APPLICATION FOR OBTAINING TERMS OF REFERENCE

Transcription

1 APPLICATION FOR OBTAINING TERMS OF REFERENCE For EXPANSION IN PESTICIDE MANUFACTURING UNIT [Schedule 5 (b) Category A as per EIA Notification 2006] (All units Producing Technical Grade Pesticides under Cat-A) At At SP 9C, SP-9B and H1-39(O), RIICO Industrial Area, Khushkhera, Taluka- Tijara, Pin , District Alwar, State- Rajasthan. Land/Plot area (Existing & Proposed): m 2 (3.05 ha) Production Capacity: (900 TPA to 7140 TPA) Applicant HPM CHEMICALS AND FERTILIZERS LIMITED (Formaly knows as Hindustan Pulverizing Mills) Plot No. SP 9C, SP-9B & H1-39(O), RIICO industrial area Khushkhera Tahasil- Tijara, District -Alwar, State Rajasthan. gr.aggarwal@hpmindia.com Contact No: Consultant ECO CHEM SALES & SERVICES Office floor, Ashoka Pavilion A, New Civil Road, Surat, (QCI/NABET Accredited No. NABET/EIA/1720/ RA 051) eco@ecoshripad.com Contact No: Dec 2017 Doc. No: 2017_ECSS_EIAI2_

2 1.0 EXECUTIVE SUMMARY HPM has ruled and led the agro-chemical industry in India and abroad. With the motto of Yielding Prosperity, the company has stood steadfast by its mission of bringing prosperity in the lives of all associated with it. As a leading pesticide company both nationwide and globally, they are the proud fore-runners and contributors to the Green Revolution drive. The shelf life of their products holds longer than any other. Our supreme and consummate infrastructure holds the premium production and warehousing facilities. HPM Chemicals and Fertilizer Ltd. Formerly known (HPM) is ISO-9001 ISO & OHSAS Certified Company. The Company had obtained Environmental Clearance (EC) for their existing unit on the name of HPM Chemicals and Fertilizers Ltd. formerly known. The Unit holds Consolidated Consent and Authorization consent to operate. The Company is now planning to expand their existing production capacity and addition of new products within existing premises. Expansion project at a glance is mentioned in table 1.1. Table 1.1: Project Summary S. No. Description Proposed Project Details 1. Name of project Environmental Clearance for Expansion in Pesticide Manufacturing Plant from 900 TPA to 7140 TPA by HPM Chemicals and Fertilizers Ltd. formerly known as Hindustan Pulverising Mills. 2. Project Site At SP-9C, SP-9B & H1-39(O), RIICO Industrial Area, Khushkhera, Taluka- Tijara, Pin , District Alwar, State- Rajasthan. 3. Project Category Schedule 5(b) Category A of EIA notification. 4. Total Project Rs Crores. cost for expansion Total Capital Rs. 2.5 Crores. Cost of EMP for expansion 5. Products HPM Chemicals and Fertilizers Ltd. formerly known proposes to manufacture: S. No. Group Quantity (TPA) Existing Proposed Total 1. Insecticides and Bio-pesticides Fungicides Bactericide Total Herbicides Total Intermediates Total By-Product CAS Exiting Proposed Total Status / # By Products Number TPA End use SODIUM SULPHITE- 20 % HYDROCHLORIC ACID - 30 % AMMONIUM ACETATE New By-Product SOLD SOLD/ CAPTIVE SOLD 4. SODIUM SOLD Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

3 S. Description Proposed Project Details No. SULPHITE- 20 % 83-7 Total Raw Materials Refer table Resource Requirement (i) Land Total plot area 30, m 2 (3.05 ha) (ii) Water Source: RIICO Water supply Construction phase: Domestic 10 KLD Construction activities and curing 10 KLD Operation phase: Industrial KLD Domestic 35 KLD Total fresh water requirement KLD (iii) Electricity 1850 kva Power requirement will be met through Jaipur Vidyut Vitran Nigam Limited (JVVNL). (iv) Backup power D.G. Set Existing (1 No.): 62 kva and Total Proposed: 910 kva (v) Fuel Coal TPA/ WOOD TPA/ Rice Husk TPA LDO 200 kg/hr for existing incinerator HSD 500 L/h for Proposed incinerator HSD 220 L/h for D.G. Sets (vi) Man power Construction Phase: Nos. Operation Phase: Existing 110 Nos. and Proposed 30 Nos. Total 140 Nos. (vii) Utility Existing Steam Boiler 2 No bar One Stand By Proposed Steam boiler - 1 No bar Existing Incinerator 1 No. 25 kg/h Proposed Incinerator 1 No. 200 kg/h 9. Source of Pollution (i) Wastewater Generation (ii) Air Emission From Incinerator HCL : < 50 mg/nm 3 (iii) Solid/Hazardous waste Generation Domestic Sewage-Existing 4.00 KLD and after expansion KLD Trade Effluent- Existing16 KLD and after expansion KLD SO 2 : < 200 mg/nm 3 CO : < 100 mg/nm 3 TOC : < 20 mg/nm 3 PM : < 50 mg/nm 3 From Boiler PM : < 1200 mg/nm 3 From D.G. Set SO 2 : < 200 mg/nm 3 CO : < 100 mg/nm 3 PM : < 50 mg/nm 3 ETP waste, Used Oil, discarded containers, Fly ash, Electrical waste. 10. Treatment Facility (i) Wastewater Pre -Treated in Effluent Treatment Plant (125 KLD capacity) and out let of treated effluent goes to multiple effect evaporation condensate water from MEE recycled to process where as the salt from MEE will send to TSDF/Land Filing, Udaipur Rajasthan (ii) Air Water scrubber followed by Caustic scrubber had been provided to control process emission, Ventury scrubber to control emission from incinerators, Cyclone Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

