Safety Data Sheet according to 2001/58/EC

Transcription

1 Print date: Revision date: Page 1 of 6 1. Identification of the substance/preparation and company Product code: 1096-Desco 1.1 Commercial product name OXYGENON 1.2 Information manufacturer/supplier Antiseptica chem.pharm. Produkte GmbH Carl-Friedrich-Gauss-Straße 7 D Pulheim-Brauweiler Telephone: +49 (0) 2234 / Telefax: +49 (0) 2234 / info@antiseptica.com Inquiry office: Telephone: +49 (0) 551 / Telephone for doctors: +49 (0) 551 / Telefax for doctors: +49 (0) 551 / giznord@giz-nord.de GIZ Giftinformationszentrum Nord Zentrum für Pharmakologie und Toxikologie, Georg-August- Universität Göttingen 2. Composition/information on ingredients Chemical characterization: (preparation) Hazardous components (Full text of each relevant R phrase can be found in heading 16) EC No. CAS No. Components Value Symbols R-phrases Pentasodium-bis-(peroxomonosulfate) % O, C R bis(sulfate) Citric acid 5-10 % Xi R36 3. Hazards identification Classification Symbol: Corrosive R-phrases: Causes burns. Harmful if swallowed. Explication of special hazards for human health and environment Contact with combustible material may cause fire. 4. First aid measures General information Move out of dangerous area. Protection is needed for the First Aider.

2 Print date: Revision date: Page 2 of 6 After inhalation Move to fresh air. If symptoms persist, call a physician. After contact with skin Wash off immediately with plenty of water. Take off all contaminated clothing immediately. After contact with eyes In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Protect unharmed eye. Call a physician immediately. Continue rinsing eyes during transport to hospital. After ingestion Do not induce vomiting. Clean mouth with water and afterwards drink plenty of water. Advice to doctor In case of ingestion, the stomach should be emptied by gastric lavage under qualified medical supervision. 5. Fire-fighting measures Suitable extinguishing media Water spray mist or foam. dry powder Extinguishing media that must not be used for safety reasons carbon dioxide (CO 2 ) Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases The product itself does not burn. Special protective equipment for firefighters In the event of fire, wear self-contained breathing apparatus. Additional information Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures Personal precautions Use personal protective equipment. Environmental precautions Prevent product from entering drains. Do not flush into surface water. Methods for cleaning up/taking up Take up mechanically and collect in suitable container for disposal. Additional information Local authorities should be advised if significant spillages cannot be contained.

3 Print date: Revision date: Page 3 of 6 7. Handling and storage 7.1 Handling Advice on safe handling Provide appropriate exhaust ventilation at places where dust is formed. Advice on protection against fire and explosion Contact with water or heating causes the release of oxygen. Keep away from combustible material. Never allow product to get in contact with water during storage. 7.2 Storage Requirements for storage rooms and vessels Keep containers tightly closed in a dry, cool and well-ventilated place. Advice on storage compatibility Keep away from combustible material. Storageclass (VCI): Exposure controls/personal protection 8.1 Exposure limit values Exposure limits (EH40) Components Exposure limit CAS No. ml/m³ mg/m³ F/ml Category Origin Pentasodium-bis-(peroxomonosulfate)-bis(sulfate) 6 TWA (8 h) MAK STEL (15 min) MAK 8.2 Exposure controls Occupational exposure controls Respirator must be worn if exposed to dust. Protective and hygiene measures General industrial hygiene practice. Keep away from food, drink and animal feeding stuffs. Respiratory protection Respirator must be worn if exposed to dust. Hand protection protective gloves Eye protection safety glasses Body protection Lab coat Remove and wash contaminated clothing before re-use.

4 Print date: Revision date: Page 4 of 6 9. Physical and chemical properties 9.1 Appearance Form: Colour: Odour: powder white mild musty 9.2 Important health, safety and environmental information ph Value ca. 3 Test method Changes in the physical state Flash point: not applicable Flammability Ignition temperature: Water solubility: no data available completely soluble 9.3 Other information Autoignition temperature 10. Stability and reactivity Conditions to avoid Exposure to sunlight. Heat. Exposure to moisture. Materials to avoid Metals. Decomposes by reaction with alkaline solutions. reducing agents Hazardous decomposition products oxygen 11. Toxicological information Additional information No data is available on the product itself. Causes burns. Health injuries are not known or expected under normal use. 12. Ecological information Ecotoxicity The product is toxic to algae.

5 Print date: Revision date: Page 5 of 6 Mobility The product can be degraded by abiotic (e.g. chemical or photolytic) processes. Persistence and degradability Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Contained tenside is more than 90% biodegradable. 13. Advice on disposal Dispose Can be disposed of as waste water, when in compliance with regulations of local sewerage undertaking or the NRA. Waste disposal number of Waste from residues / unused product: Waste disposal number of used product: Waste disposal number of contaminated packaging: Contaminated packaging Rinse empty containers with water and use the rinse-water to prepare the working solution. Triple rinse containers. Empty containers should be transported/delivered using a registered waste carrier for local recycling or waste disposal. 14. Transport information 14.1 Land transport (ADR/RID) ADR/RID: 8 Warnings plate : Hazard-no.: 80 UN number: 3260 Hazard label: 8 ADR packaging group: III Description of the goods: Corrosive solid, acidic, inorganic, n.o.s., (Sodiumperoxomonosulfate, Mixture) Remarks Limited quantities according to marginal ADR/RID : liquids not more than 6 litre(s) per inner packaging and not more than 24 litre(s) per package 14.2 Inland waterways transport 14.3 Marine transport IMDG-Code: 8 UN number: 3260 EMS: F-A, S-B Packaging group: III Marine pollutant: no

6 Print date: Revision date: Page 6 of 6 Description of the goods Corrosive solid, acidic, inorganic, n.o.s., (Sodiumperoxomonosulfate, Mixture) Hazard label: Air transport 14.5 Further Information 15. Regulatory information 15.1 Labelling Indication of danger C - Corrosive Hazardous component(s) to be indicated on label Pentasodium-bis-(peroxomonosulfate)-bis(sulfate) R phrase 34 Causes burns. S phrases /39 Do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately. (show the label where possible) Wear suitable gloves and eye/face protection National regulations Water contaminating class: 1 - slightly water contaminating 16. Other information List of relevant R phrases 08 Contact with combustible material may cause fire. 22 Harmful if swallowed. 34 Causes burns. 36 Irritating to eyes. Other data The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations.