - soil Results of PBT and vpvb assessment Component ( ) Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste treatment methods SECTION 14: Transport information Biodegradability in soil: no data available. This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII : Waste instruction. : Dispose of contents/container in accordance with licensed collector s sorting instructions. In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID applied : 375 applied : 969 applied : A197 applied : UN number UN proper shipping name N.O.S. () N.O.S. Transport document description Environmentally hazardous substance, liquid, n.o.s. Environmentally hazardous substance, N.O.S. applied : 375 N.O.S EN (English) 5/7
6 ADR IMDG IATA ADN RID N.O.S. (), 9, III, (-) N.O.S., 9, III, MARINE POLLUTANT liquid, n.o.s., 9, III N.O.S., 9, III N.O.S., 9, III Transport hazard class(es) Packing group III III III III III Environmental hazards Marine pollutant : Yes Special precautions for user - Overland transport Special provisions (ADR) : 274, 335, 375, 601 Orange plates : No supplementary information available - Transport by sea No data available - Air transport No data available - Inland waterway transport Classification code (ADN) : M6 Number of blue cones/lights (ADN) : 0 - Rail transport No data available Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations National regulation Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Transport information Special provisions (ADR) Tunnel restriction code (ADR) EN (English) 6/7
7 Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H302 H317 H319 H351 H373 H400 H410 EUH208 EUH401 Harmful if swallowed. May cause an allergic skin reaction. Causes serious eye irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Contains ( ). May produce an allergic reaction. To avoid risks to human health and the environment, comply with the instructions for use. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Carc. 2 H351 Calculation method STOT RE 2 H373 Calculation method Aquatic Acute 1 H400 On basis of test data Aquatic Chronic 1 H410 Expert judgment SDS EU BCP (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 7/7
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