4 S. Description Proposed Project Details No. (iii) Solid/Hazardous. Waste separator has been provided to boilers for controlling particulate matter. Collection, storage and disposal of solid/hazardous waste will be carried out as per Hazardous and Other Wastes [Management and Transboundary Movement) Amendment Rules, The solid, liquid and gaseous wastes from the proposed plant will be disposed-off in an environmentally acceptable manner. Process effluents will be properly pre -treated in adequate effluent treatment plant and treated wastewater will be feed to MEE and condensate if MEE water recycled back to process for reuse. The proper precaution will be taken and adequate plantation will be done to keep noise level within prescribed limit. Adequate measure has been contemplated to ensure least pollution from the proposed project. 2.0 INTRODUCTION OF PROPOSED PROJECT 2.1 Project Proponent More than four decades since its inception by a leading visionary Shri Srikisan Dass Aggarwal HPM has ruled and led the agro-chemical industry in India and abroad. With the motto of Yielding Prosperity and is ranked amongst one of the Greatest Brands in the Pesticide Industry the company has stood steadfast by its mission of bringing prosperity in the lives of all associated with it. Right from their adept team of meticulous farmers to their dynamic board of management directors, the company has ensured to touch and make a colossal impact in the lives of all. Aiming towards their mission of ensuring self-reliance in productivity, they have worked successfully to incorporate the best innovative practices in their processes. As a leading pesticide company both nationwide and globally, they are the proud fore-runners and contributors to the Green Revolution drive. Their adroit work force constantly strives to innovate and create a wide range of crop protection products and plant nutrients. Using the latest technological advancements they produce the finest fertilizers and farming seeds. The shelf life of their products holds longer than any other. Their recent extensions include the in house production of the raw material which withholds the premier use of requisite materials in the final production. Quality Assurance is an integral part of our practices at HPM. Frequent quality checks bring out the best and secure products from the production outlets to the fields. Our supreme and consummate infrastructure holds the premium production and warehousing facilities. HPM Chemicals and Fertilizer Ltd. is ISO ISO & OHSAS CERTIFIED COMPANY. The existing unit at Khushkhera industrial estate in Alwar district Rajasthan is having various infrastructure facilities, which includes Effluent Treatment Plant (ETP), Evaporation system for High TDS effluent, Air pollution control equipment, etc. Board of Directors Mr. Ashok Aggarwal, the chairman of HPM is a dynamic and an adept entrepreneur. Mr. Ashok graduated in commerce and stepped into his family business in As a distinguished and an acclaimed agro-manufacturer, his vision and conviction has steered and guided the philosophy and mission at HPM. Ms. Tapasya Goel is a vibrant and a dynamic face of HPM. She is a passionate and an experienced entrepreneur who believes in ardent desire to make a meaningful difference to Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

5 HPM Ltd. and scale it to new heights. Driven by this passion, she brings in a wide array of experience from diverse sectors. From a knack in interiors to jewelry designing, she has managed to flair extensively in whatever capacity she has been entrusted with. Mr. G.R. Aggarwal has played a pivotal role in the company s success. His administrative acumen and managerial skills have made worthy contributions to the manufacturing practices at HPM. His journey at HPM started in 2005 and since then he has set high standards for excellence and diligence in all his endeavors. He has a vast experience and expertise in leading a large team of people along with management capability and ability to solve problems quickly and efficiently. The Company had obtained Environmental Clearance (EC) for their existing unit vide No.: J /459/2009-IA-II (I) dated 4 February 2010 on the name of Hindustan Pulverising Mills, same attached as Annexure 1. The Unit holds consent to operate having file no: F(PLG)/Alwar(Tijara)/39(1)/ / dated 10/04/2018 which is valid up to 31/03/ Nature of the Project Expansion project to be developed at SP-9C, SP-9B & H1-39(O), RIICO Industrial Area, Khushkhera, Taluka - Tijara, District Alwar of Rajasthan State. Expansion project is fall under Schedule 5(b) Category A of EIA Notification 2006 and amendments time to time. 2.3 Need of the Project The company is already engaged in the business of manufacturing of Pesticide, Pesticide Intermediate, Pesticide Formulation Product, etc. The proposed expansion project provides a potential growth opportunity for the already running business of the company. The agro Chemical sector in the past ten years has seen a drastic boom in local as well as international market. Keeping the globalization trend in mind, HPM Chemicals and fertilizers Ltd. formally known has identified the demand of pesticide intermediates, fungicide, and herbicide and insecticide products. There has been a steady growth in the production of technical grade pesticides in India, which is evident from its demand increasing from 5,000 MT in 1958 to 4,02,240 MT in Justification of the proposed project is mentioned as under: It provides a potential growth opportunity, Raw materials are easily available domestically, It will increase the overall export and increase in foreign revenue, Proposed products have very demand and good sale potential domestic market. 2.4 Demand Supply Gap and Import vs. Indigenous Production The Indian crop protection industry is estimated to be USD 4.25 billion in FY14 and is expected to grow at a CAGR of 12% to reach USD 7.50 billion by FY19. Exports currently constitute almost 50% of Indian crop protection industry and are expected to grow at a CAGR of 16% to reach USD 4.2 billion by FY19, resulting in 60% share in Indian crop protection industry. Domestic market on the other hand would grow at 8% CAGR, as it is predominantly monsoon dependent, to reach USD 3.3 billion by FY19. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

6 The crop protection chemicals can be broadly classified into five types: Insecticides: Insecticides provide protection to the crops from the insects by either killing them or by preventing their attack. They help in controlling the pest population below a desired threshold level. Fungicides: Fungicides protect the crops from the attack of fungi and can be of two types protectants and eradicates. Protectants prevent or inhibit fungal growth and eradicates kill the pests on application. Herbicides: Herbicides also called as weedicides are used to kill undesirable plants. They can be of two types - selective and non-selective. Bio-pesticides: Bio-pesticides are new age crop protection products manufactured from natural substances like plants, animals, bacteria and certain minerals. They are ecofriendly, easy to use; require lower dosage amounts for same performance as compared to chemical based pesticides. Others-(Fumigants, Rodenticides, Plant growth regulators etc.): Fumigants and rodenticides are the chemicals which protect the crops from pest attacks during crop storage. Plant growth regulators help in controlling or modifying the plant growth process and are usually used in cotton, rice and fruits. Product Source Industry Analysis Indian Crop Protection Market Category % of Total Insecticides 60% Fungicides 18% Herbicides 16% Bio Pesticides 3% Others 3% Cypermethrine is the largest Synthetic Pyrethroid Insecticide in the world and is a global blockbuster product which has a market in almost every country in the world. It is also a significant product in the Indian market. The main competitors of this product are UPL and Gharda. The company already has a significant Presence in the Insecticide segment and the customers for Cypermethrin would be the same as the existing customers. Major crop protection The global demand for Cypermethrin would be tons, Deltamethrin would be 3500 tons, Lambda Cyhalothrin would be 5000 tons, Permethrin would be 5000 tons and Alfamethrin market demand is 4000 tons per year. The company would have a cost advantage as it would be manufacturing some of existing facility utilization. The market for Cypermethrin is growing at 6-8% annually, while it is estimated that the market for Deltamethrin and Lambda Cyhalothrin are growing at 12-15% annually. Markets for Alfamethrin and Permethrin are also growing at a healthy pace of 8-9%. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

7 2.5 Employment Generation There are possibilities to generate employment during the construction as well as operation phase of the proposed project. Local skilled and semi-skilled workers will be hired during construction phase, thus no need to provide housing facility to workers Nos. of people will get direct employment during construction phase. Technical staff for plant operation, general staff for administrative work and other ancillary services i.e. Security, O&M contractor and maintenance services will have required during operation phase. 110 Nos. of persons are employed in existing plant 140 Nos. technical person will get direct and other contractor worker will get indirect employment after expansion during operation phase. 3.0 PROJECT DESCRIPTION 3.1 Type of Project Expansion in Pesticide Manufacturing Plant from 900 TPA to 7140 TPA by HPM Chemicals & Fertilizers Ltd. formally known in RIICO Industrial Area, Khushkhera. All the industrial infrastructure facility is being available at RIICO Industrial Area to support proposed development. 3.2 Location of Project HPM Chemicals and Fertilizers Ltd. formerly known decided to set an industrial plant at SP-9C, SP-9B & H1-39(O), RIICO Industrial Area, Khushkhera, Taluka Tijara, District Alwar, State Rajasthan. Expansion is in its existing unit area. Location of plant site and Key map and Google image of proposed project site is depicted as figure 1.1 & 1.2 respectively. Proposed project coordinate is as under: Latitude : 28 7'31.69"N Longitude : 76 47'23.16"E Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

8 Figure 1.1: Study Area Map Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

9 Figure 1.2: Location map Figure 1.3: Google Image of Project site Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

10 Corner co-ordinate of the project site is as follows: Corner Latitude Longitude A '31.61"N '18.71"E B '34.11"N '19.46"E C '31.75"N '28.17"E D '29.31"N '27.42"E E '31.02"N '27.97"E F '30.80"N '29.21"E G '31.45"N '29.36"E H '30.43"N '22.86"E I '27.99"N '21.93"E J '29.22"N '17.75"E Layout plan showing complete manufacturing facility, utility area, greenbelt area, treatment facility, admin building, parking, entry and exit gate etc. is also attached as Annexure 2 with TOR application. Proposed project is located in RIICO industrial area. National park, Biosphere reserves, Wild life sanctuary, Archaeological place, Eco sensitive area etc. are not located within the 10 Km radius of the expansion project except protected forest. 3.3 Alternative Site Alternative Site study is not applicable as Expansion of pesticide and pesticide intermediate is in existing unit of HPM Chemicals and Fertilizers Ltd. formerly known as Hindustan Pulverising Mills located at RIICO industrial area, Khushkhera which has all required infrastructure for industrial development as well as it full fills all the required factors. 3.4 Size of Operation Expansion in Pesticide Manufacturing Plant is from 900 TPA to 7140 TPA. quantities are incorporated in section 3.5 of prefeasibility report. Product wise 3.5 Products and By-Products HPM Chemicals and Fertilizers Ltd formerly known had noted that there are good scopes in Pesticide and its intermediates sector and there will be demand for these sectors perennially. List of proposed products to be manufactured is mentioned in table 1.2 and 1.3 details of byproducts is and to be generated is mentioned in table 1.4. Table 1.2 Group wise Products S. No. Group Quantity (TPA) Existing Proposed Total 1. Insecticides and Bio-pesticides Total Fungicides Bactericide Herbicides Intermediates Total Production Capacity (TPA) Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

11 Table 1.3: Existing and Proposed Products with CAS number # Product CAS No. Existing (TPA) Proposed (TPA) Total quantity (TPA) Either/ Or Individual INSECTICIDE 1. ACETAMAPRID TECH IMIDACLOPRID THIOCLOPRID EITHER/ OR 4. THIAMETHOXAM NOVALURON(INSECTICIDE PGR) INDIVIDUAL 6. LAMDA CYHLOTHRIN BIFENTHRIN EITHER/OR 8. CHLORPYRIPHOS ACEPHATE ETHER/OR 10. PROFENOPHOS FIPRONIL BUPROFEZIN EITHER/OR CARTAP HYDROCHLORIDE 14. AZOXYSTROBIN BIO PESTICIDE 15. ABAMACTIN EMAMECTIN BENZOATE ETHER/OR , 17. SPINOSIDE BACTERIOCIDE 18. VALIDAMYCINE FUNGICIDE 19. HEXACONAZOLE TRICYCLAZOLE PROPICONAZOLE TEBUCONAZOLE EITHER/OR 23. DIFENCONAZOLE IPCONAZOLE PACLOBUTRAZOLE THIOPHENATE METHYL METALAXYL EITHER/OR HERBICIDE 28. IMAZETHAPYR INDIVIDUAL 29. METSULFURON METHYL SULFOSULFURON CHLORIMURON-ETHYL ; ETHER/OR 32. PYRAZOSULFURON BENSULFURON -METHYL CHLODINOFOB-PROPARGYL BUTACHLOR PRETILACHLOR ETHER/OR 37. GLYPHOSATE OXYFLOROFEN ATRAZINE ) EITHER/OR 40. METRIBUZIN Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

12 # Product CAS No. ADDITION OF NEW PRODUCTS Existing (TPA) Proposed (TPA) Total quantity (TPA) Either/ Or Individual HERBICIDE 41. DIFENTHIURON INDIVIDUAL 42. PENDIMETHELIN INDIVIDUAL INSECTICIDE 43. CYPERMETHRIN EITHER/OR 44. ALPHA CYPER METHRIN PERMETHRIN DELTAMETHRIN INDIVIDUAL INTERMEDIATE 47. CYPERMETHRIC ACID CHLORIDE (CMAC) INDIVIDUAL 48. SAFENER CLOQUINTO SET MEXYL INDIVIDUAL FUNGICIDE 49. MICLOBUTANIL INDIVIDUAL TOTAL Details of By-Products: # By Products Table 1.4 List of By-Products CAS Number Exiting Proposed Total Status / End use 1. SODIUM SULPHITE - 20 % SOLD 2. HYDROCHLORIC ACID - 30 % SOLD/CAPTIVE 3. AMMONIUM ACETATE 98% SOLD New by-product 4. SODIUM SULPHITE - 20 % SOLD TPA Total Manufacturing Process Brief process of all products manufacturing along with the chemical reaction, process flow diagram and material balance is detailed in Annexure Raw Materials Raw materials to be required for proposed project has been estimated based on operation of similar type of plant as well as proposed plant design data. Detail of raw material consumption for Existing and expansion plant is summarized in table 1.5. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

13 Table 1.5: List of Raw Materials # Name of Raw Material CAS No. Existing Raw Material Requirement (TPA) Proposed Raw Material Requirement (TPA) Total Raw Material Requiremen t After Expansion (TPA) 1. ACETAMAPRID TECH i. MMA (MONO METHYL AMINE - 25 % SOL. IN METHANOL ii. Tetrabutylammonium bromide (TBAB) iii. CCMT (2-Chloro-5-chloro methyl thiazole iv. MeOH v. NaOH Flakes vi. 3-Methyl-4-nitroiminoperhydro-1,3,5-oxadiazine vii. HCl (30%) IMIDACLOPRID i. 2-Chloro-5-chloromethylpyridine (CCMP) ii. 2 Nitroimino Imidazolidine (NII) iii. NaOH iv. N,N-Dimethylformamide (DMF) v. HCL 30 % THIOCLOPRID i. N - (2-Chloro-5-pyridylmethyl)-2-cyanoiminothiazolidine ii. 2-Chloro-5-Chloro methyl pyridine iii. N,N-Dimethylformamide (DMF) iv. NaOH v. N-HEXANE THIOMETHOXAM i. 2-Chloro-5-Chloro Methyl Thiazole (CCMT) ii. 3-Methyl-4-nitroiminoperhydro-1,3,5-Oxadiazine iii. N,N-Dimethylformamide (DMF) iv. Potassium Carbonate v. HCL-30 % vi. 50% H 2 O NOVALURON (INSECTICIDE PGR) i. 2, 6-Difluoro Benzamide ii. Oxyalyl Chloride Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

14 iii. BENZANAMINE(3-CHLORO 4 (1.1.2 TRI FLUROMETHOXY )ETHOXY)ANILINE) iv. TOLUENE LAMDA CYHLOTHRINE i. Z-(1R,S)-cis-2,2-dimethyl-3-(2,2-chloro-3,3,3-trifluoro-1- propenyl)cyclopropanecarboxylic acid (lambda Cyhalothric acid) ii. N HEXANE iii. Sodium cyanide iv. Meta phenoxy Benz aldehyde v. Dimethyl formamide vi. Sodium carbonate vii. Sodium hypo chloride 8 % viii. Di isopropyl amine ) ix. Isopropyl Alcohol BIFENITHRINE i. BIFENENTHRIN ALCOHOL ii. THIONYL CHLORIDE iii. Ethylene di chloride (EDC) iv. N,N-Dimethylformamide (DMF) v. N,N-Dimethylformamide (DMF) vi. LAMBDA ACID vii. K 2 CO viii. HCL-30% ix. n-hexane x. ACETIC ACID xi. NaOH 20 % CHLOROPYRIPHOS i. 3_5_6-trichloro-2-pyridinol SODIUM SALT (Na-HTCP) -85 % ii. Ethylene Dichloride (EDC ) iii. Sodium chloride iv. Catalyst Tetrabutylammonium bromide(tbab)/dimethyl amino pyridine (4 DMAP) v. SODIUM HYDROXIDE vi. DIETHYL THIO PHOSPORYL CHLORIDE (DETC) ACEPHATE i. O O - Dimethyl Phosphoro Amino Thioate ( DMPAT) ii. Dimethyl Sulphate (DMS) iii. Acetic Anhydride iv. Sulphuric Acid Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

