: Bonide Dragoon Dust with Copper

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product code : 4474 : Bonide Dragoon Dust with Copper 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Bonide Products, Inc Sutliff Road Oriskany, NY T (315) Emergency telephone number : Insecticide, Fungicide Emergency number : CHEMTREC - 1 (800) and/or 1 (703) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Carc. 2 H Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 : Warning : H351 - Suspected of causing cancer. : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves/protective clothing/eye protection/face protection P308+P313 - IF exposed or concerned: Get medical advice/attention P405 - Store locked up 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture Name Product identifier % Classification (GHS-US) Basic Copper Sulfate (CAS No) Not classified Carbaryl (CAS No) Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Carc. 2, H351 Aquatic Acute 1, H400 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Suspected of causing cancer. Revision date: 02/18/2016 EN (English US) Page 1

2 First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Assure fresh air breathing. Allow the person to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Do not handle until all safety precautions have been read and understood Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Keep container closed when not in use. Protect from moisture. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³ Revision date: 02/18/2016 EN (English US) 2/5

3 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Blue-green dust. Color : Bluish green. Odor : Musty. Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Density : 44 to 48 lb./cu.ft. Solubility : Insoluble in water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products None known. Revision date: 02/18/2016 EN (English US) 3/5

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit ATE (oral) ATE (gases) ATE (vapors) ATE (dust, mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms 230 mg/kg (Rat) 4000 mg/kg (Rat) 2000 mg/kg (Rabbit) mg/kg body weight ppmv/4h mg/l/4h mg/l/4h : Suspected of causing cancer. 3 - Not Classifiable : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 TLM fish 2 Threshold limit algae 1 Threshold limit algae 2 Basic Copper Sulfate ( ) EC50 Daphnia mg/l (96 h; Cyprinus carpio) mg/l (48 h; Daphnia pulex; Larvae) mg/l (48 h; Simocephalus serrulatis) mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) 2.3 ppm (96 h; Mytilus edulis) 2.5 ppm (96 h; Oncorhynchus kisutch; Young) 5.5 ppm (96 h; Lepomis macrochirus) 0.03 mg/l (Microcystis aeruginosa) 1.4 mg/l (Scenedesmus quadricauda) 320 μg/l Persistence and degradability Bonide Dragoon Dust with Copper Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Readily biodegradable in water. 0 g O²/g substance Bioaccumulative potential Bonide Dragoon Dust with Copper Bioaccumulative potential BCF fish (Ictalurus punctatus) Revision date: 02/18/2016 EN (English US) 4/5

5 BCF other aquatic organisms (Algae) BCF other aquatic organisms (Crustacea) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Ecology - soil Other adverse effects Toxic to bees. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information SECTION 15: Regulatory information : Dispose in a safe manner in accordance with local/national regulations. : No supplementary information available. This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Harmful if swallowed. Causes moderate eye irritation. Avoid contact with eyes or clothing. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Wear: Long-sleeved shirt and long pants, socks and shoes US Federal regulations International regulations US State regulations SECTION 16: : None. Full text of H-phrases: see section 16: Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Carc. 2 Carcinogenicity Category H301 Toxic if swallowed H312 Harmful in contact with skin H332 Harmful if inhaled H351 Suspected of causing cancer H400 Very toxic to aquatic life SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. Revision date: 02/18/2016 EN (English US) 5/5