15 v. Ammonia gas vi. Chloroform vii. Ethyl Acetate PROFENOPHOS i. 4-Bromo2-chloro phenol ii. DIETHYL THIO PHOSPORYL CHLORIDE (DETC) iii. Sodium hydroxide NAOH 26 % iv. Catalyst Tetrabutylammonium bromide(tbab v. ETHANOL -99 % vi. SODIUM HYDROSULPHIDE NaSH-26 % vii. TEBA viii. n-propyl Bromide FIPRONIL i. 5-amino-3-cyano-1-(2,6-dichloro-4-trifluoro methyl phenyl) pyrazole ii. Trifluoro methyl sulfynyl chloride iii. Toluene BUPROFEZINE i. Ammonium Bicarbonate ii. Ethylene dichloride (EDC ) iii. Thiourea iv. Carbamoyl chloride ((Chloromethyl) phenylcarbamic chloride) v. Methanol CARTAPE HYDROCHLORIDE i. 2-dimethylamino-1,3-dichloropropane HCl(1,3-dichloro-N,Ndimethylpropan-2-amine HCL ) ii. sodium thiosulphate iii. sodium cyanide iv. NaOH v. Methanol vi. HCL[g] ABAMACTINE i. STREPTOMYCESS AVERMITIES ii. ANTHELMENTHIC iii. ACARICIDAL iv. METHANOL AZOXY STROBINE i. (E) methyl 2-[2-(6-chloropyrimidin-yloxy) phenyl]-3-methoxy propionate ii. N,N-Dimethylformamide (DMF) iii. 2-Cyano phenol Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

16 iv. Potassium carbonate v. Copper (I) chloride CuCl vi. METHYLENE DICHLORIDE (MDC ) vii. HEXANE EMAMECTIN BENZOATE i. Methyl amine ii. Avermectin (ABAMACTINE ) iii. Methanol iv. Acetic acid v. Tertiary butyl dimethyl silyl chloride vi. Sodium carbonate vii. Ethylene dichloride (EDC ) viii. Ethyl Acetate ix. Benzoic acid SPENOSIDES , i. SPINOSYN J AND L ii. Ethanol -99 % iii. Isopropyl alcohol iv. RH/AL 2 O VALIDAMYCINE i. TREHALOSE DIHYDRATE ii. VALIDOXYLAMINE A iii. HEXANE HEXACONAZOL i. N,N-Dimethylformamide (DMF) ii. CHLORO METHYL OXIRANE iii. K 2 CO iv. 1,2,4 Triazole 98 % v. POLY SORBITOL TRICYCLAZOLE i. FORMIC ACID ii. 4-Methyl-2-hydrazino benzothiazole (HMBT) PROPICONAZOLE i. 1,2,4 Triazole 98 % ii. K 2 CO iii. N,N-Dimethylformamide (DMF) iv. 2-(bromomethyl)-2-(2,4 -dichlorophenyl)-4-propyl -1,3-dioxolane (BROMO KETAL) Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

17 v. Ethylene di chloride (EDC ) TEBUCONAZOLE i. 2-[2-(4-Chlorophenyl)ethyl]-2-(1,1-dimethylethyl)-oxirane (OXIRANE) ii. 1,2,4 Triazole 98 % iii. POTTASIUM HYDROXIDE (KOH) iv. n-butanol v. HCL DIFENCONAZOLE i. 2-((4-(P-CHLOROPHENOXY)-2-CHLOROPHENYL)-2-BROMOMETHYL-4- METHYL-1,3-DIOXOLANE (BROMO KETAL) ii. 1,2,4 Triazole 98 % iii. K 2 CO iv. N,N-Dimethylformamide (DMF) v. Ethylene di chloride (EDC ) IPCONAZOLE i. Ethyl 3-isopropyl-2-oxo-cyclopentane-1-carboxylate ii. 4 chloro benzyl chloride iii. Sodium carbonate iv. Toluene ) v. Trimethylsulfoxonium iodide -catalyst PACLOBUTRAZOLE i. 1-chloropinacolone ii. 1,2,4 Triazole 98 % iii. Toluene iv. NaOH v. p-chlorobenzyl Chloride vi. Sodium tetrahydridoborate. (NaBH4 ) THIOPHENATE METHYLE i. Ethylene di chloride (EDC ) ii. (sodium thiocynate) NaSCN iii. DMA (DI METHYL AMINE ) iv. MCF (METHYL CHLORO FORMATE) v. OPDA (ORTHO PHENYLENE DI AMINE) METALAXYL i. MAC--(METHOXY ACETYL CHLORIDE) ii. Methyl 2 6 dimethyl aniline iii. N,N-Dimethylformamide (DMF) iv. Toluene v. HEXANE Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

18 28. IMAZETHAPYR i. 3 -Isopropyl 3-Methyl 5H Imidazole pyrrole-3 ethyl pyridine 2 5 diol ii. METHANOL iii. Sodium hydroxide in methanol iv. ACETIC ACID v. NAOH 4 N vi. HCL-36 PER METSULFURON -METHYL i. O-sulfo Isocyanate M ethyl Benzoate ii. 2-Amino 4-Methoxy 6-Methyl 1,3,5 Triazine iii. Toluene SULFPSULPHURON i. 2-Ethylsulfonylimidazo[1,2-a]pyridine-3-sulfonamide (ESPO) ii. 4,6-Dimethoxy-2-(phenoxycarbonyl) amino pyrimidine (ADCP) iii. ACETONE iv. NaOH SOLUTION -30 % v. HCL-30 % CHLORIMURON-ETHYL i. BENZENE sulphonamide ii. Ethyl chloroformate iii. Toluene iv. Sodium carbonate v. Aminopyrimidine PYRAZOSULPHURON i. 1-Methyl-4-ethylformate-5-pyrazole sulfonamide ii. Ethyl chloroformate iii. Toluene iv. Sodium carbonate v. Aminopyrimidine BENSULPHURON -METHYL i. O Methyl Benzyl Sulphonamide ii. Ethyl chloroformate iii. Toluene iv. Sodium carbonate v. Dimethyl Amino Pyridine CHLODINOFOB-PROPARGYL i. 2-(4-hydroxy phenoxy propionic acid (98%) ii. K 2 CO Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

19 iii. phase transfer catalyst tetra butyl ammonium bromide iv. 2,3 difluoro-5-chloro pyridine (98%) v. Propargyl Chloride (70%) vi. N,N-Dimethylformamide (DMF) vii. HEXANE viii. Isopropyl alcohol ix. Activated carbon BUTACHLOR i. n-butanol ii. MRM (2-CHLORO-(N-2, 6- DIETHYL PHENYL ) ACETAMIDE iii. Ammonia gas PRITILACHLOR i. 2,6- Diethyl-N-(2-propoxyethyl) aniline (DEPA) ii. HEXANE iii. Chloro acetyl chloride (CAC) iv. Sodium carbonate v. Sodium hypo chloride 8 % GLYPHOSATE i. Phosphono methyl imino di acetic acid (PMIDA) ii. SODIUM TGSTATE iii. Hydrogen peroxide (H 2 O 2 ) iv. SODIUM META BI SULPHATE v. Vanadium Sulphate CATALYST OXYFLOROFEN i. 3-ethoxy-4-nitrophenol, ii. 3,4-dichloro-benzotrifluoride iii. Potassium carbonate iv. Toluene ATRAZINE i. Toluene ii. Cyanuuric Chloride iii. Mono Iso Propyl Amine 70 % (MIPA) iv. Na OH -47 % v. HCL -36% vi. MONO ETHYL AMINE -70 % (MEA) METRIBUZINE i. METHANOL ii. Sulfur Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

20 iii. Bromine iv. Triazinone v. Sodium Bisulfite vi. 2 Ethyl Hexanol vii. 10% NaOH solution viii. Chlorine ix. NAOH 47 % x. 32% NAOH CYPERMETHRINE i. CYPERMETHRIN ACID CHLORIDE) ii. Meta phenoxy Benz aldehyde (MPBAD) iii. N HEXANE iv. Sodium cyanide v. TriethylBenzyl Ammonium Chloride(TEBACL vi. Sodium carbonate vii. Sodium hypo chloride 8 % ALPHA CYPER METHRINE i. Meta phenoxy Benz aldehyde (MPBAD) ii. CYPERMETHRIN ACID CHLORIDE iii. Sodium cyanide iv. N HEXANE v. Catalyst vi. Sodium carbonate vii. Isopropyl alcohol viii. Sodium hypo chloride 8 % PERMETHRIN i. CYPERMETHRINE ACID CHLORIDE ii. MPBAL iii. N HEXANE iv. NaOH 47 % v. Sodium carbonate DELTAMETHRINE i. Meta phenoxy Benz aldehyde (MPBAD) ii. Dibromovinyl Dimethyl Cyclo propane Carboxylic Acid Chloride iii. Sodium cyanide iv. N HEXANE v. Catalyst vi. Sodium carbonate Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

21 vii. Isopropyl alcohol viii. Catalyst ix. Sodium hypo chloride 8 % CYPERMETHRINE ACID CHLORIDE (CMAC) i. CARBON TETRA CHLORIDE ii. ACRYLO NITRILE iii. HYDROCHLORIC ACID 30 % iv. THIONYL CHLORIDE 9/7/ v. NaOH 47 (CS LYE) vi. NAOH FLAKES vii. NA 2 SO 3 20% viii. ISOBUTELENE ix. NAHCO x. N,N-Dimethylformamide (DMF) xi. TRI ETHYL AMINE TEA xii. N HEXANE xiii. H 2 SO xiv. CAT xv. CAT xvi. CAT DIFENTHIURON i. Toluene ii. N-(2,6 Di isopropyl -4-phenoxy phenyl)-iso thiocynate iii. Tert. -butyl amine iv. n-hexane v. Isopropyl alcohol SAFENAR -CLOQUINTO SET MAXYL i. N HEXANE ii. Mono chloro acetic acid (MCA) iii. 2 HEPTANOL iv. p-toluene sulfonic acid (PTSA) v. NaHCO vi. N,N-Dimethylformamide (DMF) vii. Potassium carbonate viii. CHQ (5 CHLORO 8 HYDROXY QUINOLINE MICHLOBUTANIL i. DMSO ii. POTASSIUM HYDROXIDE (KOH) Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

22 iii. 1,2,4 Triazole 98 % iv. 1-CHLORO 2- (CYANO-2- (4-CHLORO PHENYL) HEXANE v. Toluene vi. NaHCO PENDIMETHYLENE i ii. DIETHYL KETONE iii. PT 5% ON CHARCOL iv. 2 NAPTHALINE SULPHONIC ACID v. SULPHURIC ACID H 2 SO vi. NITRIC ACID HNO vii. Ethylene di chloride (EDC ) viii. n-hexane ix. HCL -36% 10N Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

23 3.6.3 Solvent and Solvent Management Plan Table 1.6 List of Solvents # Product Name of Solvent INSECTICIDE Consumption Recovery Difference % Recovery Kg/Tons 1. Acetamiprid Methanol Imidacloprid 3. Thiacloprid 4. Thiamethoxam 5. Novaluron (INSECTICIDE PGR) 6. Lambda-Cyhalothrin 7. Bifenthrin 8. Chlorpyrifos 9. Acephate Dimethyl Formamide (DMF) Dimethyl Formamide (DMF) Hexane Dimethyl Formamide (DMF) Toluene n-hexane Isopropyl Alcohol Dimethyl Formamide (DMF) Ethylene Di Chloride (EDC) Ehanol Hexane Ethylene Di Chloride (EDC) Chloroform Ethyl Acetate Profenofos Ethanol Fipronil Tolune Buprofezin Ethylene Di Chloride (EDC) Methanol Cartap hydrochloride Methanol Azoxystrobin BIO PESTICIDE Dimethyl Formamide (DMF) Methylene Di Chloride (MDC) n-hexane Abamectin Methanol Emamectin Methanol Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

24 # Product Name of Solvent Consumption Recovery Difference % Recovery Kg/Tons Benzoate Ethyl Acetate Ethylene Di Chloride (EDC) Spinosad Ethanol BACTERIOCIDE Isopropyl Alcohol Validamycin n-hexane FUNGICIDES 19. Hexaconazol Dimethyl Formamide (DMF) Tricyclazol Formic Acid Propiconazole Dimethyl Formamide (DMF) Ethylene Di Chloride (EDC) Tebuconazole n-butanol Difenoconazol Dimethyl FormamidE (DMF) Ethylene Di Chloride (EDC) Ipconazole Toluene Paclobutrazol Toluene Thiophanate-methyl 27. Metalaxyl HERBICIDES Ethylene Di Chloride (EDC) Toluene Hexane Imazethapyr Methanol Metsulfuron-methyl Toluene Sulfosulfuron Acetone Chlorimuron ethyl Toluene Pyrazosulfuron-ethyl Toluene Bensulfuron-methyl Toluene Clodinafop-propargyl Dimethyl Formamide (DMF) Hexane/IPA Butachlor n-butanol Pretilachlor n-hexane Glyphosate* - Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

25 # Product Name of Solvent Consumption Recovery Difference % Recovery Kg/Tons 38. Oxyfluorfen Toluene Atrazine Toluene Metribuzin Methanol PROPOSED HERBICIDES 41. Diafenthiuron n-hexane /IPA Pendimethalin PROPOSED INSECTICIDES Ethylene Dichloride - EDC n-hexane Cypermethrin n-hexane Alpha Cypermethrin n-hexane Isopropyl Alcohol Permethrin n-hexane Deltamethrin PROPOSED INTERMIDIATES Cypermethric Acid Chloride (CMAC) SAFENAR Cloquintocet-mexyl PROPOSED FUNGICIDES n-hexane Isopropyl Alcohol n-hexane Dimethyl Formamide (DMF) n-hexane Myclobutanil Toluene Solvent Management Plan: The solvent distillation system is /will be designed so as to achieve minimum 97% recovery of solvent. Organization is having dedicated multipurpose solvent distillation and recovery plant. Pure solvent, crude solvent and distilled (recovered) solvent are/shall be stored only in storage tanks and are not/shall not be used drums at any stage in the Solvent Management System. Wherever required, the solvents are/shall be directly pumped into day tanks from the storage tanks and are/shall be charged into the reactors without involving any manual handling. All the pumps are/will mechanical seal type to avoid any leakage of solvent. All necessary firefighting systems are/will be provided with alarm system. Flame proof wiring and flame proof electrical accessories are/will be provided to avoid any mishap. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

26 All the storage tank and day tank are/shall be connected to a vent system through chilled water/chilled Brine condensers to prevent loss of solvents in the atmosphere. Also, all the distillation column vents are/shall be connected to chilled water/chilled Brine condensers for maximum possible recovery of the solvents. Pipelines connected with reactors and scrubbers are/will be installed with minimum number of flanges, joints and valves. Operators are/will be available round the clock at operation floor and maintain the parameters as per procedure. Periodic monitoring of work area is being/will be carried out to check the secondary fugitive emission. 3.7 RESOURCE REQUIREMENT Various resources like land, utility, power, fuel, water, manpower etc. will be utilized for carry out production activities. Simply production is converting resources into finished product Land HPM Chemicals and Fertilizers Ltd. formerly known has already 20,000 m 2 area on which existing plant is in operation, and 10, m 2 plot for ware house and utility purpose land document for the same is attached as Annexure 3 with TOR application. Expansion project will be set on existing plot. The area m 2 has been utilized for green belt in existing and m 2 area will be developed as green belt in expansion. Also, 5 m wide plantation was done by proponent outside the boundary line of 2000 m around periphery of the project in existing with the prior permission of RIICO. Construction of ware house, plant building and other ancillary amenities is and will be undertaken within the plot area. Expansion project will be developed in accordance with local development plan and used for industrial purpose. Bifurcation of plot area is mentioned in table 1.7. Table 1.7 Bifurcation of Plot area # Particulars Existing Proposed Total (m 2 ) (m 2 ) (m 2 ) 1 Production Area Storage Area Admin Building Parking, Internal Road, etc Utility Green Belt Misc (Open, Lab, Ware house, etc.) Total Green Belt outside boundary photographs Total green belt m wide plantation was done by proponent outside the boundary line of 2000 m around periphery of the project in existing with the prior permission of RIICO. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

27 3.7.2 Water Expansion project is located in RIICO Khushkhera industrial area, having all basic amenities for water, power, transport etc. Water requirement for existing and expansion project is/will be fulfilled by RIICO water supply only. No groundwater extraction shall be carried out without prior permission from the Central Ground Water Authority (CGWA). Project proponent has already made to application to RIICO for withdrawal of proposed water. Bifurcation of daily water consumption during construction and operation phase is described below in table 1.5. Construction Phase: Domestic 10 KLD Construction activities, curing and Dust suppression 10 KLD Operation Phase: Table 1.8: Water Consumption S. No. Activities Existing (KLD) Proposed (KLD) Total (KLD) Remark Fresh Recycled Fresh Recycled Fresh Recycled 1. Domestic Fresh 2. Industrial - i Processing Fresh + MEE Condensate ii. Boiler Fresh iii. Cooling Fresh iv. Scrubber Fresh Scrubber Fresh 3. Other Use i For Gardening* * * ii Sprinkling Total Grand Total Treated water from STP Treated water from STP *Will not use 6.89KLD fresh water for gardening after expansion as water required for gardening will be fulfilled by proposed STP. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

28 Total Water Consumption:50 KLD (Fresh: Condensate from MEE 9.14 KLD) Condensate from MEE (9.14 KLD) Fresh water from RIICO (40.86 KLD) Domestic: 4 WATER FROM PROCESS GENERATION: 0.06 WATER FROM RM: 1.5 Processing: 9.16 Cooling tower make up: 15.0 Boiler: FEED Scrubber: 1.20 Gardening: 6.89 Evap. Losses: 14 Septic Tank with soak pit WASTE WATER GENERATION: ORGANIC HIGH COD: 0.52 CTB: 1.00 BOILER BLOW DOWN: 0.74 Condensate 2.86 WASTE WATER GENERATION: Incineration HIGH TDS/LOW COD 16.0 ETP MEE-FEED HIGH TDS CONDENSE TE MEE: 9.14 MEE LOSS-3.66 Wet -SALT :3.20 WATER DRYING LOSS-1.54 SALT-1.66 Figure 1.4 Existing Water Balance Diagram Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

29 After expansion Water Consumption: KLD (Fresh: KLD + Condensate from MEE: KLD + Treated water from STP: 25 KLD) Condensate from MEE (73.14 KLD) Fresh water from RIICO ( KLD) Domestic: 35.0 WATER FROM PROCESS GENERATION: 0.6 WATER FROM RM- 3.5 Processing: Cooling tower make up : Boiler: FEED Scrubber 2: 5.0 Scrubber 1: 35 Evap. losses for by product: 35.0 SEWAGE TREATMENT PLANT WASTE WATER GENERATION: ORGANIC HIGH COD: 4.07 cooling tower blow down: 4.0 BOILER BLOW DOWN: 5.0 Condensate from process: 10.0 Scrubber: 5.0 Treated water: 25 for Gardening (19) and Sprinkling (6) WASTE WATER GENERATION Incineration HIGH TDS/LOW COD ETP ETP Sludge: 1.17 MEE-FEED HIGH TDS CONDENSE TE MEE: MEE Water vapour loss: Wet -SALT: WATER DRYING LOSS-10.0 SALT Figure 1.5 Water Balance Diagram after expansion Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

30 3.7.3 Electricity Construction Phase: Diesel operated construction equipment and machineries will be used during construction phase. Existing D.G. set of capacity 62 KVA will be kept as a stand-by arrangement used during power interruption. Operation Phase: Electricity: Existing 150 kva tech 500 kva formulation and additional requirement expansion project 1200 kva, Hence total will be 1850 kva will be sourced from Jaipur Vidyut Vitran Nigam Limited (JVVNL)-Bhiwadi (Jaipur). Backup Power: Existing D. G. set (62 kva) 1 No. and Proposed D.G. set 125 kva *02 Nos., 160 kva *01 No. and 500 kva 01 No. total will be 972 kva Fuel Coal 1277 TPA for existing boilers and TPA for Proposed boiler or Wood TPA for existing boilers and TPA for proposed boiler or Rice Husk TPA for proposed boiler. HSD 500 L/h for proposed incinerator and 20 L/h for existing D.G. Set and 200 L/h for proposed D.G. Sets. LDO- 200 L/h for existing Incinerator Manpower Construction Phase: Local construction workers will be employed from surrounding area during this phase. It is estimated that Nos. of Local workers (skilled and semiskilled) will get direct employment during construction phase. Operation Phase: An industrial plant normally runs in three shifts and at full rated plant capacity. Technical and non-technical personnel will be required for manufacturing unit, utility unit, O&M of plant, security, admin etc. it is estimated that additionally 30 Nos. technical person will get direct and other contractor worker will get indirect employment during operation phase after expansion. Already 110 Nos. of workers are employed for operation of existing pesticide manufacturing plant. Hence total manpower will be 140 Nos Utility The requirement of utilities for the proposed project has been estimated based on plant operation capacity. Steam Boiler 01 TPH *2 boilers of bar and proposed 10.0 TPH boiler of bar Cooling Tower 200 RT Delta T-6 deg C and 400 TR*1 for MEE. Air Compressor for Instrument Air at 2 to 3 bar pressure. Chilled brine of -20 one for 20 TR plant and one for 30 TR plant. Existing Incinerator 1 No. 25 kg/h. Proposed Incinerator 1 No. 200 kg/h. Proposed MEE- 125 KLD, existing 25 KLD total 150 KLD. Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

31 3.8 WASTE TO BE GENERATED It is envisage that due to expansion project activity various wastes to be generated which are described as under: Sewage Construction Phase: Sewage will be expected to generate due to domestic activities of workmen and staff personnel during construction phase. On site sanitation facilities will be provided to construction workers. Separate arrangement of sanitation facility for female workers. It is estimated that 6.00 KLD sewage generated, which will send to soak pit through septic tank. Operation Phase: Sewage quantity of 35 KLD will be generated and it shall be treated in packaged STP of capacity 50 KLD Effluent Effluent generated from the manufacturing process and other ancillary operation will be pretreated in adequate newly constructed effluent pre-treatment plant of capacity 125 KLD. It is estimated that 125 KLD effluents will be Pre-treated in ETP and treated water will be feed to KLD MEE and the condensate water from MEE will be recycled in processing whereas salt generated from MEE will be sent to TSDF land filing site, hence proposed project is Zero Liquid Discharge (ZLD) unit. # Activities Existing (KLD) Table 1.9 Wastewater Generation Proposed (KLD) Total (KLD) Remark 1. Domestic Treated in STP 2. Industrial i Processing ii. Boiler-blow down iii Cooling-blow down iv Scrubber Other Boiler i Condensate Total Industrial Treated in ETP followed by MEE Treated in ETP followed by MEE 4. Total Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_

32 Figure 1.6 ETP Flow Diagram Air Emission Stack discharge norms for HCL, SO 2, CO, TOC and PM will be maintained. Air emission (flue gases stack and process emission), nature of emitted pollutants and system provided for air pollution control in expansion plant is mentioned in table 1.10 and Stack # attached to Existing 1 Existing Boiler Capacity of Utility Fuel 1 TPH*2 WOOD or Coal Table 1.10: Flue Gas Emission Fuel Consumption TPA TPA Height (m) Diameter (mm) Pollutants PM <1200 mg/nm 3 2 Incinerator 25 kg/h LDO 200 L/h HCL <50 mg/nm 3, SO 2 <200 mg/nm 3 CO <100 mg/nm 3 APC device Adequate stack height and Cyclone separator Adequate stack height and Ventury Scrubber Eco Chem Sales & Services, Surat Doc. No: 2017_ECSS_EIAI2_